30 results about "C60 fullerene" patented technology

The present invention relates to covalently bonded fullerene-functionalized carbon nanotubes (CBFFCNTs), a method and an apparatus for their production and to their end products. CBFFCNTs are carbon nanotubes with one or more fullerenes or fullerene based molecules covalently bonded to the nanotube surface. They are obtained by bringing one or more catalyst particles, carbon sources and reagents together in a reactor.

A method for synthesizing compounds of the formulawhere C60 is a C60 fullerene. The method comprises the steps of forming a macrocyclic malonate compound of the formulawhere each Z is the same or different and is a straight-chain or branched-chain aliphatic radical having from 1-30 carbon atoms which may be unsubstituted or monosubstituted or polysubstituted by identical or different substitutents, in which radicals up to every third CH2 unit can be replaced by O or NR where R is alkyl having 1-20 carbon atoms or a chain containing unsubstituted or substituted aryl or other cyclic groups and n is an integer from 2 to 10; reacting said macrocyclic malonate compound with C60 to form an adduct of the formulawhere the Z radicals are linked together to form said macrocycle adduct; and hydrolyzing said macrocycle adduct to form a compound of the formula

Methods for producing p-doped organic semiconductor material with a fullerene derivative having at least one electron-withdrawing substituent covalently attached thereto, and semiconductor compositions prepared thereby are provided. Also provided are electronic devices, such as transistors, solar-cells, illuminating devices, OLEDs and detectors, comprised of these p-doped organic semiconductor materials.

The invention discloses a fullerene amino-acid-ester self-assembled medicine-carrying slow-release vesicle material, and a preparation method and application thereof, and relates to the field of fullerene. The vesicle material is prepared by enabling fullerene molecule to be connected with an amino-acid ester molecule through nucleophilic substitution, wherein fullerene is C60 fullerene and the molecular general formula is C60R5Cl. The preparation method comprises taking C60 fullerene and ICl as raw materials, taking chlorobenzene as a solvent, and synthesizing C60Cl6; adding an amino acid into a hydrochloric acid methanol saturated solution, and performing heating reflux to obtain the amino-acid ester; performing heating reflux on C60Cl6 and the amino-acid ester in a mixed solvent of ethyl acetate and toluene, so as to obtain the fullerene amino-acid-ester cruder product; and performing chromatographic separation, so as to obtain the fullerene amino-acid-ester self-assembled medicine-carrying slow-release vesicle material.

The invention belongs to a method producing solar cell by polymer, greatly improving crystallinity of P3HT in a blending film of a P3HT and C60 fullerene or a derivative PCBM of P3HT and ensuring whisker of P3HT in the blending film which is in a micro length to be uniformly dispersed on the whole film and having a nano-sized separation distance. By using the method, the transferring efficiency of solar cell arrives at 3.9 percent while the transferring efficiency of solar cell processed by thermal annealing can only reach 3.7 percent, which shows that through the method the high performed and non-annealed polymer solar cell can be produced by one step.

Fullerenes are a novel material that has been expected to serve as a promising material in the construction of organic devices. However, the electric conductivity of fullerenes, which has been, reported heretofore spreads over a wide range including values corresponding to insulators as well as those corresponding to semiconductors. The present invention makes it possible to improve the conductivity of fullerenes highly reproducibly by heating the fullerenes at a specified temperature in an inert gas which is flowed under a specified condition, that is, by controlling the concentration of impurities, particularly oxygen and water adsorbed to the fullerenes.

The invention relates to a preparation method and an application of implantable fullerene polylactic acid self-agglomerating drug-loaded sustained release microspheres so as to effectively solve the problems of preparation of the implantable fullerene polylactic acid self-agglomerating drug-loaded sustained release microspheres and application of the implantable fullerene polylactic acid self-agglomerating drug-loaded sustained release microspheres in medicines for photodynamic therapy of tumors. According to the technical scheme for solving the problems, the preparation method is characterized in that fullerene molecules are connected to polylactic acids through chemical bonds, the relative molecular weight of the polylactic acids is 10000-18000, fullerene is C60 fullerene, and the particle sizes of the microspheres are 1-10 micrometers. The preparation method is simple; preparation conditions are easily satisfied; the intrinsic characteristics of the fullerene are not damaged; and the implantable fullerene polylactic acid self-agglomerating drug-loaded sustained release microspheres enable photodynamic therapy and chemotherapy to simultaneously play a role in tumor treatment and are innovation of the medicines for treating the tumors.

The invention discloses a nano-far infrared superconducting composite material, which is prepared by subjecting 40%-60% of zirconium aluminate (800 meshes), 20%-30% of titanium dioxide (with a nanoscale of less than or equal to 100nm), 3%-8% of Inner Mongolia lanthanide rare earth (with a nanoscale of less than or equal to 100nm), 3%-6% of cobalt oxide (800 meshes-1200 meshes), 5%-10% of C60 fullerene (20nm-100nm), and 10%-20% of Guangxi tourmaline (1800 meshes-2500 meshes) to ball-milling mixing for 1h in a ball mill. The invention aims to provide a simple process of a new material, which has no energy consumption and is convenient for mass popularization. And the broad spectrum far infrared rays emitted by the material are suitable for application in most occasions.

The invention relates to a superhard semiconductor amorphous carbon block material and a preparation method thereof. The method includes the following steps: (1) prefabricating C60 fullerene into a columnar blank body; (2) loading the obtained columnar blank body into a hexagonal boron nitride crucible, and then loading into a high-temperature high-pressure assembly block; (3) placing the assemblyblock in high-temperature and high-pressure synthesis equipment for high-temperature and high-pressure treatment; and (4) acquiring the superhard semiconductor amorphous carbon block material after the treatment is completed. According to the preparation method of the superhard semiconductor amorphous carbon block material, the C60 fullerene powder is taken as a raw material, a high temperature and high pressure test is utilized, a phase change behavior of the C60 fullerene under high pressure is explored by regulating a relationship between temperature and pressure, and the amorphous carbonblock material with high hardness or superhard hardness, compactness and semiconductor properties is synthesized, so that the material has a wide application prospect.

The present invention relates to a polyolefin composition comprising a polyolefin (A), a fullerene composition (B) which comprises: a C60 fullerene or a C60 chemical derivative selected from the group consisting of methanofullerene derivatives, PCBM derivatives, ThCBM derivatives, Prato derivatives, Bingel derivatives, diazoline derivatives, azafulleroid derivatives, ketolactam derivatives, and Diels-Alder derivatives; or a C70 fullerene or a C70 chemical derivative selected from the group consisting of methanofullerene derivatives, PCBM derivatives, ThCBM derivatives, Prato derivatives, Bingel derivatives, diazoline derivatives, azafulleroid derivatives, ketolactam derivatives, and Diels-Alder derivatives; or a blend of fullerenes; a master batch, a cable, and uses thereof.

The invention discloses a 5-alkyl-2,3-dihydrobenzofuran-C60 fullerene bis-adduct and a preparation method and application thereof. The bis-adduct as shown in the formula (I) (R is methyl or ethyl or isopropyl or tertiary butyl or tertiary pentyl) can be prepared through the method including the following steps that (1) PhI=NTs is prepared, (2) a bis-addition intermediate is prepared, and (3) the target bis-adduct is prepared. The bis-adduct is low in resultant temperature, short in reaction time, prone to separation and purification, beneficial to mass production, good in optical adsorption property within the visible light range and suitable for being used as an electron acceptor material for building photovoltaic devices such as a photovoltaic cell, thereby having great scientific research, development and market investment value.

The invention relates to an additive composition for improving the performance of lubricant, and a preparation method and application method thereof. The preparation method comprises the following steps: performing hydroxylation reaction for C60 fullerene to obtain C60(OH)8-15 or C60(OH)24-26, then catalytically esterifying the hydroxyl by virtue of short chain carboxylic acid C1-5COOH to obtain an esterification product C60(OOC-R)8-15 or 24-26 which is adopted as a component A, wherein the additive composition also comprises an ester dissolving agent and an antioxidant synergistic agent, andthe weight ratio of the three components, i.e., a weight ratio of component A to ester dissolving agent to antioxidant synergistic agent is (0.1 to 10): (2 to 20): (10 to 40). The additive compositiondoes not comprise water, sulfur, phosphorus, chlorine and mechanical impurities and is environment-friendly; and the additive composition has good wear resistance and friction reduction performance:the friction coefficient of the lubricating oil is decreased by 18.8 percent to 34.3 percent, an average grinding spot diameter is reduced to 0.49, and the oxidation induction period is increased by one time or more in the existence of the high-temperature high-pressure oxygen. After the lubricating grease is added, when the device is in an idle state, the input current can be decreased by 16.3 to20.3 percent.

The invention relates to a C60 fullerene peracetylated glucose derivative and application of the C60 fullerene peracetylated glucose derivative as a lithium battery cathode material. The C60 fullereneglucosinolates derivative has a structure shown in formula I as shown in the specification. The C60 fullerene peracetylated glucose derivative which has the structure shown in formula I can be usedas an active substance to prepare the lithium battery cathode material, and the first discharge capacity of the cathode material can reach 763 mAh/g.

The invention discloses wallpaper glue which comprises the following components: 750-800 parts of deionized water; 250-300 parts of inorganic powder, 10-20 parts of fullerene particles, 1-2 parts of dispersing agent, 2-3 parts of coupling agent, 1-5 parts of mildew preventive, 1-5 parts of surfactant, 60-100 parts of an inorganic thickener, 20-50 parts of polyvinyl alcohol, 30-50 parts of a rosinsolution, 1-2 parts of an antifoaming agent, 5-15 parts of a water-retaining agent, 1-4 parts of a bactericide and 1-4 parts of a dry film mildew inhibitor, and fullerene particles are nanoscale C60 fullerene and can sterilize and disinfect wallpaper glue and prevent the wallpaper glue from decaying and mildewing.

A method for synthesizing a medicinal, nutraceutical, or food fullerene composition, including providing anisotropy in polar and non-polar C60 fullerene hemispheres to create one face of C60 fullerene having a small number of OH-groups clustered to the polar face; providing an amount of a polyhydroxylated fullerene from C60 fullerene; and blending the amount of the polyhydroxylated fullerene with an acceptable ionomer or an acceptable carrier or both. The polyhydroxylated fullerene includes fullerol-'x′ and the amount includes 200 ppm or 500 ppm, wherein ‘x’ is less than 22. The acceptable ionomer includes honey, or a mixture of 3% by wt. sucrose, 1% by wt. proline, 0.2% by wt. magnesium citrate, and 1% by wt. beta-cyclodextrin. The acceptable carrier includes water or a gelatin. A stent, a medical bandage, medical packing material, medical drainage material, acupuncture support, topical ointment, or suture material is impregnated with an anisotropic polyhydroxylated fullerene for antimicrobial action.

The invention relates to a C60 fullerene glucose thioglycoside derivative and an application thereof as a cathode material of a lithium battery. The C60 fullerene glucose thioglycoside derivative has a structure represented by the formula I.

The invention relates to a skin care herbal essence and a preparation method thereof. The skin care herbal essence simultaneously contains the following raw material components: squalane, cannabidiol and C60 fullerene (hereinafter referred to as fullerene) of the latest version produced by Mitsubishi factory in Japan. The preparation method comprises the following steps: heating squalane and cannabidiol to 63-67 DEG C, mixing the squalane and cannabidiol together with a stirrer, adding fullerene after 3-7 minutes, mixing the fullerene with the stirrer for 3-7 minutes, and finally adding Swiss snow mountain spring water and other herbal essence. The squalane and cannabidiol herbal essence and the latest version of C60 fullerene produced by the Japanese Mitsubishi factory are combined with a permeation technology to achieve the most direct and quick effect of the anti-aging skin care product. Meanwhile, the anti-aging skin care product can repair the skin and resist free radicals.