Pi-conjugated organoboron polymers for use in thin-film
organic polymer electronic devices. The polymers contain aromatic and or unsaturated repeat units and
boron atoms. The vacant p-orbital of the
boron atoms conjugate with the pi-conjugated orbital
system of the aromatic or
unsaturated monomer units extending the pi-conjugation length of the
polymer across the
boron atoms. The pi-conjugated organoboron polymers are
electron-deficient and, therefore, exhibit n-type semiconducting properties,
photoluminescence, and
electroluminescence. The invention provides thin-film
organic polymer electronic devices, such as organic photovoltaic cells (OPVs), organic diodes, organic photodiodes, organic thin-film transistors (TFTs), organic field-effect transistors (OFETs), printable or
flexible electronics, such as radio-frequency identification (RFID) tags, electronic papers, and printed circuit elements, organic light-emitting diodes (OLEDs),
polymer light-emitting diodes (PLEDs), and
energy storage devices employing the pi-conjugated organoboron polymers. In
OLED and PLED applications these materials are used as the
electron transport layer (ETL) to improve device efficiency. The polymers which exhibit photo- and
electroluminescence are also useful as light-emitting material in PLEDs.