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131 results about "Phase equilibrium" patented technology

Phase equilibrium conditions of a system comprising v components (where v ≥ 1) and φ phases (where φ ≥ 1) results from the Second Law of Thermodynamics and may be expressed by following equalities: temperatures T(α) (thermal equilibrium, in which there are no heat flows); pressures p(α) (mechanical equilibrium, i.e., the phases are not separated); ...

Method for measuring gas hydrate phase balance condition

The invention provides a method for determining the phase balance condition of gas hydrates, which mainly has the procedures: gas to be measured is caused to generate hydrates in a reaction kettle which is provided with a temperature measurement system, a pressure measurement system and an exhaust system; gas-phase space in the reaction kettle is compressed; system temperature in the reaction kettle is regulated to the temperature of the phase balance condition to be measured to exhaust the gas and lower the pressure, as well as the exhaust system is closed when the pressure in the reaction kettle rises at once because the exhaust is stopped, thus the reaction kettle is caused to become a closed system; the variation of the pressure in the reaction kettle is observed, if the pressure keeps invariant for a long time, three-phase balance is considered to be reached, at this time, the corresponding temperature and the corresponding pressure are a set of phase balance condition for the hydrates. The system temperature can further rise to the next balance temperature to be measured, the pressure variation is continuously recorded until the hydrates in the reaction kettle is completely decomposed, therefore, a series of phase balance condition data of the hydrates can be obtained. Adopting the method, the phase balance condition of the gas hydrates in a free water system or a porous media can be measured, and the measurement accuracy is high.
Owner:CHINA UNIV OF PETROLEUM (BEIJING)

Visual experimental device for hydrogen gas hydrate characteristic research

The invention relates to a visual experimental device for hydrogen gas hydrate characteristic research, which comprises a gas supply system, a water supply system, a high pressure visual reaction kettle, agitating equipment, a temperature control system, a pressure control system and a data acquisition system, wherein the gas supply system is stored with hydrogen gas and provided with vacuum pumping equipment; the water supply system is stored with a water source and can measure the water amount; the high pressure visual reaction kettle is respectively connected with the gas supply system and the water supply system through pipelines and is provided with a cavity body; the agitating equipment is provided with a motor and agitating blades which are arranged in the cavity body; the temperature control system is provided with a jacket; the pressure control system is installed on the pipeline connecting the gas supply system and the high pressure visual reaction kettle and is used for regulating the pressure of hydrogen gas; and the data acquisition system comprises an electronic endoscope, a temperature sensor, a pressure sensor, a gas flowmeter, a data acquisition instrument and a computer. The device has simple structure and low cost, and can be adopted for the phase equilibrium characteristic research of a hydrogen gas hydrate and the dynamic characteristic research of the generation and decomposition processes of the hydrogen gas hydrate.
Owner:UNIV OF SHANGHAI FOR SCI & TECH

Device for evaluating foaming property of air-soluble surface active agent and application of device

The invention relates to a device for evaluating the foaming property of an air-soluble surface active agent. The device comprises an air source part, an evaluating kettle, a liquid part and an intermediate container part. The evaluating kettle in the device is internally provided with a first piston, so that the pressure of the evaluating kettle can be maintained or raised by the means that the distilled water is pumped into the evaluating kettle by a first constant-flux pump in the process of test; the pressure of the evaluating kettle can be reduced by the means that the distilled water is discharged out by the means that a first set of valves are turned on, so that the control for the pressure of the evaluating kettle can be realized, and the cloud point pressure and the cloud point temperature of the air-soluble surface active agent in supercritical carbon dioxide can be conveniently measured. Through the rotating of the evaluating kettle, the air-soluble surface active agent and the supercritical carbon dioxide can be sufficiently and evenly mixed with each other when the solubility of the air-soluble surface active agent in the supercritical carbon dioxide is measured, so that the phase equilibrium status can be achieved; and the foam regenerating property of the air-soluble surface active agent can be evaluated since the air-soluble surface active agent can float under the action of the gravitational differentiation of the evaluating kettle when the regenerating property of the air-soluble surface active agent is measured after the foam of the air-soluble surface active agent bursts.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

Method for predicting generation of hydrate in nature gas pipeline

The invention discloses a method for predicting generation of hydrate in a nature gas pipeline, and belongs to the technical field of oil-gas storage and transportation engineering. With the continuous development of Chinese economy, the consumption demand of people for natural gas is continuously increased. The technique for transporting the natural gas needs to be continuously promoted in the industrial field, but natural gas hydrate formed in the process of transporting the natural gas through pipelines is important obstruction for restricting the development of the natural gas transportation technique. The method disclosed by the invention solves the problem that selecting a pipeline position is blind when the natural gas hydrate is disposed in the past engineering. The starting point of the hydrate generated in the pipeline is found out by analyzing the pressure and the temperature of a discretionary point of the pipeline, synthetizing a pressure-temperature curve of the pipeline and contrasting the pressure-temperature curve of the pipeline and a phase equilibrium curve of the hydrate. Through adoption of the method disclosed by the invention, the place in which the hydrate is generated in the natural gas transportation pipeline can be disposed in a targeted manner, so that the use quantity of natural gas hydrate inhibitors is reduced.
Owner:LIAONING UNIVERSITY OF PETROLEUM AND CHEMICAL TECHNOLOGY

Flowing high temperature and high pressure phase equilibrium measuring device and application method thereof

The invention discloses a flowing high temperature and high pressure phase equilibrium measuring device and an application method of the flowing high temperature and high pressure phase equilibrium measuring device. The flowing high temperature and high pressure phase equilibrium measuring device comprises a feed system, an equilibrium still, a sampling system and an ultraviolet online detecting system; the equilibrium still is made from GH132 nickel base alloy to resist against a high temperature of 773K and a high pressure of 50MPa so as to obtain a stable phase equilibrium state within a large temperature and pressure range; a window is made from sapphire, so that the whole device is visible, the whole measurement process is accurate and reliable, and the phase equilibrium change process is convenient to shoot; the reasonable feed system is used for guaranteeing uniform ingredients and uniform mixing of reagents entering the equilibrium still; the reasonable sampling system is used for preventing the sampling process from affecting the phase equilibrium of the flowing system; and the ultraviolet online detecting system facilitates collection of data and is used for comparing the data with the sample data obtained by the sampling system to guarantee the accuracy and reliability of the data.
Owner:XI AN JIAOTONG UNIV

Device and method for determination of oil gas minimum miscibility pressure through magnetic resonance imaging technology

Belonging to the technical field of chemical engineering and petroleum engineering, the invention relates to a device and a method for determination of an oil gas minimum miscibility pressure through a magnetic resonance imaging technology. The device mainly comprises a magnetic resonance imaging system and a gas injection system. For the magnetic resonance imaging system, a pressure vessel is arranged in a magnetic resonance imaging instrument, a flat bottom test tube is positioned in the high pressure vessel, and the magnetic resonance imaging instrument is electrically connected to a data acquisition and processing system. The method for determining the minimum miscibility pressure of gas and oil firstly makes use of a magnetic resonance imaging technology to determine the signal strength distribution of oil in the flat bottom test tube so as to obtain a signal strength change curve of oil in gas and liquid phases within an imaging visual field under certain temperature along with the variation of pressure. By determining the intersection point of the signal strength curve and a pressure axis, the minimum miscibility pressure of gas and oil can be obtained. The method can determine the minimum miscibility pressure of gas and oil and enhance the understanding on the gas-liquid two-phase equilibrium law of gas and oil, thus being able to provide basic physical property data for underground multiphase multicomponent migration law analysis of light hydrocarbon and CO2 tertiary oil recovery.
Owner:DALIAN UNIV OF TECH

Material design method for elastic copper alloy

The invention relates to a material design method for an elastic copper alloy, and belongs to the field of material research method and technology. The method comprises the following steps: establishing a thermodynamic model of a research system by employing a calphad method to carry out phase equilibrium calculation; determining a stable phase and a phase structure of the system by employing the first principles of quantum mechanics, and calculating elastic performance of a specified component in the research system; preparing a test sample by employing a multivariate diffusion couple experimental method, and carrying out a high-resolution material performance scanning test on the test sample to obtain experimental data; carrying out comprehensive analysis and verification on the experimental and computational data, and establishing the association of alloy components, phase composition and the elastic performance of the research system; and designing the copper alloy material of specified elastic performance according to a data result and the association of the data. By adopting the method, the corresponding relation of the elastic performance of the copper alloy with the alloy components and the phase composition can be obtained quickly; and compared with the traditional design method, the purposiveness of the material design method is stronger, expenditure of manpower and material resources is reduced, and the efficiency of scientific research is improved.
Owner:GRIMAT ENG INST CO LTD

Liquefied natural gas (LNG) cold energy-driving seawater desalination device and method with double functions of vaporization and freezing

The invention discloses a liquefied natural gas (LNG) cold energy-driving seawater desalination device and method with double functions of vaporization and freezing. The operating principle of the device is based on the characteristic that the phase equilibrium pressure of water vapor decreases along with the decrease of the temperature, the cold energy of LNG is utilized to realize low temperature and vacuum, the water vapor on the surface of the raw material seawater is pumped to promote the vaporization of seawater and the endothermal effect of the vaporization process is utilized to ensure that the raw material seawater is frozen, i.e., fresh water is separated from seawater through the two phase transition processes of vaporization and freezing. The device mainly comprises a water pump, a filter, a degassing tower, an air-precooled heat exchanger, a vaporization-crystallization device, a crystallizer, a scrubbing separator, a melting device, a vacuum pump and the like. The deviceis mainly characterized in that LNG cold energy driving is adopted, gas-liquid-solid separation is performed at the triple point of seawater, and high-quality fresh water and sea icy freshwater are obtained; and the device has the advantages of cold energy cascaded utilization, higher energy efficiency, higher fresh water yield and the like. In addition, an LNG receiving station is usually built by the sea and has good geopolitical combinability with a seawater desalination project.
Owner:ZHEJIANG UNIV

Supercritical carbon dioxide experimental equipment

The invention relates to supercritical carbon dioxide experimental equipment, which comprises a carbon dioxide gas cylinder, a cold trap, a high-pressure metering pump, a gas inlet micrometering valve and a high-pressure container, wherein a gas inlet tube, a thermoelectric couple sleeve and a discharge tube penetrate through a top cover of the high-pressure container; a polytetrafluoroethylene magnetic force stirrer is arranged at the bottom of the high-pressure container, and a magnetic force stirring controller is arranged on the outer part below the high-pressure container; and the high-pressure container is arranged in a constant temperature cavity of a constant temperature device. In addition, the output end of the discharge tube is communicated to a material collector by a discharge micrometering valve. The supercritical carbon dioxide experimental equipment is suitable for a supercritical carbon dioxide extraction technology, chemical reaction in supercritical carbon dioxide, the purification of crude products in the supercritical carbon dioxide, and the measurement of phase equilibrium and melting points of solutes in the supercritical carbon dioxide. The supercritical carbon dioxide experimental equipment has the characteristic of simple structure, and is suitable for multiple supercritical carbon dioxide experiments.
Owner:DALIAN UNIV

Marine gas hydrate three-phase dynamic virtual construction method

ActiveCN109488261AOvercome the problem of three-phase changeRealize dynamic simulation effectConstructionsFluid removalLaboratory testGeothermal gradient
The invention provides a marine gas hydrate three-phase dynamic virtual construction method. According to the method, a view angle is interactively positioned by eyeball tracking, the position of an observation point is acquired by three-dimensional space geometric analysis, the pressure value and the temperature value of the observation point are acquired according to a depth pressure conversionand marine temperature field model, the physical state of a gas hydrate at the position of the observation point is judged according to a gas hydrate three-phase state judgment model built according to geothermal gradient, water temperature gradient, deep sea gas hydrate phase equilibrium curves and the like, the physical state is dynamically displayed in a three-dimensional scene, and eyeball tracking driven gas hydrate three-phase state dynamic simulation effects are achieved. Marine gas hydrate three-phase conversion virtual construction and expression are achieved, so that the stabilizingmechanism of the marine gas hydrate is visually and vividly expressed, gas hydrate three-phase virtual scenes of different sea areas can be built based on the method, and the method is widely used forthe fields of marine gas hydrate laboratory test analysis research, on-site mining simulation, teaching, popularization of science and the like.
Owner:QINGDAO INST OF MARINE GEOLOGY

Mine protection power monitoring system

InactiveCN103107602AImplement self-testConvenient manual setting adjustmentCircuit arrangementsOvervoltageCurrent transducer
The invention discloses a mine protection power monitoring system. The mine protection power monitoring system comprises a main controller terminal and a plurality of monitoring terminals, wherein the main controller terminal and the plurality of monitoring terminals are connected through a communication network. The monitoring terminals output differential signal information to the main controller terminal and receive differential signal information of the main controller terminal. The mine protection power monitoring system can be used for a mine high-voltage distribution switch and a high-voltage magnetic starter, and contains 6kV and 10kV voltage classes and 5-630A rated operational currents. Because a double-central-controller unit is used for controlling, the power monitoring system is higher in precision, more accurate, more stable in performance and faster in processing speed, and can set and calibrate in a full digitalization mode. The power monitoring system is provided with protection functions such as undervoltage, overvoltage, overload, short circuit, phase equilibrium, earth leakage protection (grounding protection) and insulation monitoring, remote metering-remote signaling-remote controlling-remote regulating functions in a form of RS485 or a controller area network (CAN) bus, a calendar clock, and a fault memorizing and searching function. A current transformer or a hollow current transformer can be selected for use without replacing current transducers for different rated current classes.
Owner:上海久创电气自动化设备有限公司

Process for concentrating titanium white waste acid through generation of crystalline hydrate by utilizing phase equilibrium principle

The invention provides a process for concentrating titanium white waste acid through generation of crystalline hydrate by utilizing the phase equilibrium principle. According to the process, ferrous sulfate, copper sulfate or other sulfate capable of forming crystalline hydrates are added into titanium white waste acid, the phase equilibrium process is controlled by utilizing the equilibrium relationship among sulfuric acid, water and sulfate, moisture is brought out by generating sulfate hydrates containing different crystal water and crystallizing and separating the sulfate hydrate from diluted sulfuric acid, and the diluted sulfuric acid can be concentrated; and the separated ferrous sulfate and other crystalline hydrates can be recycled after being dried to remove crystal water; different concentration degrees can be realized by controlling the mode of generated crystalline hydrate and can be adjusted according to requirement, and a concentrated sulfuric acid product having an acidconcentration of higher than 60 percent can be obtained; and anhydrous ferrous sulfate and other sulfates capable of forming crystalline hydrate can be utilized as raw materials, and the raw materials have wide sources. The process is simple, has low operation temperature, small equipment investment and weak corrosion, moisture of waste acid is not needed to be directly evaporated, energy consumption is low, and resource utilization of titanium white waste acid can be realized.
Owner:SICHUAN UNIV

Experimental apparatus and method for preparing natural gas hydrate rock sample via two-step process

The invention an experimental apparatus and method for preparing a natural gas hydrate rock sample via two-step process; the apparatus according to its technical scheme comprises a cold storage, a reactor, a confining pressure pump, a gas supply system, a computer data collection system and the like; all experimental systems are positioned in the low-temperature cold storage, and cold storage temperature is adjusted through a temperature control system of the cold storage; the output end of the confining pressure pump is connected with the reactor; the output end of the gas supply system is connected with the reactor; a gas flowmeter and a temperature sensor are connected with the computer data collection system. The method for preparing the natural gas hydrate rock sample via two-step process comprises the steps of first, generating hydrate in a rock sample; second, decreasing methane gas pressure to around phase equilibrium pressure but slightly higher than phase equilibrium pressure so that the hydrate is recrystallized. By using the apparatus and method, the problem in the preparation of natural gas hydrate rock samples is solved, a hydrate rock sample closer to an actual hydrate reservoir in physical mechanical characteristic can be acquired, and experimental support is provided for the drilling and development of natural gas hydrate resources.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)
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