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High temperature, oxidation-resistant abradable coatings containing microballoons and method for applying same

An abradable coating composition for use on shrouds in gas turbine engines or other hot gas path metal components exposed to high temperatures containing an initial porous coating phase created by adding an amount of inorganic microspheres, preferably alumina-ceramic microballoons, to a base metal alloy containing high Al, Cr or Ti such as β-NiAl or, alternatively, MCrAlY that serves to increase the brittle nature of the metal matrix, thereby increasing the abradability and oxidation resistance of the coating at elevated temperatures. Coatings having a total open and closed porosity of between 20% and 55% by volume due to the presence of ceramic microballoons ranging in size from about 10 microns to about 200 microns have been found to exhibit excellent abradability for applications involving turbine shroud coatings. An abradable coating thickness in the range of between 40 and 60 ml provides improved performance for turbine shrouds exposed to gas temperatures between 1380° F. and 1800° F. Abradable coatings in accordance with the invention can be used for new metal components or to repair existing equipment. The coatings can be applied to the metal shroud using thermal spray, processes that integrate sintering and brazing, or direct write techniques.
Owner:GENERAL ELECTRIC CO

Composite cementitious material of desulfurated waste residue and mortar prepared from same

The invention relates to the field of building material, and particularly discloses a composite cementitious material of desulfurated waste residue, wherein the composition of the composite cementitious material of desulfurated waste residue comprises ingredients in the following ratios by weight: 25-40% of desulfurated waste residue, 60-75% of industrial chemical gypsum, 0-20% of inorganic mineral additive and 0-2% of chemical additive. The desulfurated waste residue is at least one of dry-process desulfurated ash, wet-process desulfurated gypsum and semidry-process desulfurated ash; the inorganic mineral additive is at least one of cement, fly ash, mineral powder and steel slag; and the chemical additive is at least one of K2SO4, Al2(SO4)3 and alums. The performances such as compressive strength and tensile bond strength of the mortar prepared from the cementitious material are basically the same as the performances of cement mortar, and the mortar can achieve related standards and requirements. In the composite cementitious material of desulfurated waste residue disclosed by the invention, solid waste is efficiently utilized for preparing composite cementitious material high in performances and low in cost by burning-free treatment process and efficient excitation pre-treatment technology, so that pollution can be reduced and energy can be saved.
Owner:SHANGHAI RES INST OF BUILDING SCI CO LTD

GC method for detecting residual quantity of solvent in compound

The invention discloses a method for analyzing a residual quantity of a solvent in a compound by GC (Gas Chromatograph). The method comprises the step of carrying out separation by adopting the following chromatographic conditions: a detector is a hydrogen flame ionization detector, the temperature of the detector is 200 DEG C to 300 DEG C and is preferably 300 DEG C, and the temperature of an injection opening is 180 DEG C to 250 DEG C and is preferably 220 DEG C; a chromatographic column is a medium-polarity capillary gas chromatography column and adopts a programmed temperature process of keeping the temperature of 40 to 60 DEG C for 3 to 10min, then heating to the temperature of 100 to 140 DEG C at a speed of 5 to 15 DEG C/min, keeping the temperature of 100 to 140 DEG C for 1 to 10min, heating to the temperature of 200 to 230 DEG C at a speed of 15 to 25 DEG C/min and keeping the temperature of 200 to 230 DEG C for 1 to 20min; carrier gas is nitrogen, hydrogen or argon and is preferably nitrogen, and the flow rate of the carrier gas is 1ml/min to 10ml/min and is preferably 3ml/min; the solvent is selected from one or more of C1 to C6 carboxylic acid, methanol, ethanol, acetonitrile, ethyl acetate, tetrahydrofuran, methylbenzene and N,N-dimethylformamide; the C1 to C6 carboxylic acid is preferably C1 to C4 carboxylic acid and is more preferably acetic acid. When the method is adopted to detect the residual quantity of the solvent, the operation is simplified, time is saved and cost is saved.
Owner:NEW FOUNDER HLDG DEV LLC +2
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