Composite cementitious material of desulfurated waste residue and mortar prepared from same

A technology of desulfurization waste residue and composite gel, which is applied in cement production and other directions, can solve the problems of high energy consumption, restrict the efficient utilization of desulfurization waste residue, etc., and achieve the effects of low production energy consumption, material cost reduction, and energy saving.

Inactive Publication Date: 2012-06-27
SHANGHAI RES INST OF BUILDING SCI CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The annual discharge of desulfurization waste residue from coal-fired power plants in Shanghai can reach 2 million tons. According to the arrangement of the municipal government's "Shanghai City Desulfurization Gypsum Comprehensive Utilization and Safety Disposal Implementation Plan" Hu Fu Ban [2009] No. 56 document, about 1 million tons of desulfurization Waste slag will find a way out in the cement plant, gypsum board plant and two gypsum calcination demonstration lines, but pretreatment measures such as drying and calcination are required. The pretreatment process consumes a lot of energy, which limits the efficient use of desulfurization waste slag. The extra 100 10,000 tons of desulfurization waste residue, especially the dry desulfurization waste residue has no way of comprehensive utilization

Method used

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  • Composite cementitious material of desulfurated waste residue and mortar prepared from same
  • Composite cementitious material of desulfurated waste residue and mortar prepared from same

Examples

Experimental program
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Effect test

Embodiment 1

[0017] Be 70% industrial chemical gypsum (main component is CaSO 4 ) and 30% desulfurization waste slag are evenly mixed, and ground until the sieve residue is less than 20% (0.08mm square hole sieve), to prepare the desulfurization waste slag composite gelling material.

[0018] 25kg of the desulfurization waste slag composite cementitious material prepared above, 1kg of mortar thickening powder, and 74kg of sand were added to 15.8kg of water and stirred evenly to obtain a desulfurization waste slag mortar material.

Embodiment 2

[0020] Composition (percentage by weight) is: 70% industrial chemical gypsum (main component is CaSO 4 ), 28% of desulfurization waste slag (a mixture of dry desulfurization ash and semi-dry desulfurization ash in a weight ratio of 1:1), 1% of chemical additives (potassium sulfate, aluminum sulfate and alum in a weight ratio of 1:1:1 Ratio mixture) and mix evenly, and grind until the sieve residue is less than 20% (0.08mm square hole sieve), to prepare high-strength desulfurization waste slag composite gelling material.

[0021] 25kg of the desulfurization waste slag composite cementitious material prepared above, 1kg of mortar thickening powder, and 74kg of sand were added with 15.8% water and stirred evenly to obtain a desulfurization waste slag mortar material.

[0022] The chemical additive can also use any ratio of alum or potassium sulfate and aluminum sulfate mixture, or use alum, potassium sulfate or aluminum sulfate alone.

Embodiment 3

[0024] Composition (percentage by weight) is: 60% industrial chemical gypsum (main component is CaSO 4 ), 20% of desulfurization waste slag (the compound of wet desulfurization gypsum and dry desulfurization ash in 1:1 weight ratio), 20% of inorganic mineral additives (mixture of fly ash, cement, mineral powder and steel slag in any ratio) Mix evenly, grind until the sieve residue is less than 20% (0.08mm square hole sieve), and prepare the desulfurization waste slag composite gelling material.

[0025] 25kg of the desulfurization waste slag composite cementitious material prepared above, 1kg of mortar thickening powder, and 74kg of sand were added to 16.4kg of water and stirred evenly to obtain a desulfurization waste slag mortar material.

[0026] Inorganic mineral additives can also use fly ash, cement, mineral powder or steel slag.

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Abstract

The invention relates to the field of building material, and particularly discloses a composite cementitious material of desulfurated waste residue, wherein the composition of the composite cementitious material of desulfurated waste residue comprises ingredients in the following ratios by weight: 25-40% of desulfurated waste residue, 60-75% of industrial chemical gypsum, 0-20% of inorganic mineral additive and 0-2% of chemical additive. The desulfurated waste residue is at least one of dry-process desulfurated ash, wet-process desulfurated gypsum and semidry-process desulfurated ash; the inorganic mineral additive is at least one of cement, fly ash, mineral powder and steel slag; and the chemical additive is at least one of K2SO4, Al2(SO4)3 and alums. The performances such as compressive strength and tensile bond strength of the mortar prepared from the cementitious material are basically the same as the performances of cement mortar, and the mortar can achieve related standards and requirements. In the composite cementitious material of desulfurated waste residue disclosed by the invention, solid waste is efficiently utilized for preparing composite cementitious material high in performances and low in cost by burning-free treatment process and efficient excitation pre-treatment technology, so that pollution can be reduced and energy can be saved.

Description

technical field [0001] The invention relates to the field of building materials, in particular to a desulfurization waste slag composite gel material and a mortar material containing the material. Background technique [0002] my country is a country with coal thermal power as the main energy source. SO 2 Become one of the main causes of air pollution, so thermal power plants must implement flue gas desulfurization. Flue gas desulfurization technology can be divided into three categories: wet method, semi-dry method and dry method. With the country's emphasis on power environmental protection, especially the reduction of sulfur dioxide and air pollution, the flue gas desulfurization transformation of thermal power plants in my country has entered a high-speed growth period, resulting in a large amount of desulfurization waste residue. The annual discharge of desulfurization waste residues from Shanghai coal-fired power plants can reach 2 million tons. The waste slag will ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B11/28C04B7/26C04B28/14
CPCY02P40/10
Inventor 赵立群叶蓓红陈宁钱耀丽
Owner SHANGHAI RES INST OF BUILDING SCI CO LTD
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