Disclosed is a three electrodes
system cell for evaluation of performance of a
molten carbonate fuel cell. A lower part of the
reference electrode is fixed to a wet seal part of the single
cell without penetrating a
current collector plate and an
electrode of the single
cell. Preferably, the
reference electrode comprises cured matrix
slurry and powders of
electrolyte stacked on the matrix
slurry in the lower part thereof. Preferably, a
diameter of an
electrolyte-interchanging hole formed in a bottom of the lower part of the
reference electrode is 1ψ. Preferably, an outer
diameter of an
alumina tube in the reference
electrode is 6ψ. According to a three electrodes
system cell for evaluation of performance of a
molten carbonate fuel cell of the invention, it is possible to separately evaluate the performance of each
electrode which cannot be evaluated by the prior method of evaluating the performance of the single cell. Particularly, contrary to the prior art, it is possible to prevent a crack of the matrix due to a physical shock and a
heat shock resulting from the outflow and inflow of the supply gas, to reduce the gas leakage resulting from a decrease of
adhesive strength between the matrix and the
alumina tube and a
heat shock due to the gas leakage, to improve the problem of
electrolyte depletion and to reduce the physical defects resulting from a size of the reference electrode. Accordingly, it is possible to clearly measure the variation of the performance of each electrode while reducing the physical errors to the highest degree, to provide an exact criterion regarding the factor influencing on the variation of performance of the single cell when evaluating the performance of the single cell having 100 cm2 of large area, and to directly evaluate the performance of the
molten carbonate fuel cell.