112 results about "Vinyl halide" patented technology

Farnesene interpolymer comprises units derived from a farnesene (e.g., α-farnesene or β-farnesene) and units derived from at least one vinyl monomer. The farnesene interpolymer can be prepared by copolymerizing the farnesene and at least one vinyl monomer in the presence of a catalyst. In some embodiments, the farnesene is prepared from a sugar by using a microorganism. In other embodiments, the at least one vinyl monomer is ethylene, an α-olefin, or a substituted or unsubstituted vinyl halide, vinyl ether, acrylonitrile, acrylic ester, methacrylic ester, acrylamide or methacrylamide, or a combination thereof.

Adhesive composition comprises a polyfarnesene and a tackifier. The polyfarnesene can be a farnesene homopolymer derived from a farnesene (e.g., α-farnesene or β-farnesene) or a farnesene interpolymer derived from a farnesene and at least a vinyl monomer. In some embodiments, the at least one vinyl monomer is ethylene, an α-olefin such as styrene, or a substituted or unsubstituted vinyl halide, vinyl ether, acrylonitrile, acrylic ester, methacrylic ester, acrylamide or methacrylamide, or a combination thereof. The composition disclosed herein can be used as a hot melt adhesive, a pressure sensitive adhesive or the like.

One aspect of the present invention relates to copper-catalyzed carbon-heteroatom and carbon-carbon bond-forming methods. In certain embodiments, the present invention relates to copper-catalyzed methods of forming a carbon-sulfur bond between the sulfur atom of a thiol moiety and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. In other embodiments, the present invention relates to copper(II)-catalyzed methods of forming a carbon-nitrogen bond between the nitrogen atom of an amide and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. In certain embodiments, the present invention relates to copper-catalyzed methods of forming a carbon-carbon bond between the carbon atom of cyanide ion and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. In another embodiment, the present invention relates to a copper-catalyzed method of transforming an aryl, heteroaryl, or vinyl chloride or bromide into the corresponding aryl, heteroaryl, or vinyl iodide. Yet another embodient of the present invention relates to a tandem method, which may be practiced in a single reaction vessel, wherein the first step of the method involves the copper-catalyzed formation of an aryl, heteroaryl, or vinyl iodide from the corresponding aryl, heteroaryl, or vinyl chloride or bromide; and the second step of the method involves the copper-catalyzed formation of an aryl, heteroaryl, or vinyl nitrile, amide or sulfide from the aryl, heteroaryl, or vinyl iodide formed in the first step.

The present invention provides transition-metal-catalyst-based methods for the arylation and vinylation of activated methyl, methylene, and methine carbons with aryl halides, vinyl halides, and the like. The methods of the invention provide several improvements over existing methods, including the ability to synthesize efficiently and under mild conditions α-aryl and α-vinyl products from a wide range of starting materials, including ketones, esters, hydrazones, and imines. Furthermore, the methods of the invention may be used in an asymmetric sense, i.e. to produce enantiomerically-enriched chiral α-aryl and α-vinyl products.

Wet-rub resistant ink compositions are described and the ink compositions have a binder material or binder composition which may be prepared from monomeric precursors which include vinyl halides, acrylates, alkylol amides and urethanes.

The invention provides copolymers of ethylenically unsaturated monomers and of ethylenically functionalized nanoparticles in the form of their aqueous polymer dispersions or water-redispersible polymer powders, obtainable by means of free-radically initiated polymerization in an aqueous medium and, if desired, subsequent drying of the resultant polymer dispersion, of

A) one or more monomers from the group consisting of vinyl esters, (meth)acrylic esters, vinylaromatics, olef ins, 1,3-dienes, vinyl ethers and vinyl halides and, if desired, further monomers copolymerizable therewith, in the presence of

B) at least one particle P having an average diameter of ≦1000 nm, which is functionalized with ethylenically unsaturated, free-radically polymerizable groups, characterized in that

B2) particles P used are one or more from the group of metal oxides and semimetal oxides, and/or

B2) particles P used are silicone resins composed of repeating units of the general formula [R⁴_(p+Z)SiO_{(4−p−Z)/2}] (II), where for at least 20 mol % of the respective silicone resin p+z=0, 1 or 3,

and where B1) and B2) are each functionalized with one or more α-organosilanes of the general formula (R¹O)₃₋(R²)_nSi—(CR³₂)—X (I), where X is a radical having 2 to 20 hydrocarbon atoms and containing an ethylenically unsaturated group.

Gypsum plaster compositions with improved adhesion to plastic surfaces and metal surfaces comprise from 10 to 90% by weight of gypsum plaster, based on the total weight of the composition, and also, where appropriate, other additives, and a combination of: a) one or more water-redispersible polymer powders based on one or more vinyl ester, (meth)acrylate, vinylaromatic, olefin, 1,3-diene, or vinyl halides monomers, and optionally other monomers copolymerizable therewith; and b) one or more alkali metal and/or alkaline earth metal salts of short-chain fatty acids having from 1 to 4 carbon atoms in the hydrocarbon skeleton and from 1 to 4 carboxy groups, and which contain no OH groups.

This invention discloses a process for synthesizing an amine functionalized monomer that comprises (1) reacting a secondary amine with a 2,3-dihalopropene to produce a vinyl halide containing secondary amine having a structural formula selected from the group consisting of

wherein R and R′ can be the same or different and represent allyl, alkoxyl or alkyl groups containing from 1 to about 10 carbon atoms, and wherein X represents a halogen atom, and wherein m represents an integer from 4 to about 10, and wherein X represents a halogen atom; and (2) reacting the vinyl halide containing secondary amine with a vinyl magnesium halide to produce the monomer having a structural formula

wherein R and R′ can be the same or different and represent alkyl, allyl or alkoxyl groups containing from 1 to about 10 carbon atoms, and wherein m represents an integer from about 4 to about 10.

The heat and light stability imparted to vinyl halide polymers by metal compounds conventionally employed for this purpose is considerably improved by the presence of a mercapto ester such as 2-mercaptoethyl stearate. The esters can replace a substantial portion of the metal compound with no significant reduction in stability.

Disclosed is a laminar shaped article comprising a heterogeneous blend of (a) a composition comprising a vinyl halide or vinylidene halide polymer and optionally an ethylene copolymer containing carboxyl and/or carbon monoxide moieties, and (b) a polyolefin functionalized with a comonomer selected from the group consisting of maleic anhydride, maleic acid diesters, maleic acid monoesters, itaconic anhydride, itaconic acid diesters, itaconic acid monoesters, fumaric acid diesters, fumaric acid monoesters, or combinations thereof as a compatibilizer; and (c) a polyamide wherein the polyamide is present in the vinyl halide or vinylidene halide polymer as a multitude of overlapping layers.

A method of making a finely textured molded article is disclosed. The method utilizes properties of the compound being molded, such as impact toughness and melt flow index. Poly(vinyl halide), particularly poly(vinyl chloride), articles an be compound-injection-molded using the method, in order to simulate the appearance of original metal, glass, or wood articles. Consumer, transportation, building construction, and other industries can benefit from durable plastic articles that simulate the more fragile articles.

Hydrophobicizing additives are water-redispersible powders or aqueous dispersions containing:

• • a) water-insoluble, film-forming base polymer(s) based on homopolymers or copolymers of one or more vinyl esters of optionally branched C_1-15 alkylcarboxylic, (meth)acrylic esters of C_1-15 alcohols, vinylaromatics, olefins, dienes and vinyl halides,
  • b) one or more hydrophobic organosilicon compounds, fatty acids, or derivatives thereof, or hydrocarbon waxes, and
  • c) one or more protective colloids,

wherein the proportion of the component b) based on the total weight of the component a) is more than 30% by weight.

Use of a blend of phthalate plasticizers is disclosed for flexible polyvinyl chloride compounds. The blend of plasticizers permits the compounds to achieve a 90° C. or higher ratings for usage in wire and cable articles.

This invention relates to a tread rubber composition for tires with the addition of crosslinked resinous nanoparticles having a high glass transition temperature (T_g) into elastomeric base polymers. The invention demonstrates greatly improved handling performance without deteriorating controllability and stability during high-speed running. The present invention more specifically discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads; wherein said tread is adapted to be ground-contacting; and wherein the tread is comprised of a rubber composition comprising: (1) a rubbery polymer; (2) from 1 to 30 parts per hundred parts of rubber by weight of pre-crosslinked polymer particles, wherein the pre-crosslinked polymer particles have a mean number average particle size as determined by light scattering which is within the range of 30 nm to 500 nm, wherein the pre-crosslinked polymer is comprised of repeat units that are derived from at least one monomer selected from the group consisting of acrylate monomers, acrylonitrile monomer, and vinyl halide monomers, wherein the pre-croslinked polymer is in the form of core-shell particles having a core and a shell, and wherein the pre-crosslinked polymer has a glass transition temperature which is within the range of 30° C. to 200° C.; and (3) 10 to 150 parts per hundred parts of rubber by weight of at least one filler selected from the group consisting of carbon black and silica.

The invention relates to a process for the preparation of polymers stabilized with protective colloids in the form of water-redispersible powders or aqueous dispersions thereof having a reduced content of volatile components, by a) polymerizing by emulsion or suspension polymerization, one or more monomers from the group consisting of vinyl esters, (meth)acrylates, vinyl aromatics, olefins, 1,3-dienes and vinyl halides and optionally further monomers copolymerizable therewith, b) aftertreating the polymer dispersion thus obtained by means of postpolymerization, distillation, and/or introduction of steam or inert gas to obtain a residual content of volatile, nonaqueous components of <2000 ppm, and c) spray drying of aftertreated polymer dispersion to a residual content of volatile, nonaqueous components of <400 ppm, the dispersion being adjusted prior to spray drying to a solids content of <45% by weight before spraying, the spray drying performed with gas at an inlet temperature of >120° C., and optimally d) redispersing of the resulting powder in water.