The invention discloses a processing technology of modified carbon fibers. The processing technology comprises the following steps of a, filament return and thread collection, wherein a protofilamentis selected, after splitting, a new filament and an old filament are connected with a heat-resistant fiber, and the mixture is erected on a thread collection plate; b, primary drying, wherein the thread collection plate and the protofilament are conveyed into a drying device for drying, and the moisture in the protofilament is removed; c, preoxidation; d, carbonization; e, electrolytic oxidation modification; f, soaking modification. The processing technology has the advantages that an electrolytic oxidation mode is adopted for modifying the surfaces of the carbon fibers, active functional groups are introduced into the surfaces of the carbon fibers, the carbon oxygen bonds of the surfaces of the carbon fibers are increased, the contact compactness of the carbon fibers and the surface of acomposite material in the compounding process is improved, and the increase and decrease shearing strength of the synthesized composite material is improved; the interface bonding force of a bondingface is improved, and accordingly the tensile strength and impact-resistance strength of the carbon fiber and resin base material composite material is improved.