155 results about "Benzole" patented technology

The invention relates to the technical field of reaction kettles, and discloses a reaction kettle device for synthesizing benzohydroxamic acid, the reaction kettle device comprises a reaction kettle body and a stirring structure arranged at the top of the reaction kettle body, a discharging pipe is arranged at the discharging end of the reaction kettle body, and supporting legs are arranged on the outer wall of the bottom of the reaction kettle body; three mounting plates distributed in an annular array are fixedly mounted on the inner wall of the reaction kettle body, a driving screw rod is rotationally mounted on the top surface of each mounting plate, the top end of each driving screw rod penetrates through the top surface of the reaction kettle body, and a guide frame is in threaded connection with the outer wall of each driving screw rod; when the feeding cylinder rotates, the transmission shaft is in intermittent contact with the protruding block, negative pressure adsorption and quantitative discharge of auxiliary materials are achieved through vertical sliding of the piston plate and cooperation of the one-way valve, it is guaranteed that raw materials can be accurately injected according to needs through the structural design, errors caused by manual control adding are avoided, the accuracy of the reaction proportion is guaranteed, and the production efficiency is improved. And the product quality stability can be improved.

The invention relates to the technical field of nano-composite water-based resin system design and function coordinated regulation and control, in particular to environment-friendly high-gloss wear-resistant water-based epoxy floor paint and a preparation method thereof. The environment-friendly high-gloss wear-resistant water-based epoxy floor paint is prepared from self-emulsifying water-based epoxy resin emulsion, a modified water-based epoxy curing agent containing biguanidyl and the like; the preparation method comprises the following steps: carrying out synergistic modification on a three-dimensional composite wear-resistant filler containing nano silicon dioxide-carbon nanotube-graphene through a silane coupling agent and dopamine; the light response type composite light stabilizer is compounded by a titanium dioxide grafted hindered amine light stabilizer and a benzophenone light stabilizer; a phase change temperature adjusting microcapsule and a nano-silver-chitosan antibacterial agent can also be added, so that multiple functions are realized. According to the floor paint disclosed by the invention, through an innovative formula and process, wear resistance, luster and weather resistance are remarkably improved, and toughness and crack resistance are enhanced; and the preparation method is environment-friendly and efficient, meets the requirements of multiple scenes, and has high economic value.

The application belongs to the technical field of cable materials, and discloses a cold-resistant and anti-cracking type special cable made of silicone rubber, which comprises a conductor cable core, an inner protective sleeve and an outer protective sleeve from inside to outside, wherein the raw materials of the outer protective sleeve comprise end-vinyl diphenyl siloxane, methyl vinyl siloxane, silane modified nano silicon dioxide, polyborosiloxane, an inhibitor, hydroxyl silicone oil, modified anti-ultraviolet polyurethane, a platinum catalyst and tetra(dimethylsiloxane) silane; diphenyl siloxane with a diphenyl side chain is selected as a main chain, and the modified anti-ultraviolet polyurethane is grafted to effectively destroy the structural regularity, inhibit low-temperature crystallization and prevent cable cracking; 4,4'-diamino benzophenone with anti-ultraviolet function is used as a chain extender and benzotriazole is used as an end-capping agent to be grafted into the polyurethane chain, so that the anti-ultraviolet capacity can be improved and migration can be avoided.

The invention relates to the technical field of transportation, and discloses a benzohydroxamic acid production raw material continuous and accurate conveying device which comprises two cases and a conveying pipeline connected between the cases, a chain running circularly is arranged in the conveying pipeline, a plurality of discs are installed on the chain at intervals, and a feeding port and a plurality of discharging assemblies are arranged on the conveying pipeline. The discharging assembly comprises two connecting pipes used for being connected with the conveying pipeline. The discharging pipe is fixedly mounted on the two connecting pipes; the two connecting semi-rings are mounted in the discharging pipe in a sliding manner; the first permanent magnet is fixedly mounted on the connecting half ring; according to the continuous and accurate conveying device for the benzohydroxamic acid production raw materials, the first electromagnet is externally arranged on the discharging pipe, opening and closing of a connecting semi-ring are remotely controlled through magnetic force, a mechanical transmission part does not need to penetrate through the pipe wall, the discharging pipe is kept totally closed, even if the first electromagnet is overhauled, the air tightness of the interior of the discharging pipe cannot be affected, and the service life of the discharging pipe is prolonged. And moisture invasion is avoided.

The invention relates to the technical field of ketone processing, in particular to a multifunctional treatment box for synthesizing 2-fluoro-benzophenone.The multifunctional treatment box comprises a processing treatment box, and a plurality of sets of processing treatment cavities used for synthesizing 2-fluoro-benzophenone are arranged in the processing treatment box from top to bottom; the processing treatment cavity comprises a mixing and dissolving reaction cavity which moves up and down along the upper side area in the processing treatment box, and a contact heating cavity and a water bath cooling cavity which are fixed in the processing treatment box are separately arranged on the upper side and the lower side of the mixing and dissolving reaction cavity at intervals; the bottom of the water bath cooling cavity is communicated with a washing cavity for washing the cooled solution in a pressing manner, the bottom of the washing cavity is communicated with a separation cavity for separating the washed solution, and the bottom end of the separation cavity is communicated with a concentration cavity for rotationally evaporating the separated solution in a control manner; the bottom end of the concentration cavity is communicated with a purification cavity in an automatic detection opening and closing manner. The treatment box can be used for automatically processing ketone in an energy-saving manner, and meanwhile, the low-cost operation is kept.

This invention discloses a high-efficiency mixing device for materials in a benzoyl hydroxamic acid reactor, belonging to the field of material mixing and reaction technology. It includes a support base and a reactor body connected to it via a support frame. The upper end of the reactor body has a feed inlet, and the lower end has a discharge outlet. A valve for controlling the opening and closing of the discharge outlet is installed. A servo motor is mounted on the upper end of the reactor body via a motor frame, and a shaft tube is installed on the drive end of the servo motor. This invention not only achieves transverse stirring by synchronously rotating the shaft tube and the stirring tube, but also changes the radius of transverse stirring, thereby improving stirring efficiency. Furthermore, it achieves longitudinal stirring through the rotation of the gas-dispersing impeller, further enhancing stirring efficiency. Simultaneously, during the stirring process, an inert gas at a certain temperature can be introduced into the reactor, thereby changing the reaction temperature within the reactor and contributing to improving the efficiency and effectiveness of the benzoyl hydroxamic acid synthesis reaction.

The utility model discloses a rectification device for producing m-chlorobenzoyl chloride, which comprises a lower tower body, a support ring plate connected with the inner wall of the bottom of the lower tower body, a spring arranged at the top of the support ring plate, a movable ring plate connected with the top end of the spring and capable of sliding up and down along the inner wall of the lower tower body, and a tower plate, the two tower plates are mounted in the supporting annular plate and the movable annular plate, and the adjusting assembly is connected with the inner wall of the lower tower body, located above the movable annular plate and used for adjusting the distance between the two tower plates. According to the utility model, the shifting plate is shifted forwards or reversely, so that the middle tower body rotates synchronously, and the pressing rod is screwed out downwards or screwed in upwards under the transmission of the inner gear ring, the gear and the rotating rod, so that the distance between the two tower plates is controllable, the tower plates can adapt to process conditions with different loads, the separation effect of benzoyl chloride is ensured, the rectification effect is greatly enhanced, and the production efficiency is improved. Therefore, the production efficiency of the m-chlorobenzoyl chloride is indirectly improved.

This invention discloses a flame-retardant and anti-aging cable composite material and its preparation method, belonging to the field of cable material preparation technology. In this invention, a flame-retardant, high-temperature resistant polysiloxane containing double bonds, an anti-aging agent, and a flame-retardant filler are prepared and blended with raw materials such as EVA and low-density polyethylene. Irradiation causes cross-linking between the materials, endowing the composite material with heat resistance, aging resistance, and good mechanical properties. The anti-aging agent of this invention includes siloxane groups and benzophenone groups, possessing good resistance to both UV aging and heat aging, which is beneficial for further improving the anti-aging performance of the prepared cable composite material. The flame-retardant filler of this invention has urethane bonds grafted onto its surface, which matches the polarity of the EVA vinyl acetate segments, improving the compatibility between the flame-retardant filler and EVA, and further enhancing the flame retardancy of the prepared composite cable material.

A sulfur-containing aromatic acrylate compound, its preparation method, and its applications are disclosed. The compound has a structure as shown in general formula (A), which integrates acrylate, benzophenone, and thioether functional groups in its molecular structure, adapting to the application requirements of various optical material raw materials. This invention also provides an efficient preparation process for this compound. Optical materials prepared using this compound as a monomer exhibit excellent aging resistance and anti-yellowing properties, as well as outstanding mechanical properties. Wherein, R1=CH2=CH-COO; R2=CH3; n=2 or 3, m=0, 1, or 2.

The invention relates to the field of coatings, and discloses a high-temperature-resistant protective coating for an alloy surface and a preparation method of the high-temperature-resistant protective coating. The protective coating is prepared from waterborne epoxy resin, high-temperature-resistant filler, cardanol-based modified benzoxazine resin, a hyperbranched modifier, a curing agent and auxiliaries; according to the cardanol-based modified benzoxazine resin, paraformaldehyde is utilized to introduce an aldehyde group into a hydrogenated cardanol matrix to prepare a cardanol-based aldehyde-containing intermediate, then the cardanol-based aldehyde-containing intermediate reacts with 1, 5-naphthalene diamine, and then the cardanol-based aldehyde-containing intermediate reacts with gamma-aminopropyltriethoxysilane and paraformaldehyde through Mannich reaction to prepare the cardanol-based modified benzoxazine resin. The hyperbranched modifier is prepared by carrying out addition on 2, 4-dihydroxybenzophenone and isocyanatopropyltriethoxysilane, initiating hydrolytic condensation by utilizing a sol-gel method and then introducing triglycidyl isocyanurate to carry out a ring-opening reaction, and the protective coating prepared by the preparation method is strong in adhesive force, high in mechanical strength, good in wear resistance, good in wear resistance, good in wear resistance and good in wear resistance. Meanwhile, good corrosion resistance, high temperature resistance, ultraviolet aging resistance and flame retardance are achieved.

The invention belongs to the technical field of wolframite flotation tailing sedimentation, and particularly relates to a wolframite tailing pulp treatment method which comprises the following steps that when the temperature is larger than or equal to 10 DEG C, a polyaluminum chloride solution is prepared; when the temperature is greater than or equal to 15 DEG C, preparing a polyacrylamide solution; then adding the polyaluminum chloride solution into the wolframite tailing pulp with the benzhydroxamic acid concentration of (5 + x) mg / L, uniformly stirring, then adding the polyacrylamide solution, uniformly stirring, and then carrying out flocculating settling; wherein the adding amount of the polyaluminum chloride in each cubic meter of the wolframite tailing pulp is (150 + 10x) g, the adding amount of the polyacrylamide in each cubic meter of the wolframite tailing pulp is (70 + 2x) g, and x is more than or equal to 0 and less than or equal to 5. According to the technical scheme, the dosage of the flocculating agent can be effectively reduced, and the tailing pulp treatment cost is reduced; loss of wolframite metal products during recycling of overflow water is effectively reduced; the settling rate of suspended matters is obviously improved, the content of the suspended matters in the overflow water is effectively reduced, and the muddy flow of the thickening pool is avoided.

The invention relates to a casting type polyurethane elastomer vibration and noise reduction material for a railway elastic sleeper. Belongs to the technical field of polymer materials. The preparation raw materials are as follows: polyether polyol and diphenylmethane diisocyanate (MDI) or toluene diisocynate (TDI) are used as main reaction raw materials; micromolecular dihydric alcohol or diamine is used as a chain extender; a hindered phenol antioxidant or a phosphite ester antioxidant; a benzotriazole ultraviolet light absorber or a benzophenone ultraviolet light absorber; an organic silicon auxiliary agent; and a nano-scale inorganic filler. The material disclosed by the invention has excellent vibration and noise reduction performance, can meet the requirements that the rigidity range is 100-400KN / mm and the tensile strength is greater than 12MPa, and also has good anti-aging performance and anti-fatigue performance; the stability and the uniformity of the product quality are ensured; and rapid curing can be achieved, and the requirement for high efficiency of site construction is met.

The invention discloses a benzophenone photoinitiator. The structure of the benzophenone photoinitiator is shown as a formula (I) or a formula (II): (I) and (II), wherein Rn is single substitution or multi-substitution on a benzene ring, and Rn is selected from one of hydrogen atom, alkyl, N-alkyl, O-alkyl, S-alkyl, Se-alkyl, Si-alkyl, aromatic ring group and acyloxy. The photoinitiator not only has a benzophenone structure, but also has a part of thioxanthone structure, so that compared with traditional benzophenone photoinitiators and thioxanthone photoinitiators, the photoinitiator is more excellent in ultraviolet absorptivity, photo-initiation efficiency, solubility and the like, is more environment-friendly, is wider in application range, and can be widely applied to the field of photoinitiators. The raw materials are easy to obtain, the production cost is low, and industrial production and application are facilitated.

The application provides a wear-resistant enameled copper wire and a preparation method thereof, and belongs to the technical field of enameled copper wires.The preparation method comprises the following steps: repeatedly coating wear-resistant paint on a copper wire and curing the wear-resistant paint into a paint film, and then cooling and winding the copper wire to obtain the wear-resistant enameled copper wire.The preparation method of the wear-resistant paint comprises the following steps: adding 4,4'-diamino-4"-hydroxytriphenylmethane and 2,2-bis-[4-(4-aminophenoxy)phenyl]propane into a polymerization bottle, adding N,N-dimethylacetamide, stirring and dissolving, adding 3,3',4,4'-benzophenonetetracarboxylic dianhydride, stirring and polymerizing, and obtaining a polyamic acid solution one; adding 4,4'-diamino diphenyl ether into the polymerization bottle, adding N,N-dimethylacetamide, stirring and dissolving, adding pyromellitic dianhydride, stirring and polymerizing, and obtaining a polyamic acid solution two; adding the polyamic acid solution one and the polyamic acid solution two into the polymerization bottle, adding a silane coupling agent, stirring, adding N,N-dimethylacetamide and a peroxide initiator, and stirring uniformly to obtain the wear-resistant paint; and the wear resistance of the wear-resistant enameled copper wire can be effectively improved.

The application discloses a preparation method of dibenzoyl peroxide, and relates to the technical field of organic peroxide preparation. The preparation method comprises the following steps: preparing dibenzoyl peroxide crude product and initial synthesis obtained recycling mother liquor; taking out two parts from the initial synthesis obtained recycling mother liquor, and reacting with a sodium hydroxide solution, hydrogen peroxide, a surfactant aqueous solution and benzoyl chloride; at least the benzoyl chloride is contained in the multiple materials, and the multiple materials are pre-mixed by a pre-mixer; heat preservation reaction is carried out, and after the reaction is completed, centrifugal separation is carried out to obtain the dibenzoyl peroxide crude product and second synthesis obtained recycling mother liquor; and the dibenzoyl peroxide crude product is sequentially subjected to water washing and solid-liquid separation to obtain a finished product. The pre-mixer is used to realize instant super-uniform mixing of the materials, the reaction is more uniform, the product is fine and small in particle size, the particle size distribution is uniform, the reaction yield is high, the amount of water used for subsequent washing is reduced, the recycling of the mother liquor reduces the discharge amount of high-salinity organic waste liquid from the source, and the preparation cost is reduced.

This invention discloses a method for preparing a series of bismaleimide products, relating to the field of high-performance thermosetting resin monomer synthesis technology. The method includes a pre-reaction of maleic anhydride and aromatic diamine at a molar ratio of 2.0–2.2:1 under nitrogen protection at 60–90°C. The resulting amic acid intermediate is pumped into a twin-screw extruder. Irradiation is performed in the vacuum dehydration ring-closing zone (or imidization zone) using a 365 nm UV LED array, coupled with a 0.3–1.0 wt% benzophenone / triethanolamine photoinitiator system. The ring-closing reaction is completed at 110±5°C and a vacuum of -0.090 to -0.098 MPa, with a total residence time of 30–90 seconds, yielding bismaleimide products with an acid value ≤0.1 mg KOH / g and a ring closure degree ≥98.5%. Rapid product switching for a series of products can be achieved by changing different aromatic diamines. This invention eliminates the use of organic solvents, reduces energy consumption by more than 55%, and has a batch-to-batch acid value variation coefficient of less than 2%, meeting the requirements of electronic-grade packaging materials. Furthermore, the process conditions are fundamentally different from existing technologies, demonstrating significant technological advancements.

The invention belongs to the field of superhigh-temperature ceramic materials, and particularly relates to a hafnium carbide precursor and a preparation method thereof.The preparation method comprises the steps that n-propyl alcohol hafnium and two special modified compounds are mixed in an inert atmosphere, dicumyl peroxide, benzophenone, triethanolamine and divinyl benzene are added for stirring, and the hafnium carbide precursor is obtained; adding tetrahydrofuran, stirring at a constant temperature to form a homogeneous solution, and finally filtering to obtain a precursor; the two modified compounds are vinyl tris (diethylamino) hafnium and acryloyloxy dibenzoyl hafnium complexes respectively, and the preparation method is realized through substitution reaction of hafnium tetrachloride and amine compounds and coordination reaction of n-propanol hafnium, dibenzoylmethane and acryloyl chloride respectively. The obtained hafnium carbide precursor contains a hafnium source, a modified compound, a cross-linking agent and a solvent, through molecular design, the ceramic yield is remarkably increased, the cracking temperature is reduced, the oxidation resistance and sintering density of final ceramic are improved, and the preparation method is suitable for preparing an ultra-high-temperature ceramic material.

The invention discloses a method for determining the content of semicarbazide in a plastic product, and belongs to the technical field of analytical testing, the method is a spectrophotometric method, and the method specifically comprises the following steps: firstly, carrying out derivatization treatment by adopting benzoyl chloride, and then carrying out absorbance detection at 280nm; compared with a liquid chromatography-mass spectrometry method, the method is faster and more efficient in detection and suitable for rapid detection occasions and checkout rooms with low investment cost requirements, the lowest detection capacity of the method is 0.1 mg / L, most quantitative requirements are met, the pretreatment process is simple, the derivation time is short, the operation process is easy to master, and the method is suitable for industrial production. And the result can be obtained only in about 10 minutes in the conventional detection, so that the timeliness and the safety are very high.

The invention provides a synthetic method of a tazobactam intermediate debrominated sulfoxide ester. According to the method, 6-APA is taken as an initial raw material, the 6-APA is prepared through a bromination-(esterification-oxidation)-debromination three-step synthesis reaction one-pot method, acid-catalyst-sodium hypochlorite-benzophenone hydrazone combination is used in the esterification-oxidation step to realize the one-pot reaction, and meanwhile, a hazardous chemical substance peracetic acid is removed. In the debromination step, a combination of illumination, a catalyst and ascorbic acid is adopted to replace zinc powder. Compared with the traditional process, the method has the advantages that the production process is simplified, the safety is better, the molar yield is increased by 13% or above, and the method is suitable for industrial production.

The application relates to a preparation method of a mesotrione intermediate. S1, 3-chloro-2-methyl aniline, hydrochloric acid and pure water are placed in a reaction kettle, stirring, cooling, dropwise addition of a NaNO2 solution, after dropwise addition is completed, temperature control is carried out, CH3SNa aqueous solution is added, after dropwise addition is completed, slow temperature rising is carried out, and reaction is continuously carried out for 8 hours; extraction, water washing and distillation are sequentially carried out, and 1-chloro-2-methyl benzyl sulfide is obtained; S2, under the atmosphere of nitrogen, formylation reagent is added into a reaction kettle under the condition of 0-10 DEG C, a catalyst is dropwise added and stirring is carried out, 1-chloro-2-methyl benzyl sulfide is dropwise added, temperature rising is carried out, and 2-chloro-3-methyl-4-methylthio benzaldehyde is obtained through post-treatment; S3, under the atmosphere of nitrogen, methanol, 2-chloro-3-methyl-4-methylthio benzaldehyde and sodium tungstate dihydrate are added into a reaction kettle, hydrogen peroxide is dropwise added, the reaction temperature is controlled, and reaction is carried out, and the mesotrione intermediate is obtained through post-treatment.

The application belongs to the technical field of organic synthesis, and particularly relates to a preparation method of maropintan and an intermediate thereof. The preparation method comprises the following steps: S1: 3-quinuclidinone or a salt thereof is reacted with benzophenone under the condition of a base, a first solvent, to obtain 2-(diphenyl methylene) quinuclidin-3-one; S2: the obtained 2-(diphenyl methylene) quinuclidin-3-one is reacted with an amine source and hydrogen under the condition of a chiral ruthenium catalyst, an optional additive and a second solvent, to obtain an intermediate (2S, 3S)-2-diphenyl methyl quinuclidin-3-amine; and S3: the obtained (2S, 3S)-2-diphenyl methyl quinuclidin-3-amine is subjected to a condensation reaction with 5-tert-butyl-2-methoxy benzaldehyde (formula V) in the presence of an acid and a third solvent, and is reduced by palladium carbon or platinum carbon and hydrogen to obtain maropintan. The method has the advantages of low-cost and easily-available raw materials, a short synthesis route, high-yield one-step reaction of double chiral centers, good selectivity, simple process, high product yield and low cost.

The utility model discloses an intermediate material heating device for benzoyl chloride production, which comprises a water bath, and a first valve and a second valve are arranged at the side end of the water bath; the heating tank is communicated with the water bath, and a third valve is arranged between the heating tank and the water bath; the input end of the hot water circulating pump is communicated with the water bath, a fourth valve is arranged between the hot water circulating pump and the water bath, the output end of the hot water circulating pump is communicated with the heating tank, and a fifth valve is arranged between the hot water circulating pump and the heating tank. Through actual production test comparison, after water bath heating, the purity of the benzoyl chloride intermediate can be remarkably improved, for example, when steam heating is adopted originally, the product melting rate is stabilized at 80%, 20% is forced to be lost due to the reaction of hot water and materials, and the loss can be completely eradicated by melting materials at the same temperature after water bath heating.

The invention discloses a synthesis method of hydrogen isotope labeled vortioxetine. The synthesis method comprises four steps of reaction: construction of diaryl sulfide, selective deuteration of methyl, selective reduction of cyano and coupling reaction of carbon-nitrogen bonds. According to the key step, deuterated dimethyl sulfoxide is used as a deuterium source under the catalysis of a methyl selective deuterated alkali metal catalyst, and methyl deuterated dimethyl sulfoxide and a methyl benzene intermediate are selectively subjected to a methyl deuterated reaction. The method effectively avoids the harsh condition of low temperature for introducing a deuterated methyl scheme after aryl halogenated hydrocarbon lithium halide exchange and deuterated iodomethane reaction, avoids the generation of dehalogenation byproducts, and overcomes the defects that the product is difficult to purify, the reaction is difficult to amplify and produce and the like. The key step of the invention adopts a specific alkali metal salt as a catalyst to carry out methyl deuteration reaction, and combines cyanobenzene to selectively reduce and construct another methyl, so the method has the remarkable advantages of low cost, environmental protection, simple process and suitability for industrial production.

This invention relates to the field of organic synthesis technology, specifically a method for synthesizing 2-chloro-4-(1H-pyrazol-3-yl)benzonitrile and its application, comprising the following steps: S1. Compound 1a is added to a first organic solvent under inert gas protection and reacted with vinyl isobutyl ether under the conditions of a catalyst and potassium carbonate to obtain a system containing compound 2a; S2. The pH of the system containing compound 2a obtained in step S1 is adjusted to 2-3, and after reaction, compound 1 is obtained through post-treatment; S3. Compound 1 is added to a second organic solvent, and ethyl formate and sodium ethoxide are added to react and obtain a system containing compound 4a; S4. Acetic acid is added to the system containing compound 4a obtained in step S3 for neutralization, and under inert gas protection, hydrazine hydrate is added dropwise to react and the product is obtained through post-treatment. The synthesis method provided by this invention uses readily available raw materials, has a simple processing procedure, does not require column chromatography, simplifies the operation, and facilitates industrial-scale production.

The application discloses an anti-aging and yellowing-resistant foamed polyester material and a preparation method thereof, and relates to the technical field of polyester materials. The anti-aging and yellowing-resistant foamed polyester material is prepared from the following raw material components in proportion by weight: 3-5 parts of anti-ultraviolet SEBS, 3.6-7 parts of triethylamine, 4-6 parts of a flame-retardant and wear-resistant filler, 100 parts of TPEE, 0.9-1.1 parts of a polymer wax, and 0.6-0.8 parts of a foaming agent. The anti-ultraviolet SEBS is obtained by copolymerization grafting of an unsaturated benzophenone ultraviolet absorber, SEBS and maleic anhydride. The flame-retardant and wear-resistant filler is obtained by mixing and reacting carboxylated nano silicon dioxide, pentaerythritol and phosphorus oxychloride. The polymer wax is EVA wax. The foaming agent is azodicarbonamide. The anti-aging and yellowing-resistant foamed polyester material has good mechanical properties, anti-aging performance, flame-retardant performance and compression resistance.

This invention relates to the field of long-lasting reflective road marking coating technology, and discloses a functional coating for long-lasting reflective road marking and its preparation method. The coating, by weight, comprises the following raw materials: 40-60 parts polyacrylic acid resin emulsion, 1-3 parts defoamer, 3-5 parts modified nano-silicon carbide, 1-3 parts modified glass microspheres, 4-10 parts filler, 1-3 parts curing agent, 2-5 parts dispersant, and 30-35 parts deionized water. The nano-silicon carbide is modified with maleic anhydride and then grafted with polyphenylene ether. The polyphenylene ether improves the interfacial compatibility between the nano-silicon carbide and the matrix, promotes uniform dispersion of the nano-silicon carbide, and inhibits agglomeration, significantly improving the coating's wear resistance and impact resistance. The benzophenone structure is grafted onto the glass microspheres using a silane coupling agent, achieving a high-density directional distribution of ultraviolet-absorbing groups. This maintains the coating's transparency, while the surface graft layer inhibits photo-oxidation chain reactions, significantly improving the coating's anti-aging ability.

The invention provides a preparation method of 4, 4 '-difluorobenzophenone, which comprises the following steps: uniformly mixing carbon tetrachloride and lewis acid, adding fluorobenzene in an inert gas atmosphere at-30-25 DEG C, stirring and reacting for 8-24 hours, and post-treating the obtained reaction liquid to obtain the 4, 4'-difluorobenzophenone, the method is simple in reaction process, mild in condition and convenient to operate, a high-risk strong oxidant is not needed in the whole reaction process, strong acid with strong irritation and corrosivity is prevented from being used, generation of pollution gas is reduced, the synthesis efficiency is high, and the total yield reaches up to 93%.

The present invention provides an improved process for the preparation of benzonitrile compounds More particularly, the present invention relates to an improved process for the preparation of benzonitrile compounds of Formula (I) by nitrilation of the corresponding benzotrichloride compounds of Formula (II).

This invention relates to the field of high-performance polypropylene materials technology, specifically to a biodegradable foamed polypropylene composite material and its preparation method. The invention aims to solve the problem of the inability to simultaneously achieve both mechanical and degradation performance in existing polypropylene composite materials. This invention uses modified polypropylene obtained by modifying polypropylene materials with high-density polyethylene and low-density polyethylene as the matrix material; maleic anhydride-grafted polypropylene as a compatibilizer; modified nano-silica; degradation aids obtained by melt extrusion of PBAT, ferric stearate, and benzophenone; and sulfonated lignin. Finally, a stepwise melt blending process is employed, combined with a dual foaming technology of chemical foaming agent and supercritical carbon dioxide, to obtain a polypropylene-based composite material. The resulting material exhibits excellent mechanical properties while possessing a highly efficient and controllable degradation rate, achieving a synergistic improvement in both mechanical and degradation performance.