Preparation method of composite antistatic agent for fiber fabric

A composite antistatic agent and antistatic agent technology, which is applied in fiber treatment, textiles and papermaking, etc., can solve problems such as increased friction coefficient, poor fiber adsorption, and poor antistatic effect, and achieves improved surface conductivity and excellent antistatic properties. Effects of electrostatic properties and good high temperature resistance

Inactive Publication Date: 2015-06-24
SUZHOU CHENHENG WEAVING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Among the currently used antistatic agents, although the cationic antistatic agent has good antistatic effect, its main nitrogen-containing compound is easy to change color in high temperature environment, which affects the dyeing of fibers and fabrics; the antistatic effect of anionic antistatic agent is also low. It is very ideal, but the sulfate ester salt is not stable to oxygen and heat; non-ionic antistatic agent is less toxic than ionic antistatic agent, it is irritating to the skin, and has emulsifying and wetting effects, but its effect on Fiber adsorption is poor and cannot be ionized by itself, so the antistatic effect is poor; organic silicon antistatic agent has outstanding antistatic effect, but it has more residues after thermal decomposition under high temperature and high speed friction, which is easy to form white powder; organic Fluorine-type antistatic agents are rarely used due to their high price; the aqueous solution of polymer-type antistatic agents has a high viscosity, which tends to increase the friction coefficient during high-speed spinning, which is not conducive to preventing the generation of static electricity

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] This embodiment provides a method for preparing a composite antistatic agent for fiber fabrics. In the preparation method, the composite antistatic agent for fiber fabrics includes the following components in parts by mass:

[0046]Butanol phosphate antistatic agent: 40 parts, hydroxyl-terminated hyperbranched antistatic agent: 8 parts, carboxyl-terminated hyperbranched antistatic agent: 15 parts, quaternary ammonium salt-terminated hyperbranched antistatic agent: 23 parts;

[0047] The concrete preparation method of this fiber fabric composite antistatic agent is as follows:

[0048] (1) Preparation of Butanol Phosphate Antistatic Agent

[0049] (1) Add n-butanol to a clean three-necked flask, then add phosphorus pentoxide, slowly put it into a three-necked flask with n-butanol with a medicine spoon, and place the three-necked flask in a large beaker filled with cold water to Control its temperature not to exceed 50°C during the addition process;

[0050] The molar r...

Embodiment 2

[0070] This embodiment provides a method for preparing a composite antistatic agent for fiber fabrics. In the preparation method, the composite antistatic agent for fiber fabrics includes the following components in parts by mass:

[0071] Butanol phosphate antistatic agent: 35 parts, hydroxyl-terminated hyperbranched antistatic agent: 5 parts, carboxyl-terminated hyperbranched antistatic agent: 10 parts, quaternary ammonium salt-terminated hyperbranched antistatic agent: 25 parts;

[0072] The concrete preparation method of this fiber fabric composite antistatic agent is as follows:

[0073] (1) Preparation of Butanol Phosphate Antistatic Agent

[0074] (1) Add n-butanol to a clean three-necked flask, then add phosphorus pentoxide, slowly put it into a three-necked flask with n-butanol with a medicine spoon, and place the three-necked flask in a large beaker filled with cold water to Control its temperature not to exceed 50°C during the addition process;

[0075] The molar ...

Embodiment 3

[0095] This embodiment provides a method for preparing a composite antistatic agent for fiber fabrics. In the preparation method, the composite antistatic agent for fiber fabrics includes the following components in parts by mass:

[0096] Butanol phosphate antistatic agent: 38 parts, hydroxyl-terminated hyperbranched antistatic agent: 10 parts, carboxyl-terminated hyperbranched antistatic agent: 13 parts, quaternary ammonium salt-terminated hyperbranched antistatic agent: 20 parts;

[0097] The concrete preparation method of this fiber fabric composite antistatic agent is as follows:

[0098] (1) Preparation of Butanol Phosphate Antistatic Agent

[0099] (1) Add n-butanol to a clean three-necked flask, then add phosphorus pentoxide, slowly put it into a three-necked flask with n-butanol with a medicine spoon, and place the three-necked flask in a large beaker filled with cold water to Control its temperature not to exceed 50°C during the addition process;

[0100] The molar...

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PUM

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Abstract

The invention discloses a preparation method of a composite antistatic agent for a fiber fabric. The composite antistatic agent for the fiber fabric in the preparation method comprises the following components: a butanol phosphate ester antistatic agent, a terminal hydroxyl hyperbranched antistatic agent, a terminal carboxyl hyperbranched antistatic agent and a terminal quaternary ammonium salt hyperbranched antistatic agent; and the preparation method comprises the following steps: firstly, respectively preparing the butanol phosphate ester antistatic agent, the terminal hydroxyl hyperbranched antistatic agent, the terminal carboxyl hyperbranched antistatic agent and the terminal quaternary ammonium salt hyperbranched antistatic agent; and mixing the four antistatic agents to prepare the composite antistatic agent for the fiber fabric. The preparation method is simple and feasible; and the prepared antistatic agent has a good antistatic effect, good heat resistance and good acid and alkali resistance.

Description

technical field [0001] The invention belongs to the technical field of textiles, and in particular relates to a preparation method of a composite electrostatic agent for fiber fabrics. Background technique [0002] Chemical fibers, especially synthetic fibers, have many excellent characteristics compared with natural fibers, such as they can obtain special performance and aesthetic properties in fiber production and processing, and they are low in price, high in durability, good in strength and toughness, etc. , has been rapidly developed and widely used. Synthetic fibers have many advantages, but there are also many shortcomings that cannot be ignored, such as low hygroscopicity, poor dyeing performance, easy accumulation of charges, static electricity, and poor wearing comfort. There may be more brilliant breakthroughs. [0003] With the rapid and dramatic increase in the output of synthetic fibers, the problem of static electricity in textiles has become increasingly ac...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M13/292D06M15/53D06M15/592
Inventor 叶冬明陈菊媛
Owner SUZHOU CHENHENG WEAVING
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