The application relates to the technical field of
organic synthesis, and discloses an organic sulfinate salt composition, a preparation method and application thereof and the composition. The preparation method comprises the following steps: contacting a monovalent organic sulfinate salt shown in formula I with a
divalent metal salt or a salt of a
metal with a valence higher than two under the condition that a poor
solvent exists; the organic sulfinate salt prepared by the method has high yield and high purity, almost no sulfinate salt by-product is generated, the method has the advantages of simple operation, safe and easily-obtained reaction raw materials, rapid reaction, no need of recrystallization, the target product can be obtained through
filtration after the reaction, less
solvent is used, the cost is low, etc., the composition has the beneficial effects that the composition is more stable than a corresponding
sodium salt, the
sulfur odor is reduced, the composition has strong
reducing capacity, etc.