36 results about "Ethyl vinyl" patented technology

The invention provides a salt-responsive temperature-resistant salt-resistant water-based drilling fluid tackifying filtrate reducer as well as a preparation method and application thereof, and belongs to the technical field of drilling. The tackifying filtrate reducer is prepared from the following raw materials in parts by mass: 30 to 50 parts of 1-(2-carboxyethyl)-2-vinylpyridine, 20 to 40 parts of (3-(methacrylamido) propyl) dimethyl (3-thiopropyl) ammonium hydroxide inner salt, 35 to 55 parts of N, N-dimethylacrylamide, 10 to 25 parts of 4-vinylpyridine, 300 to 500 parts of water and 1 to 5 parts of an initiator. According to the filtrate reducer, cations and anions are concentrated on one monomer molecule, so that the synthesized product contains the cations and the anions with the same charge number, has good adsorption capacity and salt response characteristics, is compatible with salt essentially, can effectively resist high temperature and high salt, and can be recycled. And the viscosity-increasing and filtrate-reducing agent has good viscosity-increasing and filtrate-reducing effects on the drilling fluid.

The invention discloses an alpha, omega-diiodo perfluoroalkane derivative, an alpha, omega-diiodo ethyl perfluoroalkane derivative as well as a preparation method and application of the alpha, omega-diiodo perfluoroalkane derivative and the alpha, omega-diiodo ethyl perfluoroalkane derivative. According to the method, alpha, omega-diiodo perfluoroalkane is taken as a raw material, and the alpha, omega-diiodo perfluoroalkane and ethylene are subjected to free radical addition reaction under the action of an initiator and a solvent to prepare the alpha, omega-diiodo ethyl perfluoroalkane. The alpha, omega-diiodoethyl perfluoroalkane and alkali are subjected to a one-molecule and / or two-molecule hydrogen iodide hydride elimination reaction, and alpha, omega-iodoethyl vinyl perfluoroalkane and / or alpha, omega-divinyl perfluoroalkane are / is generated. The method is simple and convenient to operate, the raw material utilization rate and the target product yield are high, the preparation cost is effectively reduced, and the industrial production requirement is met. The alpha, omega-diiodo perfluoroalkane derivative or alpha, omega-diiodo ethyl perfluoroalkane derivative prepared by the method disclosed by the invention can be used as a vulcanization point monomer for preparing peroxide vulcanized fluororubber, and compared with common rubber, the rubber has more excellent compression deformation performance, strength and medium resistance and has a wide application prospect.

The invention relates to a bisulfonate hydrophobic association polymer oil-displacing agent with a benzene ring structure and a preparation method thereof. The polymer oil-displacing agent is formed by copolymerization of three monomers, namely acrylamide, sodium 2-allyl methylamino ethanesulfonate and long-chain alkyl disulfoethyl (4-vinyl benzyl) betaine which is a hydrophobic monomer with the benzene ring structure. The preparation method comprises the following steps: firstly adding distilled water, sequentially adding acrylamide, 2-allylmethylamino sodium ethanesulfonate and long-chain alkyl disulfoethyl (4-vinyl benzyl) betaine, adding water to adjust the total concentration, introducing N2 to remove oxygen, adding an initiator, and reacting at a certain temperature to obtain the terpolymer. The polymer oil-displacing agent prepared by the invention has good water solubility and good temperature resistance and shear resistance, shows good salt resistance in saline water with the degree of mineralization being greater than or equal to 30000 mg / L, shows a good oil-displacing effect in heterogeneous rock cores, and can improve the crude oil recovery rate by 10% or above.

The invention discloses a method for synthesizing branched polyester by using polyester and a carbon dioxide derivative and a product thereof. The method comprises the following steps: carrying out solid-phase ester exchange reaction on a carbon dioxide derivative and polyester under inert gas protection and heating conditions to obtain branched polyester; the carbon dioxide derivative is prepared from at least one of 3-ethylidene-6-vinyl tetrahydro-2H-pyran-2-ketone and a homopolymer pEVL (Poly (Ethylene Vinyl Vinyl) L) thereof. According to the invention, a large amount of polyester materials and carbon dioxide wastes can be utilized, so that the current relatively difficult problems of carbon emission and pollution are solved.

The invention discloses a high-barrier polypropylene material, a preparation method thereof and application of the high-barrier polypropylene material in an organic silica gel sealing packaging material, and relates to the technical field of high polymer materials. When the high-barrier polypropylene material is prepared, firstly, polypropylene is grafted with dichloro (vinyl) phosphine and vinylmethylsilane and then reacts with 1-ethylene-1H-pyrrole to obtain modified polypropylene, secondly, pretreated montmorillonite is subjected to demethylation through aluminum chloride and then reacts with 2-chloro-5-(1H-pyrrole-1-yl) pyridine to obtain the high-barrier polypropylene material. Then carrying out a reaction with N-triethyl-(4-vinylbenzyl) ammonium to obtain modified montmorillonite; and finally, mixing the modified polypropylene and the modified montmorillonite to obtain the high-barrier polypropylene material. The high-barrier polypropylene material prepared by the invention has high barrier rate, flame retardant property and ultraviolet aging resistance.

The invention discloses a corrosion-resistant polyion liquid coating and a preparation method thereof. According to the invention, ionic liquid monomer 3-ethyl-1-vinyl imidazole bromine salt is adopted to prepare polyionic liquid (PIL) through a free radical polymerization method, then the polyionic liquid is coated on a Cu (at) Cu (OH) 2 filter material with a super-hydrophilic Cu (OH) 2 nanoneedle coated copper mesh, the polyionic liquid is used as a protective coating of Cu (OH) 2, and the Cu (at) Cu (OH) 2 filter material can be used for filtering and purifying the Cu (OH) 2 nano-needle coated Cu (at) Cu (OH) 2 nano-needle coated Cu (at) Cu (OH) 2 nano-needle coated copper mesh. The prepared Cu-coated Cu (OH) 2-PIL filter material not only has an oil-water separation capacity in a wastewater environment, but also has a certain capacity of separating organic solvents with different polarities, Cu-coated Cu (OH) 2 and Cu-coated Cu (OH) 2-PIL as well as Cu-coated Cu (OH) 2 and Cu-coated Cu (OH) 2-PIL soaked in acid, alkali and salt solutions are analyzed by adopting methods such as XRD (X-Ray Diffraction), SEM (Scanning Electron Microscope), XPS (X-Ray Photoelectron Spectroscopy) and the like, and a result shows that a copper hydroxide layer structure on the surface of Cu-coated Cu (OH) 2 soaked in NaOH and NaCl severely collapses; after the PIL coated Cu coated Cu (OH) 2-PIL is soaked in NaOH and NaCl, Cu (OH) 2 on the surface of the PIL coated Cu coated Cu (OH) 2-PIL completely reacts with the HCl and loses separation capacity, however, the PIL coated Cu coated Cu (OH) 2-PIL still retains a complete nano copper hydroxide layer after being soaked in NaOH and NaCl, and part of Cu (OH) 2 is retained after being soaked in the HCl.

To provide a rubber-modified styrene resin composition having an excellent balance of total light transmittance, diffused light transmittance, and whitening resistance, by optimizing reinforcing rubber particles dispersed in the rubber-modified styrene resin composition.SOLUTION: The rubber-modified styrene resin composition of the present invention contains a styrene polymer forming a matrix and rubber-like polymer particles dispersed as islands in the matrix. The rubber-like polymer particles include styrene-based polymer particles and have a sea-island structure, containing 99.0 to 94.0% by mass of the styrene-based polymer and 1.0 to 6.0% by mass of the rubber-like polymer. The rubber-like polymer particles are a polybutadiene rubber and / or a styrene-butadiene copolymer. The particle size of the rubber-like polymer particles is 2.0 to 5.5 μm, and a content of methyl ethyl ketone insoluble gel in the rubber-modified styrene resin composition is 2.0 to 15.0% by mass.SELECTED DRAWING: None

The present invention discloses a corrosion-resistant polyionic liquid coating and a preparation method thereof. In the present invention, the ionic liquid monomer 3-ethyl-1-vinylimidazolium bromide is used to prepare polyionic liquid (PIL) by free radical polymerization, and then it is coated on the Cu@Cu(OH)2 filter material with superhydrophilic Cu(OH)2 nanoneedles coated copper mesh. Using the polyionic liquid as a protective coating for Cu(OH)2, the prepared Cu@Cu(OH)2-PIL filter material not only has the ability of oil-water separation in wastewater environment, but also has the ability to separate organic solvents with different polarities to a certain extent. XRD, SEM, XPS and other methods are used to analyze Cu@Cu(OH)2 and Cu@Cu(OH)2-PIL, as well as Cu@Cu(OH)2 and Cu@Cu(OH)2-PIL after being soaked in acid, alkali and salt solutions. It is found that the structure of the copper hydroxide layer on the surface of Cu@Cu(OH)2 collapses seriously after being soaked in NaOH and NaCl; after being soaked in HCl, the surface Cu(OH)2 completely reacts with HCl and loses the separation ability. However, the Cu@Cu(OH)2-PIL coated with PIL still retains a complete nano-copper hydroxide layer after being soaked in NaOH and NaCl, and still retains part of Cu(OH)2 after being soaked in HCl.

The invention discloses a polyion liquid derived carbon coated metal catalyst as well as preparation and application thereof. The preparation method comprises the following steps: 1, obtaining an activated carbon / AIBN suspension; step 2, obtaining an activated carbon / AIBN suspension loaded with platinum; 3, dissolving 1-ethyl-3-vinyl imidazole nitrate in a mixed solution of ethanol and water, removing oxygen, slowly adding into the platinum-loaded activated carbon / AIBN suspension, stirring and polymerizing for 12-24 hours at 60-70 DEG C under the protection of nitrogen, and performing suction filtration to obtain a polymerized ionic liquid modified activated carbon-loaded platinum catalyst precursor; step 4, drying; and 5, roasting to obtain the polyion liquid derived carbon coated metal catalyst. The invention provides the application of the polyion liquid derived carbon coated metal catalyst in the catalytic hydrogenation reaction of chloronitrobenzene, and the catalyst has excellent activity, selectivity and stability.

The invention discloses a preparation method and application of magnetic microspheres for drug adsorption. Ferric salt is dissolved in water and heated, an alkaline agent is slowly dropwise added and stirred, cleaning is conducted after the reaction is finished, and Fe3O4 nanoparticles are prepared; the preparation method comprises the following steps: dispersing Fe3O4 nanoparticles in water, heating, adding a double-bond compound, and cleaning after the reaction is finished, so as to prepare Fe3O4 nanoparticles with-C = C-double bonds on the surface; fe3O4 nanoparticles with-C = C-double bonds on the surfaces are dispersed in water, an emulsifier and an active group compound are added, the active group compound is sodium p-styrenesulfonate, vinylpyrrolidone or triethyl (4-vinylbenzyl) ammonium chloride, continuous heating is performed, cleaning is performed after the reaction is finished, and the magnetic microspheres for drug adsorption are prepared. The magnetic microspheres can be fully mixed with sewage through the directional movement of the magnetic microspheres, adsorption, purification and concentration of drugs are completed through anion groups or cation groups, the operation steps of testing are greatly simplified, and the working efficiency is improved.

The invention belongs to the technical field of gel electrolytes, and particularly relates to an intrinsic flame-retardant gel polymer electrolyte, a preparation method thereof and a battery. The intrinsic flame-retardant gel polymer electrolyte comprises a flame-retardant polymer and an electrolyte, and the flame-retardant polymer comprises the following raw material components: diethyl vinyl phosphate, methyl methacrylate and polyethylene glycol dimethacrylate, diethyl vinyl phosphate is chemically bonded in a polymer network formed by cross-linking polymerization of methyl methacrylate and polyethylene glycol dimethacrylate through an in-situ thermal polymerization reaction, and the volume ratio of the dosage of methyl methacrylate to the dosage of polyethylene glycol dimethacrylate to the dosage of diethyl vinyl phosphate is (1-3): 1: 1. The electrolyte can inhibit a combustion chain reaction under extreme conditions without depending on an additional flame retardant additive, and can realize collaborative optimization of intrinsic flame retardant performance and electrochemical performance on the premise of not influencing an ion transmission channel of the electrolyte.

The application discloses a method for synthesizing branched polyester by using polyester and carbon dioxide derivatives and a product thereof. The method comprises the following steps: performing solid-phase ester exchange reaction on the carbon dioxide derivatives and the polyester under the conditions of inert gas protection and heating to obtain branched polyester; and the carbon dioxide derivatives comprise at least one of 3-ethylidene-6-vinyl tetrahydro-2H-pyran-2-one and a homopolymer pEVL thereof. The application can utilize a large amount of polyester materials and carbon dioxide waste to solve the current more intractable carbon emission and pollution problems.

The present invention relates to the technical field of runway joint sealants, and discloses a joint sealant for high-plateau airport runways and a preparation method thereof. The joint sealant comprises a base paste and a vulcanizing paste. The base paste includes liquid polysulfide raw rubber, ethyl vinyl sulfide, and auxiliary material A; the vulcanizing paste includes manganese dioxide, a photoinitiator, and auxiliary material B. The airport runway joint sealant provided by the present invention can effectively solve problems such as low curing rate of polysulfide joint sealants caused by large day-night temperature differences in high-plateau airports, poor performance after curing, and easy attenuation of performance caused by high-plateau ultraviolet radiation. Moreover, the curing rate can meet the requirements of non-stop operation construction, and has broad market application prospects.

The present application relates to the technical field of oilfield treatment agent, and is an oilfield sewage treatment oil removal agent and a preparation method thereof.The former is obtained by the following method: 1-ethyl-4-vinylbenzene, methacrylate, long-chain alkyl dimethyl allyl ammonium chloride, urea, anhydrous ethanol and water are stirred and uniformly mixed to obtain a mixed solution, and then acrylamide and a catalyst are added to the mixed solution to react and obtain the oil removal agent.The raw materials are easy to obtain, and the process is simple.The oil removal agent obtained by the preparation method has strong oil removal capacity, high oil removal rate, and is suitable for oil-water separation of oilfield sewage.The oil removal agent is effective in a wide pH range, does not contain metal ions, avoids secondary pollution, and also has the functions of demulsification, sterilization, flocculation and slow release.

The application discloses a production method for improving the binding force of a multilayer copper current collector, and relates to the technical field of current collector production.The production method solves the problems of poor binding force between a base film and a copper metal layer, easy peeling and many pinholes in a traditional composite current collector.The production method comprises four steps: base film pretreatment, argon-oxygen plasma treatment of both sides of the base film; irradiation grafting, covalent grafting of ethyl vinyl methacrylate and glycidyl methacrylate to the surface of the base film; magnetron sputtering bottoming, deposition of a seed layer on the surface of the base film; and electroplating thickening, formation of the copper metal layer by using an electroplating solution containing copper sulfate, hydrochloric acid, sulfuric acid and an additive in a specific proportion.The method of the application converts mechanical binding into chemical bonding through the synergistic effect of 'plasma pretreatment+UV grafting', significantly improves the interlayer peeling force, reduces pinhole defects, is stable in process and easy to be industrialized, and helps the development of high-performance batteries.

The invention provides a dye compound as well as a preparation method and application thereof, and particularly relates to the technical field of dye chemical industry. The dye compound has a structure shown in the specification, wherein R1 is selected from a hydrogen atom, methyl, ethyl, n-propyl or isopropyl; r2 is selected from methyl, ethyl, cyanoethyl, vinyl or allyl; and R3 is selected from methyl or halogen. The dye compound has extremely high washing fastness, the pH application range of a dyeing bath is very wide, the flexibility and adaptability of a dyeing process are improved, and the color difference problem caused by pH fluctuation is reduced. Meanwhile, the heavy dyeing performance is excellent, and the reliability and the yield of the dyeing process are further improved. In addition, the dye is also good in dispersity, so that the uniformity and stability of the dyeing process are ensured.

The invention relates to the technical field of flame-retardant resin, and provides polydivinylbenzene flame-retardant resin as well as a preparation method and a cured product thereof. The polydivinylbenzene flame-retardant resin provided by the invention is formed by copolymerization of divinyl benzene, ethyl vinyl benzene, a silicon-containing monomer and benzofuran, the divinyl benzene provides a side chain unsaturated group required by crosslinking, and the cured resin has an excellent rigid skeleton; flexible alkyl side chains are regularly inserted into a main chain of the ethyl styrene monomer, so that the impact resistance of the material is improved; by adding the silicon-containing monomer, the combustion performance of the material can be reduced, and the high-temperature resistance and tensile strength of the material are improved; the benzofuran can effectively control the molecular weight of the polymer and reduce the molecular weight distribution of the product. In conclusion, the polydivinylbenzene flame-retardant resin provided by the invention has the advantages of excellent flame retardance, high temperature resistance, high toughness and low dielectric loss, and can meet the use requirements in the fields of electronic packaging, high-end copper-clad plates and the like.

The invention discloses a preparation method of a chiral amino acid derivative. The preparation method specifically comprises the following steps: step 1, preparing 4-vinyl benzoyl chloride; step 2, preparing free chiral diethyl glutamate; and step 3, preparing chiral diethyl (4-vinyl benzoyl) glutamic acid according to the product obtained in the step 1 and the product obtained in the step 2. The invention also discloses a chiral amino acid derivative, and when the prepared chiral amino acid derivative is used as a chiral main chain monomer for synthesizing a chiral polymer, precious metal catalysis is not needed. The problem that the cost is high due to the fact that precious metal catalysis is needed in the chiral polymer synthesis process of an existing chiral monomer is solved.

The application discloses a polyionic liquid derivative carbon-coated metal catalyst and a preparation and application thereof. The preparation method is carried out according to the following steps: step one: obtaining an activated carbon / AIBN suspension liquid; step two: obtaining an activated carbon / AIBN suspension liquid loaded with platinum; step three: dissolving 1-ethyl-3-vinylimidazole nitrate in a mixed solution of ethanol and water, slowly adding the activated carbon / AIBN suspension liquid loaded with platinum into the solution after oxygen removal, stirring and polymerizing at 60-70 DEG C for 12-24 hours under nitrogen protection, and then performing suction filtration to obtain a polyionic liquid modified activated carbon loaded platinum catalyst precursor; step four: drying; and step five: calcining to obtain the polyionic liquid derivative carbon-coated metal catalyst. The application provides application of the polyionic liquid derivative carbon-coated metal catalyst in a catalytic hydrogenation reaction of chloronitrobenzene, and the catalyst has excellent activity, selectivity and stability.

The application discloses a strain of Zygosacharomyces rouxii and application of the strain in fermented food, and belongs to the field of fermentation engineering and biotechnology. The application provides a strain of Zygosacharomyces rouxii MY03, and the preservation number is CCTCC NO: M 20221652. The Zygosacharomyces rouxii MY03 is used for yellow rice wine fermentation, and the alcohol content, fusel and amino acid content of the prepared yellow rice wine have no significant difference compared with a traditional fermentation method, the organic acid content is reduced, the ethyl ester content is increased by 50.82%, the fusel and ester of the produced yellow rice wine are coordinated, the astringency, sourness and alcohol aroma are reduced, the aroma and taste are more balanced, the content of ethyl vinyl guaiacol is increased from 9.16 mu / g to 74.31 mu / g, the herbal aroma is prominent, and the flavor and sensory diversity of the yellow rice wine are increased.

A composition comprising the following: a) an ethylene / alpha-olefin / interpolymer; b) a peroxide; c) a "Si-containing compound" selected from the following (i) to (v): (i) wherein each R is independently selected from C1-C3 alkyl, and n is 1 to 16; (ii) wherein each R is independently methyl or ethyl, and n is from 1 to 18; (iii) wherein each R is independently methyl or ethyl; (iv), vinyl oligomeric siloxane; or (v) any combination of (i) to (iv).

The invention discloses a method for modifying the stability of a perovskite solar cell based on polyion liquid. The perovskite solar cell used in the method structurally comprises conductive glass, an electron transport layer, a perovskite layer, a hole transport layer and a back electrode in sequence from bottom to top. Poly (1-ethyl-3-vinyl imidazolium iodide) is added into a perovskite precursor solution, 5 + / -1 mg of the polymer is added into the precursor solution with the concentration being 1 ml, or an isopropanol solution of the poly (1-ethyl-3-vinyl imidazolium iodide) is spin-coated on a perovskite layer, and 5 + / -1 mg of the polymer is added into the isopropanol solution with the concentration being 1 ml; fTO or ITO is used as the conductive glass; the chemical formula of the perovskite layer is ABX3 (A is Cs, FA and MA, B is Pb and Sn, and X is Cl, Br and I). According to the method, the long-term stability of the perovskite is realized by utilizing the advantages that the imidazole group can effectively passivate the perovskite and the polyion liquid.

A layer of perovskite material for use in an energy harvesting device, the layer having a thickness of less than 60 µm and the perovskite material comprising crystalline material of formula (LC)2(SC)n-1MnX3n+1 with a polar crystallographic point group, wherein each LC is a cation of formula A-B-C, wherein A is selected from ethyl, ethenyl, ethynyl, C1- 4 alkoxymethyl, C1-4 alkylthio, aryl, and heteroaryl, each of which is optionally substituted one or more times with fluoro and wherein the aryl and heteroaryl are optionally substituted one or more times with a substituent selected from C1-4 alkyl, C2-4 alkenyl, C2-4 alkynyl, C1-4 fluoroalkyl, C2-4 fluoroalkenyl, C2-4 fluoroalkynyl, C1-4 alkoxy, hydroxy, formyl, carboxyl and heteroaryl, B is absent or is selected from C1-6 alkylene, C2-6 alkenylene and C2-6 alkynylene, each of which is optionally substituted with fluoro, and C is –N(R1)3+ or – CR1N(R1)2N(R1)2+, wherein each R1 is independently selected from H and C1-6 alkyl, each SC is a cation selected from Cs+, N(R2)4+ and R2CN(R2)2N(R2)2 +, wherein each R2 is independently selected from H and methyl, each M is selected from Pb2+, Sn2+ and Ge2+, each X is halide, n is an integer selected from 1 to 6, and the material comprising photovoltaic and ferroelectric or piezoelectric properties.

Disclosed herein are compositions and methods related to a packaging laminate comprising: a first polymeric layer formed form a composition including polypropylene copolymer and / or a high density polyethylene (HDPE) resin; and a second polymeric layer formed from a composition including a high density polyethylene (HDPE) resin, a linear low density polyethylene (LLDPE) resin, a low density polyethylene (LDPE), and / or LDPE / HDPE copolymer with a coextruded ethyl vinyl alcohol (EVOH) and compatibilizer. Recyclable packaging containers formed of the packaging laminates are also disclosed.

The application belongs to the technical field of clay stabilizer preparation, and particularly relates to a clay stabilizer and a preparation method thereof. The clay stabilizer is composed of the following raw materials: 1-ethyl-3-vinylimidazolium bromide, [3-(dodecyloxy)-2-hydroxypropyl] di(2-hydroxyethyl) methylammonium methyl sulfate, 3-{(dimethyl(3-trimethoxysilyl)propyl)ammonium} propane-1-sulfonate, polyallylamine hydrochloride, glycerophosphorylcholine, lauryl alcohol polyoxyethylene polyoxypropylene ether, glacial acetic acid, and the balance is deionized water. The clay stabilizer has excellent permeability and anti-swelling rate due to the synergistic effect between the raw materials.

A composition comprising the following: a) an ethylene / alpha-olefin / interpolymer; b) a peroxide; c) a “Si-containing compound” selected from the following (i) through (v): (i), where each R is independently selected from a C1-C3 alkyl, and n is from 1 to 16; (ii), where each R is independently methyl or ethyl, and n is from 1 to 18; (iii), where each R is independently methyl or ethyl; (iv) a vinyl oligomericsiloxane; or (v) any combination of (i) through (iv).

The invention belongs to the technical field of clay stabilizer preparation, and particularly relates to a clay stabilizer and a preparation method thereof. The invention relates to a clay stabilizer. The invention relates to an environment-friendly flame retardant which is prepared from the following raw materials: 1-ethyl-3-vinyl imidazole onium bromide, [3-(dodecyloxy)-2-hydroxypropyl] bis (2-hydroxyethyl) methyl ammonium sulfate methyl ester salt, 3-{(dimethyl (3-trimethoxysilyl) propyl) ammonium} propane-1-sulfonate, polyallylamine hydrochloride, glycerophosphorylcholine, polyoxyethylene polyoxypropylene lauryl ether and glacial acetic acid. And the balance of deionized water. According to the clay stabilizer disclosed by the invention, the raw materials have a synergistic effect, so that the clay stabilizer has excellent permeability and anti-swelling rate.

The application discloses a preparation method of multi-metal organic framework modified graphene oxide microspheres. The prepared microspheres are coated with multiple layers of graphene oxide on the surface of ethyl vinylbenzene / divinylbenzene (EVB / DVB) microspheres, and then the multi-metal organic framework is modified on the surface of the graphene oxide. The application uses graphene oxide as an intermediate to connect the metal organic framework and the polymer, thereby improving the stability of the material. The EVB / DVB microspheres are used as the matrix of the metal organic framework, so that the stability of the metal organic framework can be enhanced, and the metal organic framework is convenient for centrifugal recovery. The composite material can provide coordination, hydrophobic and pi-pi conjugation, thereby improving the affinity of the material to bisphenol substances, and the adsorption of the bisphenol organic substances is obviously improved. The metal organic framework is bonded to the microspheres, so that the specific surface area is increased, the contact area with the bisphenol substances is increased, and the adsorption efficiency is improved.

The invention discloses CO2-based thermoplastic polyurethane and a preparation method thereof. The method adopts a one-pot two-step reaction and comprises the following steps: firstly, performing ring-opening copolymerization on alpha-ethylidene-delta-vinyl-delta-valerolactone (EVP) (from telomerization of CO2 and 1, 3-butadiene) and a cyclic monomer (cyclic lactone or cyclic carbonate) to prepare unsaturated copolyester polyol with a side chain containing carbon-carbon double bonds; and taking the polyol as a soft segment, and reacting with diisocyanate and a chain extender to obtain the thermoplastic polyurethane. Controllable transformation of the material from a crystalline state to an amorphous state and from a plastomer to a high-elastic body is realized by regulating and controlling the EVP content (0-19 mol%). The obtained material can be selectively subjected to bulk depolymerization under the action of a catalyst, is efficiently recovered into EVP and a cyclic monomer, and has good chemical recovery performance. Meanwhile, side chain double bonds provide reaction sites for subsequent functionalization, so that the polymer has good application prospects in the fields of elastomers, adhesives, biomedical materials and the like.

The application discloses a preparation method of photo-crosslinking stabilized temperature-responsive ionic polymer micelles, and specifically comprises the following steps: preparing a PNIPAM-based polymer and a urea group-containing intermediate; preparing a positive ion polymer by using the urea group-containing product, N-triethyl-(4-vinyl benzyl) ammonium chloride, p-styrene-7-hydroxy-4-methyl coumarin and AIBN; preparing a negative ion polymer by using the urea group-containing product, sodium p-styrene sulfonate, p-styrene-7-hydroxy-4-methyl coumarin and AIBN; and irradiating aqueous solutions of the positive ion polymer and the negative ion polymer with ultraviolet light, and then mixing to obtain composite ionic polymer micelles. Based on a modular polymerization route of thiol-ene click chemistry, a temperature-sensitive PNIPAM unit, an ultraviolet light-crosslinkable photosensitive group and an ionizable quaternary ammonium salt / sulfonate group are integrated, so that a temperature-ultraviolet light dual-responsive polymer with positive / negative ion characteristics is constructed.