The invention discloses a preparation method of a silane-modified fluoroethyl ester polymer used as a lithium battery binder, which comprises the following steps: 1) mixing perfluorovinyl ester compounds, silane compounds, 80%- Add 90% of the solvent into the container and stir, heat up to 60-80°C, dissolve the initiator in the remaining solvent and add it dropwise to the reaction solution. After the addition is complete, keep warm and continue the reaction for 10-12h; The solution was transferred to a rotary evaporator, the solvent was evaporated, the precipitate was washed with n-hexane, and the precipitate was dried to obtain the silane-modified fluoroethyl ester polymer. The fluorine atoms in the polymer prepared by the invention have a good binding force with lithium ions, which accelerates the transfer of lithium ions and improves the Coulombic efficiency of the battery; the silane structure enhances the adhesion between the polymer and the inorganic active silicon particles, and improves the battery life The cycle stability of the prepared polymers has excellent initial Coulombic efficiency and electrochemical stability.