The invention belongs to the technical field of catalytic materials, and particularly relates to a
macro-micro-nano integrated structured
titanium silicalite
molecular sieve catalyst as well as a preparation method and application thereof. According to the catalyst, SiC
whiskers are grown on the surface of a 3D communicating hole SiC carrier in situ, TS-1
titanium silicalite
molecular sieve precursor
coating is combined with a steam
crystal transformation process, and a TS-1
titanium silicalite
molecular sieve coating with framework
nickel doping and open mesopores is grown on the surface of the SiC
whiskers, so that the loading capacity and catalytic activity of the titanium silicalite molecular
sieve are effectively improved; meanwhile, excellent
interface bonding force and a continuous heat
conduction channel are provided through the SiC
whiskers, and the
heat transfer performance is enhanced. Compared with a traditional
coating, the coating of the catalyst is rougher, and fluid turbulence and
mass transfer efficiency are enhanced. According to the structured titanium silicalite molecular
sieve catalyst, the utilization efficiency, the
reaction rate and the selectivity of the catalyst are remarkably improved through
coupling of macroscopic channels, micron pore channels and nano mesopores, and the structured titanium silicalite molecular
sieve catalyst is particularly suitable for
phenol hydroxylation reaction and olefin oxidation reaction.