The invention provides an environmentally-friendly mixed refrigerant I. The environmentally-friendly mixed refrigerant I is characterized in that 1, 1, 2-trifluoroethylene, 1, 1-difluoroethylene, 1, 1, 2, 3, 3, 3-hexafluoropropylene, 1, 1-difluoromethane and other substances are added to trifluoropropene or tetrafluoropropene, thus the direct filling performance of the mixed refrigerant in an airconditioning system is improved. Additionally, the invention also provides an environmentally-friendly mixed refrigerant II. The environmentally-friendly mixed refrigerant II is characterized in that1, 1, 2, 2-tetrafluoroethane, 1, 1, 1, 2-tetrafluoroethane, 1, 1, 1, 2, 2-pentafluoroethane, 1, 1, 1, 2, 3, 3, 3-heptafluoropropane, trifluoroiodomethane, etc. are added in the abovementioned mixture,thus the flammability of the refrigerant is reduced. The invention also provides an environmentally-friendly mixed refrigerant III. The environmentally-friendly mixed refrigerant III is characterizedin that AlF3, FeF3, MgF2 and CuO nanoparticles are added in the abovementioned mixture, so that the intermiscibility of the refrigerant and mineral frozen engine oil can be improved.