200 results about "Hydrofluoroolefin" patented technology

Disclosed herein are processes for the production of hydrofluoroolefins by dehydrofluorination. Also disclosed herein are processes for separation of hydrofluoroolefins from hydrofluorocarbons and from hydrogen fluoride.

The present invention relates to compositions containing hydrofluoroolefins and to the uses thereof as heat transfer fluids, blowing agents, solvents and aerosols. More particularly, the invention relates to compositions having: 5 to 65% by weight, preferably from 5 to 15% by weight, of 2,3,3,3-tetrafluoropropene, 5 to 70% by weight, preferably 40 to 60% by weight, of HFC-134a and 25 to 42% by weight of HFC-32.

The invention pertains to heat transfer compositions, particularly to automobile refrigerants comprising a hydrofluoroalkene, an iodocarbon, a polyol ester and at least one compound comprising trifluoromethane, methyl iodide, heptafluorobutane or propene.

An absorptive refrigeration method that employs a refrigerant comprising one or more hydrofluoroolefin or hydrochlorofluoroolefin refrigerants, and an oil selected from the group consisting of a polyalkyene glycol oil, a poly alpha olefin oil, a mineral oil and a polyolester oil.

The present invention relates to heat transfer compositions comprising an oxygenaged lubricant comprising polyvinyl ether oil and a refrigerant comprising hydrofluoroolefins and/or hydrochlorofluoroolefins. The heat transfer compositions of the present invention have the benefit of exhibiting superior thermal stability and are useful in such applications as refrigeration, air conditioning, and heat transfer systems.

The invention pertains to heat transfer compositions, particularly to automobile refrigerants comprising a hydrofluoroalkene, an iodocarbon, and at least one lubricant having hydrogen atoms and carbon atoms, wherein no more than 17% of the total number of hydrogen atoms which are attached to a carbon atom are tertiary hydrogen atoms.

The present invention relates to solvent/cleaner and heat transfer fluid compositions comprising at least one hydrochlorofluoroolefin (HCFO), 1-chloro-3, 3,3-trifluoropropene (HCFO-1233zd), particularly the trans- isomer. The HCFO of the present invention can be used in combination with co-agents including, hydrofluorocarbons (HFCs), hydrofluoroolefins (HFOs), hydrocarbons, ethers including hydrofluoroethers (HFEs), esters, ketones, alcohols, 1,2-transdichloroethylene and mixtures thereof.

The invention discloses a fluorinated chrome base fluorination catalyst and application thereof. The weight percentage composition of a precursor of the catalyst is that chromic oxide 80.0%-99.0% and rare-earth metal oxide 1.0%-20.0%, wherein the rare-earth metal oxide is selected from one or more of CeO2, La2O3, Nd2O3, Y2O3, ZrO2 and Yb2O3. The precursor of the catalyst is roasted at 300 DEG C-400 DEG C, and the fluorinated chrome base fluorination catalyst is obtained by fluorating the precursor of the catalyst by utilizing hydrogen fluoride gas at 350-450 centidegree. The obtained fluorination catalyst has the advantages of being good in carbon deposit resistance performance and activation and the like. The catalyst is mainly used for preparation of hydrofluoroolefin and hydrogen fluorine chlorine olefins.

According to a compressor and a refrigeration cycle device using same of the present invention, a refrigerant and refrigeration oil 103 are sealed in an container 101, the refrigerant is a hydrofluoroolefin having double bond of carbon in its composition or a mixture of hydrofluoroolefin as a base component and hydrofluorocarbon having no double bond, and at least one of benzotriazole, dialkyl dithiophosphoric acid zinc, dialkyl selenium, metal phenate, and organic nitrogen compound is included in the refrigeration oil 103, and it is an object to suppress the decomposition and polymerization of refrigeration oil and a refrigerant, and to secure reliability of the compressor and the refrigeration cycle device.

A compressor 1 for compressing a refrigerant containing a hydrofluoroolefin refrigerant, a condenser 2 for condensing the refrigerant by heat exchange, a throttle device 4 for decompressing the condensed refrigerant, an evaporator 5 for evaporating the refrigerant by heat exchange between the decompressed refrigerant and air, and air adsorbing means 3 for adsorbing oxygen and nitrogen are connected by piping so as to configure a refrigerant circuit through which the refrigerant containing the hydrofluoroolefin refrigerant is circulated.

In a compressor, a single refrigerant of hydrofluoroolefin having a double bond of carbon or a mixed refrigerant containing hydrofluoroolefin and hydrofluorocarbon having no double bond of carbon is used, and moreover a refrigerating machine oil containing an additive for suppressing deterioration of the refrigerating machine oil and an antiwear agent is used, the compressor including a sliding portion which is exposed to the mixed refrigerant and the refrigerating machine oil and which has a hardness of 47-55 HRC. Thus, decomposition and polymerization of the refrigerant and the refrigerating machine oil can be inhibited (i.e., occurrence of sludge can be inhibited), and antiwear property of sliding portions, e.g. vane and piston, of the compressor can be maintained. As a result, reliability of the compressor and the refrigerating cycle apparatus using the compressor can be ensured.

Azeotropic or azeotrope-like compositions of the present technology include methyl chloride and at least one hydrofluorocarbon or hydrofluoro-olefin. In some examples, the at least one hydrofluorocarbon or hydrofluoro-olefin can be selected from the group consisting of 1,1,1,2-tetrafluoroethane and 1,3,3,3-tetrafluoropropene. The azeotropic or azeotrope-like compositions can be used as solvents or diluents in polymerization processes, including slurry polymerization processes.

A blowing agent for thermosetting foams is disclosed. The blowing agent is a hydrofluoroolefin (HCFO), preferably HFCO-1234ze in combination with a hydrochlorofluoroolefin (HCFO) preferably one selected from HCFO-1233zd, HCFO-1223, HCFO-1233xf and mixtures thereof. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.

The present invention relates, in part, to the discovery that the presence of moisture in 1,1,2,3-tetrachloropropene (HCO-1230xa) results in catalyst deactivation and accelerated corrosion in the reactor during the fluorination of HCO-1230xa to 2-chloro-3,3,3-trifluoropropene. By substantially removing the moisture, it is shown that the catalyst life is extended and results in improved operation efficiency of the fluorination reaction. Such steps similarly result in an overall improvement in the production of certain hydrofluoroolefins, particularly 2,3,3,3-tetrafluoropropene (HFO-1234yf).

Hydrofluoroolefins and hydrochlorofluoroolefins contaminated with acid and/or iron compounds are purified and stabilized by contacting the haloolefin with a solid adsorbent such as alumina and then combining the purified haloolefin with one or more stabilizers such as an epoxide. The purified, stabilized haloolefins thus obtained are useful in a wide variety of end-use applications, including, for example, as refrigerants, propellants, foaming agents, fire suppression or extinguishing agents, and solvents.

A scroll compressor employs therein a refrigerant having a small global warming potential and a small ozone depletion potential and mainly comprising hydrofluoroolefin having a carbon-carbon double bond. A stationary scroll has and end plate and a discharge port defined in the end plate at a central portion thereof so as to open into a discharge chamber. The stationary scroll also has a bypass hole defined in the end plate to allow a plurality of compression chambers to communicate with the discharge chamber before the compression chambers communicate with the discharge port. A check valve is provided on the bypass hole to allow the refrigerant to flow from the compression chambers to the discharge chamber. This construction can restrain a baneful influence on the global environment, reduce a temperature increase caused by excessive compression, and restrain decomposition of the refrigerant even in long-term use.

The present invention relates to polymeric oil-return agents which solubilize or disperse mineral oil and/or synthetic oil lubricants with hydrofluorocarbon, hydrochlorofluorocarbon, and hydrofluoroolefin-based refrigerants and refrigerant compositions containing them. The polymeric oil-return agents are random copolymers containing less than about 30 wt % fluorine and produced from at least one monomer providing compatibility with the oil phase and at least one monomer providing compatibility with the refrigerant phase. The polymeric oil-return agents provide for more efficient return of mineral oil and/or synthetic oil lubricants from non-compressor zones back to a compressor zone in a refrigeration system.