A refrigerating machine oil including a refrigerating machine oil basis such as polyol ester oil and an additive polyol ester oil is mixed to a refrigerant including 2,3,3,3-tetrafluoropropene, 1,3,3,3-tetrafluoropropene or the like. A compressor for refrigeration and air-conditioning including the mixture charged therein is used. The composition of the additive polyol ester oil is 1 to 30 wt %.
The wear resistance of the compressor is improved, and the efficiency of a refrigerating and air-conditioning apparatus using the compressor is enhanced.