The application discloses a multilayer
phase change all-year energy-saving material and a preparation method thereof. The material comprises, from inside to outside, a carbonized substrate layer, a
radiation energy collecting layer and a
phase change radiation switch layer. The carbonized substrate layer is made of carbonized material
slurry. The raw materials of the
phase change radiation switch layer comprise modified nano
vanadium dioxide 0.5-25 parts, a
polymer substrate 20-60 parts,
acetone 130-200 parts and
zirconium dioxide 0.2-15 parts in terms of
mass fraction. In the multilayer phase change all-year energy-saving material, the phase change radiation switch realizes the switch change of transmission and reflection at different temperatures through the spectrum change of the
phase change material. The material has good radiation
refrigeration function in summer, has solar
reflectivity of more than 90% and atmospheric window
emissivity, has
solar transmittance of more than 70% in winter, absorbs
solar heat through the radiation energy collecting layer to realize building heat absorption, and realizes all-year energy saving.