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45 results about "Epoxy amine" patented technology

An amine cured epoxy coating is an epoxy coating where an anime-based hardener was used in the curation process. In the most general sense, these epoxy coatings are described on the molecular level as having anime and alcohol functional groups formed during the curing. Four classes of amine hardeners are available: Aliphatic amines.

Waterborne epoxy resin coating as well as preparation method and application thereof

The invention discloses a water-borne epoxy resin coating which comprises a component A and a component B, the component A is prepared from 60 to 80 parts of 50 percent modified water-borne epoxy resin emulsion, 5 to 15 parts of deionized water, 0.5 to 1 part of wetting dispersant, 0.2 to 0.8 part of defoaming agent, 5 to 10 parts of modified zinc phosphate, 3 to 5 parts of ion exchange antirust pigment, 4 to 6 parts of sericite powder, 3 to 5 parts of glass flake, 5 to 10 parts of precipitated barium sulphate, 1 to 5 parts of nano silicon dioxide and 0.5 to 1 part of rheological additive; 1 to 2 parts of modified organic bentonite slurry; 0.1 to 0.3 part of a pH conditioning agent; and 0.2 to 0.8 part of a flash rust inhibitor. The component B is prepared from 40 to 50 parts of waterborne epoxy-amine adduct, 20 to 30 parts of 50 percent modified polyamide curing agent, 5 to 15 parts of 60 percent Mannich base phenolic aldehyde amine curing agent, 0.5 to 1.5 parts of epoxy silane coupling agent, 1 to 2 parts of nonionic surfactant and 15 to 20 parts of deionized water. The emulsion stability of the waterborne epoxy resin coating is improved through a bisphenol A / F mixed epoxy emulsion and a grafted polyethylene glycol hydrophilic chain segment.
Owner:HUIZHOU DADONG PAINT CO LTD

New energy battery packaging film and preparation method thereof

ActiveCN120574423AMasterbatchPolymer science
The invention relates to the technical field of outer layer materials of aluminum-plastic films for battery packaging, and discloses a new energy battery packaging film and a preparation method thereof.The preparation method comprises the steps that in a molten state and under the action of a free radical initiator, a self-made grafting monomer is grafted to a molecular main chain of LLDPE resin through a free radical graft copolymerization reaction, and epoxy LLDPE master batches are prepared; the preparation method comprises the following steps: based on an epoxy-amido ring-opening reaction mechanism, carrying out melt blending on an epoxy-based LLDPE master batch and PA6 resin to generate a bridging type PA6-LLDPE composite master batch, and carrying out blow molding to prepare a PA6-LLDPE film; a PA6-LLDPE film is used for replacing an outer layer PA6 film in an aluminum plastic film, and the new energy battery packaging film is prepared. The prepared PA6-LLDPE film product can replace an outer layer pure PA6 film of an aluminum plastic film to be used for packaging a battery which is high in product falling risk and few in burrs in the assembling process, so that the beneficial technical effect of reducing the overall production cost of the aluminum plastic film is achieved.
Owner:SUZHOU ZIJIN PLASTIC

Long-acting anticorrosive epoxy primer and preparation method thereof

The invention relates to a long-acting anticorrosive epoxy primer and a preparation method thereof, and belongs to the technical field of protective coatings. The primer is a two-component system, a component A comprises epoxy resin and a thermal latent cationic initiator, and a component B comprises an amine curing agent and alkaline silane. The decomposition temperature of the initiator is designed to be matched with the exothermic peak of epoxy-amine curing reaction, and hydrolytic condensation of alkaline silane is triggered in the curing process, so that a compact composite structure is formed. According to the structure, the adhesive force, the shielding property and the medium permeability resistance of the coating are effectively improved, and the long-acting corrosion resistance of the coating is remarkably enhanced. The invention further provides a corresponding preparation method which is simple and controllable in process and suitable for protection of metal components in a harsh corrosion environment.
Owner:ZHONGSHAN UBEST TECH CO LTD

Composite material hollow plate and preparation method thereof

ActiveCN121424766AGlass/slag layered productsEpoxy amineHigh surface
The invention discloses a composite material hollow plate and a preparation method, and belongs to the technical field of composite material plate preparation. The composite material hollow plate comprises an outer plate and an inner plate, a plurality of corrugated supporting structures are connected between the outer plate and the inner plate, and a cavity is formed between every two adjacent corrugated supporting structures. A wear-resistant reinforcing agent is added into an outer plate material to improve the surface wear resistance, an epoxy-amine dual-core double-wall microcapsule is introduced into an inner plate material to enhance the crack repairing capacity, and a shape memory reinforcing agent is added into a corrugated supporting structure material to endow the material with the shape memory characteristic. The invention solves the technical problems of difficulty in consideration of strength and toughness, short service life, poor buffer performance, insufficient interface bonding strength and the like of the existing composite material hollow plate, and is particularly suitable for steel coil packaging and other application scenes requiring repeated use and high reliability.
Owner:BENXI HETENG TECH DEV CO LTD

A rapidly curable waterborne acrylic-modified epoxy resin emulsion for multi-substrate coating and a preparation method thereof

The application discloses a kind of for multi-substrate coating fast-curable water-based acrylic modified epoxy resin emulsion and its preparation method, first by itaconic acid, alcohol ether solvent and bisphenol A type epoxy resin synthesis epoxy adduct intermediate product, then with other acrylic monomer free radical polymerization is formed acrylic modified epoxy resin with this intermediate product, finally using additional epoxy emulsifier by phase inversion method is made water-based acrylic modified epoxy resin emulsion.The emulsion prepared in the application has higher glass transition temperature, has faster surface dry and curing speed, can satisfy the fast curing of coating film on various substrate workpieces, workpiece offline stacking resistance requirements;Side chain contains a certain amount of carboxyl and hydroxyl, can give coating excellent adhesion, realize good adhesion on various substrates;Resin structure contains a certain amount of bisphenol A type epoxy resin, and epoxy-amine curing agent is well compatible after curing, and coating is uniform.
Owner:CNOOC CHANGZHOU PAINT & COATINGS IND RES INST +2

High-thermal-stability epoxy amine adduct, single-component pouring sealant and preparation process

The invention discloses a high-thermal-stability epoxy amine adduct, a single-component pouring sealant and a preparation process of the high-thermal-stability epoxy amine adduct, the high-thermal-stability epoxy amine adduct is prepared by reacting a single-epoxy compound containing a cyclic structure, aromatic polyamine and a double-epoxy compound containing a flexible chain segment according to a specific molar ratio, and the molecular structure of the high-thermal-stability epoxy amine adduct has rigidity, flexibility and latency; the single-component pouring sealant taking the addition product as a curing agent comprises epoxy resin, the addition product, inorganic filler, a silane coupling agent and the like, the pouring sealant can be stably stored at room temperature, a three-dimensional network structure formed after heating and curing is compact, and the pouring sealant has high glass transition temperature, high thermal decomposition temperature and excellent long-term thermal aging performance; and the epoxy resin is especially suitable for potting protection of electronic components with extremely high requirements on heat resistance and reliability.
Owner:SHENZHEN DST TECH CO LTD

Epoxy damping prepreg resin of epoxy / amine dual-curing system and preparation method of epoxy damping prepreg resin

PendingCN120923720APolymer scienceSide chain
The invention discloses epoxy damping prepreg resin of an epoxy / amine dual-curing system and a preparation method of the epoxy damping prepreg resin, and belongs to the technical field of prepreg resin preparation. The preparation method of the epoxy damping prepreg resin of the epoxy / amine dual-curing system comprises the following steps: grafting a polyurethane flexible chain segment to an epoxy resin side chain segment to prepare epoxy-terminated urethane resin; mixing the epoxy-terminated urethane resin with polyether triamine, and carrying out pre-curing, so as to obtain pre-cured resin; and mixing the pre-cured resin, dicyandiamide and a diaminoimidazole triazine complex, and carrying out final curing, so as to obtain the epoxy damping prepreg resin of the epoxy / amine dual-curing system. By regulating and controlling the curing degree, on the basis that the viscosity, viscosity and the like of the resin are freely adjusted to meet the requirements of a production process, the tensile strength, modulus, short-time bending creep and other mechanical properties of the prepreg resin cannot be greatly changed due to the adjustment of the viscosity and the viscosity, and meanwhile, the damping performance of the prepreg resin can be remarkably improved.
Owner:NAVAL UNIV OF ENG PLA

A perfluoroalkylsilane coupling agent for surface modification of a material and a method for preparing the same

The present application relates to the technical field of surface modification materials, and particularly relates to a perfluoroalkyl silane coupling agent for material surface modification and a preparation method thereof. The coupling agent comprises synergistically modified perfluoroalkyl triethoxysilane, an organic small-molecule functional regulator, an acid catalyst, a surfactant, a stabilizer, ethanol and deionized water. The synergistically modified perfluoroalkyl triethoxysilane is prepared by synergistic modification of perfluoroalkyl triethoxysilane, monohydroxyl column [5] arene, octakis(glycidyl ether propyl) silsesquioxane, N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and 2,6-pyridine dimethyl formaldehyde through host-guest inclusion, epoxy-amine ring-opening reaction and Schiff base condensation reaction, and the organic small-molecule functional regulator is 9,10-dihydroxyanthracene. The preparation method is simple and suitable for surface modification of various substrates such as glass, metal, ceramic and polymer materials.
Owner:GUANGZHOU LYCRA FLUOROSILICONE HIGH-TECH MATERIALS CO LTD

Cross-linked polyester resin

The present invention provides a cross-linked polyester resin that exhibits high strength at room temperature through dynamic covalent crosslinking that allows for bond exchange at high temperatures. Above its softening temperature, it is reprocessable and allows for inter-film adhesion and self-healing. Furthermore, even without the addition of an ester exchange catalyst, it exhibits softening behavior based on bond exchange in the ester exchange reaction, demonstrating self-adhesion, reformability, and damage repair properties. A cross-linked polyester resin is obtained by cross-linking a polyester resin having carboxyl groups on its side chains with an epoxy crosslinker having multiple epoxy groups. The epoxy crosslinker comprises an epoxyamine compound having two or more tertiary amino groups and two or more epoxy groups within the molecule, with the epoxyamine compound being present in an amount of 3 to 30 moles per 100 moles of carboxyl groups in the polyester resin having carboxyl groups on its side chains.
Owner:TOYOBO CO LTD

An aldehyde-trapping self-healing waterborne coating and a method of making the same

PendingCN122278287APolymer scienceSide chain
This invention relates to the field of polymer fine chemical materials and the synthesis technology of special functional waterborne coatings, specifically to an aldehyde-capturing self-healing waterborne coating and its preparation method. The invention discloses an aldehyde-capturing self-healing waterborne coating and its preparation method. This coating uses a side-chain carboxylated ketone-containing waterborne polyurethane-acrylate composite emulsion as the core film-forming material, forming dynamic hydrazone crosslinks with adipic acid dihydrazide, and introducing an epoxy-amine permanent crosslinking network. The side-chain carboxyl groups are derived from maleic anhydride grafted and undergo ring-opening transformation upon contact with water, and are covalently fixed to the polymer side chains, preventing the migration of small molecule acids and ensuring coating storage stability. After the coating cures, environmental moisture triggers the dissociation of side-chain carboxyl groups, releasing protons and catalyzing the dynamic exchange of hydrazone bonds, achieving room-temperature self-healing. Excess hydrazone groups in the coating capture aldehyde pollutants, and the newly generated hydrazone bonds introduce polar groups and crosslinking sites, enhancing network stability.
Owner:SHOUBANG CHEM CO LTD GAOMING DISTRICT FOSHAN CITY

Aqueous coating composition containing an epoxy-amine system and an aromatic carboxylic acid as curing catalyst

Disclosed herein is an aqueous coating composition containing an aqueous epoxy resin dispersion, an aqueous amine-functional resin dispersion and an aromatic carboxylic acid. The aqueous dispersion contains at least one specific di- and / or polyfunctional monomeric amine and at least one resin component including at least one specific polyfunctional organic amine. Further disclosed herein is a kit-of-parts including a base varnish containing the aqueous epoxy resin dispersion and a curing component containing the aqueous amine-functional resin dispersion as well as the aromatic carboxylic acid. Additionally disclosed herein is a process for producing a coating on the substrate as well as coated substrates resulting from said process. Cured coating layers formed from said compositions exhibit a good adhesion to the substrate as well as a high intercoat adhesion and blistering stability under humidity conditions without negatively influencing the excellent sandability and the good stone chipping properties.
Owner:BASF COATINGS GMBH

Bi-component aliphatic polyamine epoxy graphene acid-resistant coating

The invention belongs to the technical field of epoxy resin coatings, and particularly relates to a bi-component aliphatic polyamine epoxy graphene acid-resistant coating which comprises epoxy resin in a component A and a curing agent in a component B. The curing agent is perfluoroalkyl secondary amine. Alicyclic diamine and perfluoroalkyl ethylene are subjected to a Michael addition reaction under the action of a catalyst cupric trifluoroacetate, the cupric trifluoroacetate catalyst effectively prevents the perfluoroalkyl ethylene and a generated target product secondary amine from being further subjected to an excessive addition reaction, and the reaction efficiency is improved; after the curing agent is subjected to cross-linking reaction with the epoxy resins in the scheme, a large number of ether bonds existing in a traditional phenolic epoxy amine curing system can be eliminated, so that nucleophilic reagent attack sites are reduced, meanwhile, the curing agent perfluoroalkyl secondary amine is converted into a tertiary amine structure, coordination activation of H to nitrogen atoms is reduced, and a coating is more stable.
Owner:JIANGSU BANGJIE ANTI CORROSION THERMAL INSULATIONTECH

A high-adhesion silicone resin antibacterial and anticorrosive coating and its preparation method

The present invention belongs to the field of intelligent organosilicon polymer materials, and provides a kind of high-adhesion silicone resin antibacterial, anticorrosive coating and preparation method thereof.By organosilane modified natural antibacterial agent dehydroabietic acid, it is introduced into silicone resin system, and the antibacterial performance of silicone resin coating is improved.Using 3-aminopropyl triethoxysilane (KH-550) and γ-glycidyl ether oxygen propyl trimethoxysilane (KH-560) as raw materials, multifunctional siloxane (MF-S) is synthesized, as epoxy-amine curing agent, by condensation reaction, the cross-linking density of methylphenyl silicone resin is increased, so that it has excellent mechanical properties.After the obtained coating is cured at room temperature, the hardness reaches more than 6H, the adhesion reaches 1 grade, and the tensile strength of the obtained film reaches 9MPa.The silicone resin coating prepared by the present invention has good antibacterial performance, antifouling performance and anticorrosive performance, and the preparation method is simple and efficient, strong in practicality, has broad application prospects, and is conducive to realizing industrialized production.
Owner:QINGDAO ENERGY TECH CO LTD +1

Water-based high-solid epoxy micaceous iron oxide intermediate paint for heavy-duty anticorrosion, and preparation method and application thereof

The application discloses a water-based high-solid-content epoxy micawHITE intermediate paint for heavy-duty corrosion protection and a preparation method and application thereof, and comprises components A and B; the component A comprises water-based epoxy dispersion, a toughening agent, titanium barium powder, micawHITE and polyamide wax paste; the solid content of the water-based epoxy dispersion is not less than 70%, and the epoxy equivalent of the water-based epoxy dispersion is 270-330; the component B comprises water-based epoxy amine curing agent, micawHITE and polyamide wax paste; the HLB value of the water-based epoxy amine curing agent is 10-18, and the solid content is greater than 50%. When the curing agent is added during construction, only a small amount of water is needed to dilute, so that the construction viscosity and requirements of airless spraying can be achieved. The water-based high-solid-content epoxy micawHITE intermediate paint for heavy-duty corrosion protection prepared by the application has high film thickness for one-time construction, can reach a dry film of more than 180 microns, and can meet the construction requirements of heavy-duty corrosion protection paint, and the paint film is not cracked, has no thick edges, and does not sag.
Owner:BEIXIN JIABAOLI COATINGS (GUANGDONG) CO LTD

Electric leakage response thin film material and preparation method and application thereof

The invention belongs to the technical field of electrochromic materials, and particularly relates to an electric leakage response film material and a preparation method and application thereof. The invention relates to an electric leakage response film material, which is a single composite layer and comprises a cross-linked polymer matrix formed by polyethylene glycol diglycidyl ether and polyether amine through an epoxy-amine reaction; the tungsten trioxide particles are dispersed in the cross-linked polymer matrix; and a source of lithium ions dispersed in the cross-linked polymer matrix.
Owner:YUNNAN POWER GRID CO LTD ELECTRIC POWER RES INST +2

Electrocoating composition

Cathodic electrocoating composition with improved edge protection and coating appearance are provided. An exemplary cathodic electrocoating composition includes an aqueous carrier, a film forming binder dispersed in the carrier and including an epoxy-amine adduct and a blocked polyisocyanate crosslinking agent; a pigment paste; a water-soluble cellulose ether; and a cationic microgel dispersion which is prepared by a process comprising dispersing in aqueous medium a mixture of a cationic polyepoxide-amine reaction product which contains amine groups selected from the group consisting of primary amine groups, secondary amine groups, and mixtures thereof and a polyepoxide crosslinking agent and heating the mixture to a temperature sufficient to crosslink the mixture to form the cationic microgel dispersion. The water-soluble cellulose ether may be hydroxyethyl cellulose.
Owner:AXALTA COATING SYSTEMS IP CO LLC

Remaining water resource recycling system for epichlorohydrin rectifying still

The utility model relates to the technical field of wastewater filtration and recovery, and provides a waste water recycling system for an epichlorohydrin rectifying still, which is used for recycling the wastewater of the epichlorohydrin rectifying still and comprises a security filter I, an electrodialysis device, a waste water recycling device and a waste water recycling device, the electrodialysis device is used for separating organic matters and high-salinity water in the wastewater, the filter device I is communicated with the electrodialysis device through a booster pump I, the membrane concentration piece I is communicated with the filter device I through a high-pressure pump II, and the membrane concentration piece I is used for separating moisture and organic matters in the wastewater. The problem that wastewater generated in the production process of epoxy aminopropane cannot be purified and recycled in the prior art is solved.
Owner:RIGHTLEDER (SHANGHAI) TECH CO LTD

Biodegradable lubricating oil and preparation method thereof

The invention belongs to the technical field of biodegradable lubricating oil, and particularly discloses biodegradable lubricating oil and a preparation method thereof. The biodegradable lubricating oil provided by the invention is prepared from the following components in parts by mass: 25 to 35 parts of modified composite vegetable oil, 2 to 8 parts of methacrylate grafted modified chitin nanocrystals, 4 to 9 parts of a thickening agent, 0.5 to 1.5 parts of an antioxidant and 0.5 to 1.0 part of a tackifier. According to the invention, the composite vegetable oil subjected to epoxy-amine ring opening modification is used as basic lubricating oil, and then methacrylate grafted modified chitin nanocrystals and other additives are introduced, so that the plant-based lubricating oil has high wear resistance and excellent extreme pressure property, and also has the properties of low condensation point, biodegradability and the like.
Owner:HEBEI JINGU RECYCLING RESOURCES DEV

Multi-color injection molding process for smart wearable devices

The present application relates to the technical field of material processing, and discloses a multi-color injection molding process for intelligent wearable equipment, which comprises the following steps: preparing hard granules by melt extruding polybutylene terephthalate resin and epoxy-containing styrene-acrylonitrile copolymer; preparing soft granules by mixing thermoplastic polyurethane elastomer and amino-terminated hyperbranched polyamide-ester auxiliary; laser etching the hard skeleton bonding surface to form microtexture; and using segmented speed control in the second injection molding, using the shear friction heat generated by high-speed pulse injection to activate the epoxy-amine chemical cross-linking reaction at the interface. The present application realizes the firm combination of hard and soft materials without adhesives through the synergistic mechanism of rheological matching and in-situ chemical bonding, significantly improves the bonding strength and moisture and heat aging resistance of the interface, simplifies the process flow, and is suitable for the precision manufacturing of intelligent wearable equipment.
Owner:SHENZHEN BSC TECHNOLOGY CO LTD

Antibacterial high-elasticity foam and preparation method thereof

The invention relates to the technical field of foam, and discloses antibacterial high-elasticity foam and a preparation method thereof, and the foam is prepared from the following raw materials: low-density polyethylene, aminated polyethylene, an epichlorohydrin modified ethylene-octene copolymer, a foaming agent, a sensitizing agent and an antioxidant. Aminated polyethylene and an epichlorohydrin modified ethylene-octene copolymer are introduced into raw material components of the antibacterial high-elasticity foam, an irradiation crosslinking process is combined, quaternization reaction of the aminated polyethylene and the epichlorohydrin modified ethylene-octene copolymer forms an antibacterial active center, and quaternary ammonium salt provides lasting antibacterial property; the epoxy-amido ring-opening reaction of the two is carried out to construct a covalent cross-linked structure to enhance the compressive deformation resistance of the material; the epoxy chloropropane modified ethylene-octylene copolymer and the low-density polyethylene matrix form an island structure, impact energy is absorbed through elastic deformation, and the rebound resilience of the material is improved. Through mutual cooperation of the raw materials, the antibacterial property, antibacterial durability and rebound resilience of the foam are effectively improved.
Owner:河南纳美纺织科技有限公司

Acetoacetic acid esterified water-borne epoxy resin as well as preparation method and application thereof

The invention discloses acetoacetic acid esterified water-borne epoxy resin in the technical field of epoxy resin, and the acetoacetic acid esterified water-borne epoxy resin is prepared from the following raw materials in parts by weight: 3-8% of an emulsifier, 0-25% of an epoxy compound, 40-60% of acetoacetic acid esterified epoxy resin, 0-10% of a solvent and 30-50% of deionized water. The problems that an existing waterborne epoxy system is insufficient in chemical resistance, an epoxy-amine system is slowly cured in a low-temperature and high-humidity environment, and the construction efficiency is affected are solved, multifunctional resin with dual reaction activity is created, and waterborne epoxy resin with the environment-friendly advantage is obtained by emulsifying the multifunctional resin through an emulsifier of a special structure.
Owner:JIANGSU FUQISEN NEW MATERIAL CO LTD

Disposable isolation plug with long-acting anti-aging performance and preparation process of disposable isolation plug

The invention discloses a disposable isolation plug with long-acting aging resistance and a preparation process thereof, belongs to the technical field of isolation material preparation, and aims to solve the technical problem that the aging resistance and solvent resistance of a disposable isolation plug in the prior art need to be further improved. According to the invention, a silicon-oxygen hybrid triazine compound is adopted as a matrix, the silicon-oxygen hybrid compound is introduced to construct a stable spatial network, and silicon shell triazine microspheres and epoxy amine cured flexible particles are assisted to jointly adjust the interface structure and chain segment motion characteristics of the material; the obtained disposable isolation plug forms a structural system with balanced support and recoverable deformation capability, and all the components form a continuous and stable mechanical response path in the system, so that the material shows low compression permanent deformation rate and good size retentivity under the conditions of normal temperature, high temperature, soaking and aging.
Owner:RUIJIA YIXING TECH

Epoxy amine (METH)acrylate hydroxy urethane resin composition

A two-part epoxy resin composition is provided comprising: a first resin part comprising a modified hydroxy alkyl urethane and an epoxy component; and a second resin part comprising an amine component; wherein the modified hydroxy alkyl urethane is formed by a reaction between a (meth)acrylate monomer or oligomer and a hydroxy alkyl urethane having the formula: (Formula (I)); where: R1 is an amine residue; and R2 and R3 are the same or different and are selected from the group consisting of H, alkyl, and hydroxyalkyl.
Owner:SPIDER RESIN LIMITED

Epoxy cement composite mortar as well as preparation method and application thereof

PendingCN120681997ACellulosePolymer science
The invention relates to the technical field of building materials, and particularly discloses epoxy cement composite mortar as well as a preparation method and application thereof. The epoxy cement composite mortar comprises a cement-based mortar component and a waterborne epoxy-amine system cross-linked polymer, the cement mortar comprises the following raw materials: Portland cement, medium sand, a filler, polyether polyol, poly (ethylene glycol) methyl ether methacryloyl acid, a defoaming agent and cellulose acetate butyrate. The waterborne epoxy-amine system cross-linked polymer comprises the following raw materials: waterborne epoxy resin, a polyamide curing agent, propylene glycol monomethyl ether and zinc acetylacetonate. The epoxy cement composite mortar obtained in the invention has good flowability and leveling property, can realize self-leveling construction, and has 7d and 28d compressive strength, bonding strength and breaking strength up to 50.1 MPa, 100.4 MPa, 8.1 MPa and 17.5 MPa to the maximum extent, and the strength of the epoxy cement composite mortar is improved.
Owner:SHIJIAZHUANG CHAOSHUO FLOORING PROJECTS CO LTD

Network toughening of additively manufactured, high glass transition temperature materials via sequentially cured, interpenetrating polymers

Resins and formulations of individual monomers bearing both vinyl ester and epoxy functionality were either synthesized or formulated such that vinyl ester components capable of polymerizing by photo-induced, free radical polymerization were mixed with step-growth epoxy-amine systems, facilitating sequential cure. The vinyl ester component was photopolymerized using vat photopolymerization (VPP). Additionally, the preparation of bio-based photo curable thermosetting resins that have tailorable thermal and mechanical properties is provided. All monomers and polymers described herein are useful in a variety of applications, including additive manufacturing applications.
Owner:UNITED STATES OF AMERICA THE AS REPRESENTED BY THE SEC OF THE ARMY +1

Adhesion promoting compounds and uses thereof

The present invention relates to novel compounds and their use as adhesion promoting additives. In particular, the present invention relates to additives for promoting adhesion between epoxy amines and polysiloxanes. In marine and protective coating applications, the additives are particularly useful for promoting adhesion between epoxy amine coatings and polysiloxane coatings. The present invention also relates to methods of promoting adhesion between epoxy amines and polysiloxanes.
Owner:NORTHUMBRIA UNIV SERVICES LTD

An aminated resin material, its preparation and application

The present invention relates to an aminated resin material and its preparation and application. The aminated resin uses anisotropic microspheres (Janus) as the matrix, and then atomic transfer radical polymerization (ATRP) technology is used to graft polymer brushes on the surface of the microspheres to increase the density of functional groups on the microsphere surface. Finally, amino groups are introduced onto the microsphere surface through an epoxy-amine ring-opening reaction to obtain the aminated resin, which is used as a metal ion adsorption material. The present invention has the characteristics of simple equipment, pure products, monodispersity, and uniform pore size. The preparation of the aminated resin in the present invention has the advantages of controllable operation and simple method.
Owner:DALIAN INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES +1

Preparation method and application of polyhydroxy phosphine-nitrogen flame retardant

The invention relates to a preparation method and application of a polyhydroxy phosphine-nitrogen flame retardant, the polyhydroxy phosphine-nitrogen flame retardant is prepared by recycling nitrogen-containing polyol in a thermosetting ester epoxy / amine cured product degradation product and further reacting, and the preparation method comprises the following steps: (1) carrying out alcoholysis on a thermosetting ester epoxy / amine cured product by using ethylene glycol and sodium hydroxide to obtain degradation liquid; (2) filtering the degradation liquid, carrying out rotary evaporation to remove ethylene glycol, aging with ethanol to remove salt, adjusting the pH value to be neutral, and carrying out rotary evaporation to obtain nitrogen-containing polyol EP / N-8OH; and (3) mixing the EP / N-8OH with triethylamine and tetrahydrofuran, dropwise adding diphenyl phosphinyl chloride under the protection of nitrogen, and performing treatment after reaction to obtain P, P-diphenyl phosphinic acid-3-[(5-{[bis (2, 3-dihydroxypropyl) amino] methyl}-3, 3, 5-trimethyl cyclohexyl) (2, 3-dihydroxypropyl) amino]-2-hydroxypropyl ester (polyhydroxy phosphine nitrogen flame retardant, DPP-P). The application method comprises the following steps: mixing DPP-P with bisphenol A epoxy resin E-51, a curing agent 1, 2, 3, 6-tetrahydrophthalic anhydride and a catalyst N, N-dimethylamine, and carrying out preheating, defoaming and stepped heating curing, so that the prepared flame-retardant modified epoxy resin E51-DPP-P has good flame retardance and mechanical properties.
Owner:SOUTHWEAT UNIV OF SCI & TECH

Composite hollow panel and method of manufacture

ActiveCN121424766BGlass/slag layered productsEpoxy amineHigh surface
The application discloses a kind of composite hollow plate and preparation method, belong to composite plate preparation technical field.Composite hollow plate includes outer plate and inner plate, and a plurality of corrugated support structures are connected between outer plate and inner plate, and adjacent corrugated support structures are cavity.Outer plate material is added wear-resistant reinforcing agent to improve surface wear resistance, and epoxy-amine binuclear double-wall microcapsule is introduced in inner plate material to enhance crack repair ability, and shape memory reinforcing agent is added in corrugated support structure material to give material shape memory characteristics.The application solves the technical problems that the strength and toughness of the existing composite hollow plate are difficult to consider, the service life is short, the cushioning performance is poor, and the interface bonding strength is insufficient, and is especially suitable for steel coil packaging and other application scenarios that require repeated use and high reliability.
Owner:BENXI HETENG TECH DEV CO LTD