The invention discloses a carbon
fiber modified with a crystalized crosslinkable
polyaryletherketone sizing agent and a preparation method of the carbon
fiber and belongs to technical field of carbonfiber surface treatment. The preparation method includes subjecting double-
fluorine monomer containing
aniline side groups and
bisphenol monomers to
polymerization, or modifying crystalized
polyaryletherketone, so as to obtain soluble amorphous
polyaryletherketone polymer, and blocking thermotropic crosslinking groups to two terminals of the
polymer; meanwhile, subjecting the carbon
fiber to surface electrochemical reduction, and
grafting the crosslinking groups which are the same as the mentioned to the surface of the carbon fiber; further, drafting the carbon fiber which is subjected to thesurface electrochemical reduction to pass through a
sizing agent solution to size the carbon fiber, and performing acidification to recover the
crystallinity of the polyaryletherketone
sizing agent; finally, finishing the carbon fiber. The carbon fiber can be used for preparing a
composite material, the
composite material is subjected to high-heat treatment, so that the crosslinking reaction is initiated, the
crystallinity of the polyaryletherketone
polymer is improved, the sizing agent is allowed to have a crystalline texture and can form a chemical bonding with the surface of the carbon fiber, and further, the interference
shear strength is improved, and the
composite material has high
temperature resistance and
corrosion resistance performance.