The invention discloses a carbon 
fiber modified with a crystalized crosslinkable 
polyaryletherketone sizing agent and a preparation method of the carbon 
fiber and belongs to technical field of carbonfiber surface treatment. The preparation method includes subjecting double-
fluorine monomer containing 
aniline side groups and 
bisphenol monomers to 
polymerization, or modifying crystalized 
polyaryletherketone, so as to obtain soluble amorphous 
polyaryletherketone polymer, and blocking thermotropic crosslinking groups to two terminals of the 
polymer; meanwhile, subjecting the carbon 
fiber to surface electrochemical reduction, and 
grafting the crosslinking groups which are the same as the mentioned to the surface of the carbon fiber; further, drafting the carbon fiber which is subjected to thesurface electrochemical reduction to pass through a 
sizing agent solution to size the carbon fiber, and performing acidification to recover the 
crystallinity of the polyaryletherketone 
sizing agent; finally, finishing the carbon fiber. The carbon fiber can be used for preparing a 
composite material, the 
composite material is subjected to high-heat treatment, so that the crosslinking reaction is initiated, the 
crystallinity of the polyaryletherketone 
polymer is improved, the sizing agent is allowed to have a crystalline texture and can form a chemical bonding with the surface of the carbon fiber, and further, the interference 
shear strength is improved, and the 
composite material has high 
temperature resistance and 
corrosion resistance performance.