A UV curable composition containing a mixture of free radical polymerizable monomers and a APO
photoinitiator according to formula (I), wherein R1 is selected from the group consisting of an
alkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an alkaryl group and an
aryl group or a heteroaryl group; R2 and R3 are independently selected from an
alkyl group and an
alkoxy group; R4 is selected from a
hydrogen, an
alkyl group and an
alkoxy group; X and Y are independently selected from an
oxygen atom, a
methylene group, a - C(=CH2)- group, and a
carbon atom present in a group selected from a
straight chain alkylene group, an alkenylene group, an
arylene group, a heteroarylene group and a cycloalkylene group; L represents a
divalent linking group selected from the group consisting of an unsubstituted alkylene group, an
arylene group, a heteroarylene group, a cycloalkylene group, a substituted alkylene group substituted by one or more
ether groups, a substituted alkylene group substituted by one or more substituents selected from the group consisting of an
aryl group, a heteroaryl group, an
arylene group, a heteroarylene group, a cycloalkylene group, an ester group, an
amide group, an amine group, an
ether group, a
thioether group, a
ketone group, an
aldehyde group, a
sulfoxide group, a
sulfone group, a
sulfonate ester group, a sulphonamide group, -Cl, -Br, -I, -OH, - SH, -CN and -NO2; and wherein the UV curable composition is free of a
photoinitiator including 2 monoacyl
phosphine oxide moieties linked to each other via their
acyl group and wherein the 2 monoacyl
phosphine oxide moieties have a
chemical structure differing in the
phosphine oxide part. Cured products and
inkjet printing methods with the
radiation curable compositions are also disclosed.