PET-based graphene composite material, preparation method thereof, and aerostat

A composite material and graphene technology, applied in the direction of rigid spacecraft, etc., can solve the problems of poor dispersion of graphene oxide, and achieve the effects of improved dispersion, excellent gas barrier and mechanical strength, and simple process

Active Publication Date: 2016-08-03
LUOYANG INST OF CUTTING EDGE TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology allows for improved dispersion or solubility of carbon nanoparticles (CNs) into polyethyleneglycols (PEG). By mixing certain chemical substances together during synthesis, CN particles can be made more easily dissolved when mixed with other molecules like water. These special compounds improve the performance of these films by making them stronger against impact force compared to traditional methods that use pure hydroxypropyltrimonium bromate (HTPB), which makes their film weaker at high pressure. Additionally, this new approach simplifies the manufacturing processes used to make such films without requiring expensive precursors.

Problems solved by technology

This patented technical solution describes how poly ethylenetterephthafonate (PET), or another type of plastic called polytetrafluorobutylethermalimberplifier(PTFE)) can be made into useful products such as pipings, tubular structures, insulation foam sheets, electronics applications, etc., while also improving their overall characteristics like heat conductivity, moisture protection, and gas blocking capabilities. Additionally, there have been attempts to create PE/graphite nanofibril Composites containing both graphene flakes and fullerenic layers on top of each other. These new methods aim to overcome difficulties associated with producing pure graphene without impurities from previous processes.

Method used

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  • PET-based graphene composite material, preparation method thereof, and aerostat
  • PET-based graphene composite material, preparation method thereof, and aerostat

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preparation example Construction

[0023] In order to solve the problem of poor dispersion of graphene oxide in the PET-based graphene composite material formed by the prior art melt blending method, in a typical implementation of the present application, a preparation of a PET-based graphene composite material is provided The method, the preparation method includes: step S1, the graphene oxide modified by ethylene glycol and the PET monomer are subjected to an esterification reaction or a transesterification reaction to obtain an initial product, and the PET monomer is terephthalic acid and / or terephthalic acid Dimethyl ester; Step S2, making the initial product undergo polycondensation reaction to obtain a PET-based graphene composite material.

[0024] The ethylene glycol-modified graphene oxide is in-situ polymerized with the PET monomer, and the graphene oxide is dispersed in it while the ethylene glycol is reacted with the PET monomer, thereby improving the composite of graphene on the PET-based graphene. ...

Embodiment 1

[0042] Take by weighing 5g polyvinylpyrrolidone (PVP) and add in the ethylene glycol of 600ml and stir at room temperature until completely dissolving to form ethylene glycol solution; Add 5g graphene oxide powder in this ethylene glycol solution, the exfoliation of this graphene oxide powder The thickness is 3nm, the length is 50μm, and the colloidal solution of ethylene glycol-modified graphene oxide is obtained by ultrasonic treatment with a power of 500W for 2 hours; the prepared graphite oxide is added to a 5L polymerization kettle with nitrogen gas inlet and outlet and mechanical stirring Ethylene glycol colloid solution and 1000g of terephthalic acid (PTA) (wherein the molar ratio of ethylene glycol to terephthalic acid is 1.5:1), 0.3gSb 2 o 3 , start mechanical stirring, and replace the air in the polymerization kettle with high-purity nitrogen at the same time, replace it 4 times, make the pressure in the polymerization kettle 0.2MPa, raise the temperature of the poly...

Embodiment 2

[0044] Take by weighing 5g polyvinylpyrrolidone (PVP) and add in the ethylene glycol of 600ml and stir at room temperature until completely dissolving to form ethylene glycol solution; Add 5g graphene oxide powder in this ethylene glycol solution, the exfoliation of this graphene oxide powder The thickness is 3nm, the length is 50μm, and the colloidal solution of ethylene glycol-modified graphene oxide is obtained by ultrasonic treatment with a power of 500W for 2 hours; the prepared graphite oxide is added to a 5L polymerization kettle with nitrogen gas inlet and outlet and mechanical stirring Ethylene glycol colloid solution and 1000g of terephthalic acid (PTA) (wherein the molar ratio of ethylene glycol to terephthalic acid is 1.5:1), 0.3gSb 2 o 3 , start mechanical stirring, and replace the air in the polymerization kettle with high-purity nitrogen at the same time, replace it 4 times, make the pressure in the polymerization kettle 0.4MPa, raise the temperature of the poly...

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Abstract

The invention provides a PET-based graphene composite material, a preparation method thereof, and an aerostat. The preparation method comprises the following steps: 1, carrying out an esterification reaction or an ester interchange reaction on ethylene glycol modified graphene oxide and a PET monomer to obtain a head product, wherein the PET monomer is terephthalic acid and/or dimetyl terephthalate; and 2, carrying out a condensation polymerization reaction on the head product to obtain the PET-based graphene composite material. The in situ polymerization reaction of the ethylene glycol modified graphene oxide and the PET monomer is carried out to make graphene oxide be dispersed in the reaction process of ethylene glycol and the PET monomer, so the dispersibility of graphene in the PET-based graphene composite material is improved. The preparation method directly adopting the PET monomer as a raw material has the advantages of simple process, short preparation period, low cost, and suitableness for large-scale technologic production; and the PET-based graphene composite material prepared in the invention has excellent gas barrier property and mechanical strength.

Description

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Claims

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Application Information

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Owner LUOYANG INST OF CUTTING EDGE TECH
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