Water-based mortar modifier, its preparation method and application

A modifier and mortar technology, which is applied in the field of water-based mortar modifier and its preparation, can solve the problems of inaccurate measurement, the inability of mortar modifier to maintain mortar construction performance for a long time, and inconvenient use, so as to increase the Workability and plasticity, improving mortar workability, and reducing friction

Active Publication Date: 2012-11-21
GUANGZHOU CHEM CO LTD CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In view of the fact that the existing mortar modifiers cannot maintain the construction performance of the mortar for a long time, and the existing solid mortar modifiers have defects such as inconvenient use and inaccurate measurement, the primary purpose of the present invention is to provide a water-based mortar Modifier, the mortar modifier is a stable water agent, which can significantly improve the workability and viscosity of mortar, and effectively maintain the above properties for 8-16 hours

Method used

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  • Water-based mortar modifier, its preparation method and application
  • Water-based mortar modifier, its preparation method and application
  • Water-based mortar modifier, its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A water-based mortar modifier, prepared by the following steps:

[0034] (1) Preparation of polyether-type polycarboxylate superplasticizer: Dissolve 100 grams of acryl alcohol polyoxyethylene ether (molecular weight: 2400), 9.5 grams of acrylic acid, and 2.0 grams of maleic anhydride in 105 grams of water. Add 25 grams of ammonium persulfate aqueous solution (mass concentration 4.5%) dropwise, finish dropping within 120 minutes, keep warm at 65°C for 3 hours after the dropwise addition, then cool down to 45°C, add an appropriate amount of NaOH to neutralize, and adjust the pH of the system to 7 -8, to prepare a polyether polycarboxylate water reducer.

[0035] (2) Add 13% polyether polycarboxylate superplasticizer, 1% sodium lauryl sulfate, 0.5% sodium α-allyl sulfonate, 1.5% sodium gluconate, 3.0% three Sodium polyphosphate, 0.5% polyethylene glycol, 0.5% hydroxypropyl cellulose and 80% water are mixed and stirred evenly to obtain a water-based mortar modifier; The ...

Embodiment 2

[0037] A water-based mortar modifier, prepared by the following steps:

[0038] (1) Preparation of polyether-type polycarboxylate superplasticizer: Dissolve 100 grams of isobutylene alcohol polyoxyethylene ether (molecular weight 1200), 18 grams of acrylic acid, and 5 grams of maleic anhydride in 105 grams of water, and heat up to 70 ° C to evenly Add 30 grams of ammonium persulfate aqueous solution (mass concentration 6.0%) dropwise, and finish dropping within 150 minutes. After dropping, keep warm at 60°C for 4 hours, then cool down to 45°C, add an appropriate amount of NaOH to neutralize, and adjust the pH of the system to 7 -8, to prepare a polyether polycarboxylate water reducer.

[0039] (2) Add 11% polyether polycarboxylate superplasticizer, 3.0% sodium rosinate, 0.4% sodium fatty alcohol polyoxyethylene ether sulfonate, 1.5% sodium gluconate, 3.0% lignin sulfonate Sodium phosphate, 0.5% polyvinylpyrrolidone, 0.6% hydroxypropyl starch are mixed with 80% water, stirred ...

Embodiment 3

[0041] A water-based mortar modifier, prepared by the following steps:

[0042] (1) Preparation of polyether-type polycarboxylate superplasticizer: Dissolve 100 grams of isobutylene alcohol polyoxyethylene ether (molecular weight 3600), 7.5 grams of acrylic acid, and 1.2 grams of maleic anhydride in 105 grams of water, and heat up to 62 ° C to uniformly Add 32 grams of potassium persulfate aqueous solution (mass concentration 5.0%) dropwise, and finish the drop within 150 minutes. After the dropwise addition, keep warm at 60°C for 2 hours, then cool down to 45°C, add appropriate amount of NaOH to neutralize, and adjust the pH of the system to 7 -8, to prepare a polyether polycarboxylate water reducer.

[0043] (2) Add 11.0% polyether polycarboxylate superplasticizer, 1.0% sodium rosinate, 2.4% sodium fatty alcohol polyoxyethylene ether sulfonate, 1.8% sodium gluconate, 2.5% lignin sulfonate Sodium phosphate, 0.5% polyvinylpyrrolidone, 0.8% hydroxypropyl starch and 80% water a...

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Abstract

The invention discloses a water-based mortar modifier, its preparation method and application. The modifier comprises the following preparation raw materials by mass: 10-20% of polyether polycarboxylic acid water reducing agent, 0.1-10% of air entraining components, 1-20% of coagulation retarding components, 0.1-2% of water retention components and 60-85% of water. The polyether polycarboxylic acid water reducing agent is prepared by the method of: dissolving an enol polyether macromonomer, acrylic acid, and maleic anhydride in water, conducting heating to raise the temperature to 60-70DEG C, then adding a persulfate water solution dropwisely, carrying out heat preservation under 60-65DEG C for 2-4h, then performing cooling to a temperature of 45DEG C, and adjusting the pH value of the system to 7-8, thus obtaining the polyether polycarboxylic acid water reducing agent. The modifier provided in the invention can form a protective film on a cement particle surface, and at the same time can produce uniform and tiny bubbles, as well as reduce the friction between the particles in the system, thus effectively improving the workability and plasticity of the mortar system. Furthermore, the mortar modifier provided in the invention is a water-based multifunctional building mortar modifier, and is convenient to use. Doping of the modifier can significantly improve the workability and vicidity of mortar, and can maintain the properties effectively for 8-16 hours.

Description

technical field [0001] The invention relates to a water-based mortar modifier and its preparation method and application. The water-based mortar modifier can be used to improve the construction performance of mortar (referring to workability and viscosity), especially to effectively maintain and prolong the mortar. A water-based modifier for construction properties. Background technique [0002] The mixture of cement, sand and water is called cement mortar. In construction projects, mortar is often used for wall masonry and for interior and exterior plastering. Therefore, mortar needs to have better construction performance (referring to workability and viscosity), and people often add rubber powder, modified cellulose, etc. to improve its performance. The workability and viscosity of traditional mortar lose quickly, and generally need to be stirred on site and used up within 3-4 hours. [0003] For a long time, an additive called "mortar king" has been commonly used on c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/38C04B24/34C04B24/32
Inventor 吴昆胡文光吕满庚练锦添
Owner GUANGZHOU CHEM CO LTD CHINESE ACADEMY OF SCI
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