94 results about "Interfacial polycondensation" patented technology

The present invention provides a method and compound fabric for latent heat effect which means a compound fabric capable of undergoing heat storage (release) material for microcapsules with waterborne polyurethane shell which use interfacial condensation polymerization by waterborne polyurethane thereof, such as alkyl alkyrate (alkyric acid alkyl ester) for temperature in the range of 0° C. to 80° C. The fabric is selected from the group of consisting of woven, non-woven and structure of woven, and the present invention provides method to coat waterborne polyurethane shell microcapsules of heat storage (release) material for compound fabric

The invention discloses a polyamide nano filter membrane containing zwitterions and a preparation method thereof. The polyamide nano filter membrane containing the zwitterions comprises a porous polysulfone supporting player and a polyamide functional layer containing the zwitterions, and is prepared by carrying out interfacial polycondensation to the mixed water solution of polyamine and a zwitterionic monomer and the organic solution of multielement acyl chloride. Under the operation pressure of 0.6MPa, the nano filter membrane prepared by the method has high water flux (35-50L.m<-2>.h<-1>), and simultaneously, has very high trapping rate of 90-98% to divalent salt ions, and has lower trapping rate of less than 40% to univalent salt ions, in addition, the nano filter membrane has good stain resistance under the long-term operation. Thus, the prepared polyamide nano filter membrane containing the zwitterions has high permeability and stain resistance, the preparation method is simpleand easy to implement, the cost is low, and the industrial application prospect is good.

The invention relates to a polymeric composite membrane structure, in particular to a polymeric composite reverse osmosis membrane with an antibacterial function. The antibacterial composite reverse osmosis membrane is characterized in that: a polyamide polymeric desalination layer is compounded on a porous supporting membrane through interfacial polycondensation of polyamine and polyacyl chloride; and a polymeric material with the antibacterial function is compounded on the polymeric desalination layer by a surface coating technology. Sericin with the antibacterial function is coated on the surface of the conventional composite reverse osmosis membrane, so that hydrophilcity and antibacterial activity of the composite reverse osmosis membrane can be greatly improved and high biological pollution resistance is achieved. The antibacterial composite reverse osmosis membrane has the characteristics of simplicity in preparation, high desalination rate and high water flux. The reverse osmosis membrane has wide application.

The invention discloses a polymeric membrane and a preparation method thereof, in particular to a polyamide nanofiltration membrane and a preparation method thereof. The membrane comprises a porous support layer membrane and a polyamide ultrathin functional layer, wherein the polyamide ultrathin functional layer simultaneously contains sulfonyl amino, amide, carboxylic and sulfonic functional groups. The preparation method comprises the following step of compounding an aromatic polyamide ultrathin functional layer on a polysulfone support membrane through the interfacial polycondensation between aromatic polyhydric acyl chloride or other aromatic polyhydric acyl chloride mixture with modified acyl chloride groups on aromatic rings and a 4-amino piperidine water solution. The invention has the advantages that: the preparation method is novel and simple; and the nanofiltration membrane has better hydrophilcity and chlorine resistance and keeps higher removal ratio to bivalent ions while maintaining higher reflux. The invention has wide application in liquid separation industry.

The invention relates to a polymer separation membrane, in particular to a polyamide composite nanofiltration membrane and a preparation method thereof. A polyamide ultra-thin functional layer is compounded on a porous support membrane through interfacial polycondensation between aliphatic macromolecular polyamine and poly(acyl chloride). The preparation method comprises the following steps: directly immersing the porous support membrane into aliphatic macromolecular polyamine water solution, using a rubber roller to roll the surface of the support membrane, taking out, draining the water solution, blow-drying with nitrogen, performing single-side interfacial polymerization reaction with poly(acyl chloride) solution only on the surface of the porous support membrane, shade-drying the composite membrane in the air, and further performing heat treatment and rinsing for getting the composite nanofiltration membrane. The invention provides the novel polyamide composite nanofiltration membrane which is easy to get raw materials, low in price and excellent in selective separation performance and the preparation method thereof. The novel polyamide composite nanofiltration membrane has a wide range of applications, and the manufacturing method is simple.

The invention discloses a method for preparing a pollution-resistant low-pressure reverse osmosis membrane and belongs to the technical field of the separation of reverse osmosis membranes for water treatment. The method comprises the following steps of: preparing a polyamide membrane on a polysulfone porous membrane by using an aqueous solution of polyamine and an organic solution of polyacyl chloride through interfacial polycondensation, and coating and cross-linking a layer of polyvinyl alcohol-grafted zwitterionic copolymer membrane on the surface of the polyamide membrane. The method for preparing the pollution-resistant low-pressure reverse osmosis membrane is reasonably designed; a polyvinyl alcohol-grafted zwitterionic copolymer is coated and cross-linked on the polyamide membrane which is prepared on the polysulfone porous membrane by using the aqueous solution of polyamine and the organic solution of polyacyl chloride through interfacial polycondensation, so that the hydrophilcity of the surface of the membrane is improved, and the adhesiveness of organic matter is reduced; and the reverse osmosis membrane has good pollution resistance during long-time running. The membrane has high backwashing resistance and stability; and the salt rejection rate of the membrane on a NaCl aqueous solution at the concentration of 3.5g.L<-1> can reach over 97.0 percent at the temperature of 25 DEG C and under the pressure of 1.5MPa.

The present invention relates to a new-type aromatic polyamide reverse osmosis composite membrane containing diphenyl structure. It is prepared by utilizing aromatic polybasic acyl chloride containing diphenyl structure and aromatic polyamide to make them implement interfacial polycondencation reaction on the polysulfone supporting layer. It can be extensively used in the fields of sea-water desalination and preparation of ultrapure water.

The present invention provides a composite reverse osmosis membrane as a polyamide membrane including a side chain amino group such as a residue of a polyvinyl alcohol-based amine compound represented by Formula 1. Such a membrane can remove organic impurities under a low pressure, providing an economical method for removal of impurities. An aqueous solution including a polyvinyl alcohol-based amine compound having a side chain amino group represented by Formula 1 is applied on a polysulfone-based ultrafiltration membrane as a microporous support. Next, trimesic acid chloride solution is applied causing interfacial polycondensation, which generates a reverse osmosis membrane. When this composite reverse osmosis membrane is evaluated by using a pH 6.5 aqueous solution including 500 mg / l of sodium chloride at an operation pressure of 5 kg / cm2 and at a temperature of 25° C., the permeable flux is at least 1.5 m3 / m2·d, and the salt rejection is 80% or less. wherein 0<a, 0≦b, 2<c, 1≦x≦5, 0≦y≦4; R1 is at least one group selected from the group consisting of an ether group, an alkylene group and an ester group; and R2 is at least one group selected from the group consisting of an alkyl group and a halogen group.

The invention relates to a structure of a high molecular composite membrane, in particular to a self-cleaning high molecular reverse osmosis membrane. The self-cleaning reverse osmosis membrane is characterized in that a porous support membrane is compounded with a polyamide ultrathin desalting layer through interfacial polycondensation of aromatic polyamine and polyatomic acyl chloride, and the compounded desalting layer is compounded with a temperature-sensitive functional high molecular material with low critical transition temperature through solution coating technology. The self-cleaning reverse osmosis membrane has the advantage that the desalting rate and water flux of the reverse osmosis membrane are not lower than those of the prior anti-pollution reverse osmosis membrane technology, and also has the advantages of universality, simplicity, high efficiency and the like; and a preparation method thereof is comparatively simple. The reverse osmosis membrane of the invention has wide application.

The invention relates to a macromolecular composite membrane for water treatment and in particular relates to a composite reverse osmosis membrane with an antibacterial function. The composite reverse osmosis membrane is characterized by compositing a polyamide macromolecular desalination layer on a porous support membrane through interfacial polycondensation between polyamine and poly-acyl chloride and coating an inorganic material layer with an antibacterial function on the macromolecular desalination layer through the technology of compositing by alternate impregnation in solutions. The composite reverse osmosis membrane has the advantages that the hydrophilicity and antibacterial property of the composite reverse osmosis membrane are greatly improved and the composite reverse osmosis membrane has good biological pollution resistance by depositing the inorganic material with the antibacterial function on the surface of the existing polyamide composite reverse osmosis membrane; and the composite reverse osmosis membrane with the antibacterial function also has the characteristics that the composite reverse osmosis membrane is easy to prepare, and the desalination rate and the water flux are not lower than the desalination rates and the water fluxes of the existing composite reverse osmosis membranes. The composite reverse osmosis membrane has a wide range of application.

Materials and methods for the formation of microcapsules that include a high concentration of agriculturally active ingredients (AIs) and a lipophilic polymer encapsulated within a polymeric shell formed via an interfacial polycondensation reaction. Under some conditions, these microcapsules may be formed using less lipophilic solvent than is required using convention microencapsulation techniques. These inventive methods include forming an oil-in-water emulsion in some cases using a first polymer as a lipophilic solvent for the AI and forming a microcapsule that includes the AI and polymer. Other methods include forming a microcapsule that includes a lipophilic monomer, agriculturally active ingredient and initiator having a polymeric shell then elevating the temperature to initiate polymerization of the monomer with the microcapsule.

The invention relates to a polymer separation membrane, in particular to a high-performance polyamide composite membrane. In the invention, an ultra-thin active separating layer is compounded on a porous supporting membrane through interfacial polycondensation between an aqueous solution containing aliphatic macromolecular polyamine and an organic solution containing a dyadic aromatic reaction monomer; the aliphatic macromolecular polyamine is polyvinylamine; the dyadic aromatic reaction monomer is phthaloyl chloride or paraphthaloyl chloride or 2,4-toluene diisocyanate; and the thickness of the active separating layer is 0.02-0.5 mum. The invention has the advantage that a novel high-performance composite nanofiltration membrane which is made of raw materials easy to obtain and has low cost and excellent preferential segregation performance is provided. The high-performance composite nanofiltration membrane provided by the invention has multiple purposes and a simple manufacturing method.

The invention relates to a macromolecular separation membrane, and in particular relates to a high-flux composite nanofiltration membrane. An ultrathin active separation layer is compounded on a porous support membrane through interfacial polycondensation between the aqueous solution containing aliphatic macromolecular polyamine and an organic solution containing aromatic polyacyl chloride; the aliphatic macromolecular polyamine is sericin with concentration of 0.2-6.0wt%; and the aromatic polyacyl chloride is trimesoyl chloride or 5-isocyanate-isophthalyl chloride or 5-oxyformyl chloride-isophthalyl chloride or phthaloyl chloride or paraphthaloyl chloride or 2,4-toluene diisocyanate, with concentration of 0.5-4.0wt%. The invention provides a novel high-flux composite nanofiltration membrane which has the advantages that: the raw materials are easily available, the cost is low, the selective separation performance is good, and the penetration flux is high. The high-flux composite nanofiltration membrane provided by the invention is widely applicable, and the manufacturing method is simple.

The invention discloses a method for modifying the surface of high molecular weight polyethylene powder through interfacial polycondensation. The method comprises the following steps of: soaking ultra-high molecular weight polyethylene (UHMWPE) powder in a reaction monomer solution containing two or more than two acyl chloride groups or isocyanate groups; and adding into a reaction monomer solution containing two or more than two amino groups and hydroxyl groups, stirring and dispersing, and obtaining a layer of polyurea and / or polyurethane and / or polyamide film on the surface of the ultra-high molecular weight polyethylene powder through the interfacial polycondensation, so that the compatibility and adhesion of the surface of the UHMWPE powder are effectively improved and the performance of the UHMWPE powder is not changed. In addition, the method for modifying the surface of the UHMWPE powder is easy to implement, high in treatment speed and good in treatment effect, has low requirement on equipment, and is suitable for industrial production.

The invention relates to a novel poly piperazine amide nanofiltration membrane and a preparation method thereof. The poly piperazine amide nanofiltration membrane provided by the invention consists of a polysulfone supporting layer and a poly piperazine amide functional layer which is prepared by interfacial polycondensation of the aromatic multi acyl chloride with biphenyl structure or compounds thereof and piperazine. The novel poly piperazine amide nanofiltration membrane is prepared by utilizing the interfacial polycondensation of the organic solution of the novel butyryl chloride with biphenyl structure or compounds thereof and the aqueous solution of piperazine on the polysulfone porous supporting layer. The nanofiltration membrane prepared by the method has high water flux (more than 60l / m<2>.h) and high desalinization ratio (above 98%) of dianion and comparatively high desalinization ratio of single valence anion (60%-70%) under the operation pressure of 0.5Mpa.

The invention is to provide a process for manufacturing a high-purity polycarbonate, comprising: mixing a crude polycarbonate organic solution after completion of the polycondensation reaction by an interfacial polycondensation method which contains water-soluble impurities, with an aqueous washing liquid to form an emulsion; and performing purification using a coalescer. The manufacturing process performs the operation while controlling a draw-out amount of the polycarbonate organic solution whose moisture has been removed and which is drawn out from the coalescer and a discharge amount of the aqueous solution from the coalescer top which contains the impurities along with part of the polycarbonate organic solution, so that the polycarbonate organic solution and the aqueous washing liquid may not form a substantial interface by separating into two phases of the organic phase and the aqueous phase at least in the element section inside the coalescer. By operating as in the above, the manufacturing process produces the purified polycarbonate organic solution stably and produces the high-purity polycarbonate using the purified organic solution.

The invention relates to a polyamide antiosmosis composite film which contains a biphenyl structure and a preparation method thereof. The polyamide antiosmosis composite film is prepared by utilizing the novel aromatic polybasic acyl chloride which contains the biphenyl structure and a mixture thereof, and aromatic polybasic amine and a mixture thereof on a porous polysulfone support layer by interfacial polymerization. By selecting appropriate preparation condition, the antiosmosis composite film has excellent performance. The flux of the polyamide antiosmosis composite film can reach 63.81 / m<2>.h and the desulfurization ratio can reach 99.1 percent. The polyamide antiosmosis composite film prepared by utilizing the invention has simple preparation technology, better control condition, low cost and wide practicability. The polyamide antiosmosis composite film can be applied to the fields of seawater desalination, brackish water desalination ultrapure water preparation and so on.

The invention discloses a nanofiltration membrane, a preparation method and application thereof. The nanofiltration membrane comprises a support bottom membrane and an active separation layer arrangedon the support bottom membrane, wherein the active separation layer has an interpenetrating network structure, and the interpenetrating network structure is mainly formed by interpenetrating polyamide formed by an interfacial polycondensation reaction of a polyethyleneimine monomer and an acyl chloride monomer with ultrafine nanofibers. The preparation method comprises the following steps: arranging an ultrafine nano-fiber layer on a micro-filtration membrane to prepare an ultrafine nano-fiber / micro-filtration membrane composite substrate; and carrying out an interfacial polycondensation reaction on a polyethyleneimine monomer and an acyl chloride monomer on the surface of the superfine nanofiber / micro-filtration membrane composite substrate, and carrying out heat treatment to obtain thenano-filtration membrane. The preparation method of the nanofiltration membrane is simple, and the obtained nanofiltration membrane has high flux and high salt rejection performance, so that the desalination energy consumption cost is reduced, and the nanofiltration membrane has a wide application prospect in the aspects of seawater desalination pretreatment, water softening and the like.

The invention relates to a polymeric membrane for water treatment, in particular to a high-flux composite reverse osmosis membrane. An ultrathin desalination separation layer is compounded on a porous supporting membrane through interfacial polycondensation between a polyamine-containing aqueous solution and an organic solution containing aromatic polyacyl chloride; the polyamine is a mixture of metaphenylene diamine and sericin; and the aromatic polyacyl chloride is benzenetricarbonyl trichloride, 5-isocyanate- isophthaloyl chloride, 5-oxoformyl chloride-isophthaloyl chloride, isophthaloyl dichloride, paraphthaloyl chloride or 2,4-toluene diisocyanate. The high-flux composite reverse osmosis membrane has the advantages of readily available raw materials, low price and excellent selective separation property. The water flux of the high-flux composite reverse osmosis membrane is higher than that of the conventional polyamide composite reverse osmosis membrane. The high-flux composite reverse osmosis membrane has high membrane surface hydrophilicity and high pollution resistance. The high-flux composite reverse osmosis membrane has wide application.

The invention provides a polyamide nanofiltration membrane with a pattern surface. The polyamide nanofiltration membrane is formed by compounding a supporting base membrane and a polyamide separationlayer with a pattern surface; wherein the polyamide separation layer is subjected to interfacial polycondensation on the surface of the supporting base membrane, and the surface of the polyamide separation layer has patterns; through fine regulation and control of an interfacial polymerization reaction system and process parameters, the microstructure of a primary polymer film and the growth process of a separation layer are regulated to induce a polyamide surface with pattern morphology on the surface of a porous base film, and the nanofiltration membrane is endowed with good separation performance by the patterned surface; the membrane preparation method is simple, is convenient to realize in continuous industrial production, and is expected to have a wide application prospect in the aspects of wastewater salt separation recycling, seawater desalination and drinking water purification.

In manufacturing a composite semipermeable membrane useful for separating a liquid mixture selectively, it is rendered possible to provide a composite semipermeable membrane that exhibits reduced deterioration of water permeability and solute removing property as a result of drying and that demonstrates reduced economic burden and load for waste liquid treatment without impairing the water permeability or solute removal ratio of the composite semipermeable membrane through change of the membrane manufacturing method, by making a saccharide exist in an aqueous polyfunctional amine solution in performing interfacial polycondensation by bringing the aqueous solution of the polyfunctional amine into contact with an organic solvent solution containing a polyfunctional acid halide on a microporous support membrane.

The invention relates to the field of an organic optical functional material and in particular relates to a second-order nonlinear optical polyarylester material, and a synthetic method and application thereof. According to the invention, a bisacyl chloride compound and a bisphenol compound with a carboxyl functional group are taken as monomers for interfacial polycondensation, so that polyarylester with carboxyl on the side chain thereof can be obtained; furthermore, a chromophore molecule with electro-optical activity is introduced to the side chain of the polymer so that a side-chain type second-order nonlinear optical polyarylester material can be obtained; or, a bisphenol compound, a bishydroxyl chromophore and a bisacyl chloride compound are utilized as monomers for copolymerization, so that a main-chain type second-order nonlinear optical polyarylester material containing a chromophore module on the main chain can be obtained. The two methods both successfully solves the problem that polyarylester is difficult to dissolve and not easy to fabricate into a thin-film device. The two polyarylester materials are prepared into thin films and then polarized by heating in an electric field so that polyarylester thin films with high electro-optical activity can be obtained; and the polyarylester thin films can be used as materials for preparing an electro-optical device.

Amino acid-based poly(ester urea)s (PEU) are emerging as a class of polymers that have shown promise in regenerative medicine applications. Embodiments of the invention relate to the synthesis of PEUs carrying pendent “clickable” groups on modified tyrosine amino acids. The pendent species include alkyne, azide, alkene, tyrosine-phenol, and ketone groups. PEUs with Mw exceeding 100k Da were obtained via interfacial polycondensation methods and the concentration of pendent groups was varied by copolymerization. The incorporation of derivatizable functionalities is demonstrated using 1H NMR and UV-Vis spectroscopy methods. Electrospinning was used to fabricate PEU nanofibers with a diameters ranging from 350 nm to 500 nm. The nanofiber matricies possess mechanical strengths suitable for tissue engineering (Young's modulus: 300±45 MPa; tensile stress: 8.5±1.2 MPa). A series of bioactive peptides and fluorescent molecules were conjugated to the surface of the nanofibers following electrospinning using bio-orthogonal reactions in aqueous media.

The invention discloses a preparation method of an asymmetric antioxidant polyamide permeable membrane. The method comprises the steps of: adopting p-phenylenediamine (MPD) and trimesoyl chloride (TMC) monomers, combining a polyamide surface layer on the surface of a polysulfone (PES) support membrane through an interfacial polycondensation way, and implementing posttreatment on the surface layer through oxalic acid cooperating with a dehydrating agent, thus preparing an antioxidant polyamide composite permeable membrane. The treatment method, which adopts the oxalic acid cooperating with the dehydrating agent, can effectively improve the oxidative resistance and the hydrophilicity of the polyamide surface layer, and the method, cooperating with an asymmetric membrane structure, can greatly reduce the influence of concentration polarization on membrane separating property, so as to further enhance the water flux of the membrane as well as the reject rate to salt ions. The initiative preparation method, which operates at normal temperature and under normal pressure, is simple in experimental condition and short in preparation cycle, and the method is specifically applicable to mass preparation of high-performance permeable separating membranes.

The invention relates to a macromolecular composite membrane and in particular relates to a surface mineralized composite reverse osmosis membrane with high hydrophilicity. The composite reverse osmosis membrane is used for performing water treatment and is characterized by compositing a polyamide macromolecular desalination layer on a porous support membrane through interfacial polycondensation between polyamine and poly-acyl chloride and compositing a barium sulfate coating on the macromolecular desalination layer through the technology of mineralization by alternate impregnation in solutions. The hydrophilicity of the composite reverse osmosis membrane is greatly improved by depositing high-hydrophilicity inorganic materials on the surface of the existing polyamide composite reverse osmosis membrane. The composite reverse osmosis membrane has the advantages that on the premise that the desalination rate is unchanged or is slightly increased, the water flux of the composite reverse osmosis membrane is higher than that of the traditional composite reverse osmosis membrane formed by a porous support layer and a macromolecular desalination layer; and a preparation method is simpler. The composite reverse osmosis membrane has a wide range of application.

One or more embodiments of the present invention provide a hyperbranched amino-acid-based PEU polymer for use in regenerative medicine and / or drug delivery applications has tunable mechanical and thermal properties, but is sufficiently stable to permit such things as ethyloxide sterilization without degradation and / or significant loss of function. These hyperbranched amino acid-based poly(ester urea) (PEU) by interfacial polycondensation between linear and branched amino acid-based polyester monomers and a urea forming material such as trisphosgene or phosgene. By controlling the amount of branched monomer incorporated into the copolymer, the mechanical properties and water uptake abilities of the resulting hyperbranched amino acid-based PEUs may be tuned. The hyperbranched PEUs nanofibers are sterilizable with ETO and are stable for long periods of ETO sterilization, elevated temperature and exposure to aqueous environments. In various embodiments, these hyperbranched amino acid-based PEUs are also biodegradable and can be formed into fibers.

The invention discloses an organic composite membrane, in particular to a pollution-resistant composite membrane and a preparation method thereof. The invention compounds an aromatic polyamide lamina on a porous supporting membrane by polyamine and aromatic acyl chloride or isocyanate or oxygen formyl chloride interfacial polycondensation, the surface of the aromatic polyamide lamina has chloroformic acid pentachlorobenzene groups; polysulfone supporting membrane is directly soaked into polyamide solution, single interfacial polymerization reaction is carried out on the supporting membrane and aromatic acyl chloride solution after a rubber roll is used for rolling the surface of the supporting membrane, the supporting membrane is dried in the shade for 1-3 minutes in air, heat treatment is carried out for 3-10 minutes at 40-70 DEG C, the ultra-thin composite membrane is prepared by washing. The invention is characterized in that the prepared membrane has good bacteriostatic effect, efficient desalting property and simple preparation. The products and the method of the invention can be widely applied in the processing procedure of organic liquids.

The invention provides aromatic polycarbonate. The main chain of the aromatic polycarbonate comprises non-aromatic structure micromolecule coupling group -O-[R1-O]k- or -N-[R1-N]k-, wherein R1 is ethylidene, propylidene or butylidene, k is 1-8, preferably 2-6. The aromatic polycarbonate can be prepared from bisphenol, coupling agent, end-capping reagent and phosgene through traditional interfacial polycondensation reaction.