The invention discloses a non-migration and non-transferable high-temperature smooth master batch and a preparation process thereof, and provides a smooth master batch with a stable friction coefficient, the smooth master batch comprises co-polypropylene, modified polysiloxane, silicon dioxide and a composite antioxidant, after the smooth master batch is added to a film, stable smooth performance can be obtained, no influence is caused by migration or high temperature, the product quality is stable, and the production efficiency is improved; the special structure has good compatibility with resin, can be anchored in the resin and does not transfer, for example, the special structure is added to a film heat sealing surface and does not migrate or transfer to a corona surface, so that the corona effect is not influenced, and no negative effect is generated on later aluminum plating and compounding effects; the molecular weight is higher, the heat resistance is good, yellowing is avoided, and the appearance quality of the film is not influenced; VOCs are low, odor is low, and environment friendliness and safety are achieved; the use amount is small, but the smooth performance is stable, the problem that a conventional migration smooth master batch affects film corona is avoided, and meanwhile the problem that a conventional silicone master batch is large in addition amount and affects film haze is solved; silicon dioxide can be used as an anti-blocking agent, so that the opening smoothness of the film is improved.