Explosive modification composition, and preparation method and application thereof

A technology of composition and explosives, which is applied in the direction of explosives, non-explosive stabilizers, non-explosive/non-thermal agent components, etc. It can solve the problems of water resistance and poor fluidity, achieve stable surface properties, improve fluidity, and improve safety performance and storage performance effects

Active Publication Date: 2017-07-21
HENAN JIULIAN IND AUDIO SUPPLIES CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Wang Wanyong (Wang Wanyong. Experimental Research on Improving the Water Resistance and Fluidity of Rock Expanded Ammonium Nitrate Explosives[J]. Coal Mine Blasting, 2015(3):13-15) Aiming at the poor water resistance and fluidity of rock expanded ammonium nitrate explosives in the existing continuous production line In order to improve the water resistance and fluidity of rock puffed ammonium nitrate explosives, it is proposed to improve the water resistance and fluidity of rock expanded ammonium nitrate explosives through double modification technology, that is, to improve the composite oil phase and wood powder, while ensuring that the performance of the explosives is not affected

Method used

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  • Explosive modification composition, and preparation method and application thereof

Examples

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Comparison scheme
Effect test

Embodiment 1

[0026] Example 1: An explosive modification composition prepared from the following raw materials in parts by weight: 20 parts of octadecyl primary amine, 70 parts of phosphoric acid, and 10 parts of stearate.

[0027] Octadecyl primary amine, molecular formula C 18 h 39 N, has a weak irritating ammonia smell, is not easily soluble in water, is easily soluble in chloroform, ethanol, ethanol and benzene, is alkaline, and can react with acid to produce the corresponding amine salt; the appearance is white solid and flaky. commercially available.

[0028] This embodiment stearate is zinc stearate, molecular formula is C 36 h 70 o 4 Zn, the appearance is white light fine powder, the specification is 200 mesh, 325 mesh.

[0029] The preparation method of a kind of explosive modified composition of the present embodiment comprises the following steps:

[0030] Step S1: Weigh the above weight parts of octadecyl primary amine and phosphoric acid, add the phosphoric acid into oc...

Embodiment 2

[0041] Example 2: An explosive modification composition prepared from the following raw materials in parts by weight: 23 parts of primary octadecylamine, 70 parts of phosphoric acid, 6 parts of stearate, and 1 part of coloring agent.

[0042] In this embodiment, the stearate is zinc stearate; the coloring agent is carbon black; the auxiliary material is sepiolite, and the particle size is 300 mesh.

[0043] The preparation method of a kind of explosive modified composition of the present embodiment comprises the following steps:

[0044] Step S1: Weigh the above weight parts of octadecyl primary amine and phosphoric acid, add the phosphoric acid into octadecyl primary amine, stir at 70°C for 20 minutes, discharge, dehydrate and dry, grind to obtain powder;

[0045] Step S2: Add the above-mentioned stearate and colorant in sequence to the powder, mix thoroughly, and grind to obtain a product.

[0046] The obtained product is the finished explosive modified composition, and its...

Embodiment 3

[0048] Embodiment 3: A kind of explosive modification composition, is prepared by the raw material of following parts by weight: 20 parts of octadecyl primary amines, 70 parts of phosphoric acid, 8 parts of stearate, 1 part of coloring agent, 1 part of auxiliary materials share.

[0049] In this embodiment, the stearate is zinc stearate; the coloring agent is carbon black; the auxiliary material is sepiolite, and the particle size is 200 mesh.

[0050] The preparation method of a kind of explosive modified composition of the present embodiment comprises the following steps:

[0051] Step S1: Weigh the above weight parts of octadecyl primary amine and phosphoric acid, add the phosphoric acid into octadecyl primary amine, stir at 75°C for 12 minutes, discharge, dehydrate and dry, grind to obtain powder;

[0052] Step S2: Add the above-mentioned stearate, colorant and auxiliary materials in sequence to the powder, mix thoroughly, and grind to obtain a product.

[0053] The obta...

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Abstract

The invention provides an explosive modification composition, and a preparation method and application thereof, belonging to the technical field of explosives. The explosive modification composition is prepared from the following raw materials by weight: 15 to 25 parts of octadecyl primary amine, 60 to 80 parts of phosphoric acid, 5 to 15 parts of stearate, 0 to 3 parts of a coloring agent and 0 to 3 parts of an accessory material. The explosive modification composition is applicable to rock expanded ammonium nitrate explosives and can improve the free-running property of the rock expanded ammonium nitrate explosives, adjust charging density and enhance the explosive strength, safety performance and storage performance of explosives.

Description

technical field [0001] The invention belongs to the technical field of explosives, and in particular relates to a modified explosive composition, a preparation method and application thereof. Background technique [0002] Expanded explosive is a new type of ammonium nitrate explosive developed in the 1990s. Its biggest feature is that it does not contain TNT, but its power is equivalent to that of ammonium nitrate explosives containing TNT, while reducing environmental pollution. The preparation of puffed explosives is to first make a puffing agent from a surfactant, a foaming agent, a water enhancer and an ammonium nitrate crystal phase stabilizer; into microporous ammonium nitrate; finally, expanded ammonium nitrate, fuel oil, wood powder (expanded explosives used in coal mines also need to be added with salt) are mixed to make expanded explosives. [0003] Ammonium nitrate itself is a strong polar inorganic salt that is easily soluble in water. It can strongly absorb wa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C06B23/00C06B31/28
CPCC06B23/00C06B23/006C06B31/28
Inventor 龙明喜段智慧郭哓飒朱海燕徐芳芳江长青徐国喜
Owner HENAN JIULIAN IND AUDIO SUPPLIES CO LTD
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