The invention discloses a blue superindividual corundum and a preparation method thereof. The preparation method comprises the following steps of: carrying out mixing, smelting, temperature reduction solidification, blowing-in grinding, magnetic separation impurity removal, screening and secondary magnetic separation impurity removal on one ton of alumina powder, anatase titanium dioxide, titanium stone powder, aluminium fluoride and zirconium dioxide powder; and then carrying out magnetic separation by using a magnetic separator so as to obtain the blue superindividual corundum. Because iron ores are not used, the smelting process causes no smoke and odour, and the processing process of a product causes no hydrogen sulfide gas, therefore the whole production process causes no pollution to the environment; in addition, because a right amount of the zirconium dioxide is added, the zirconium dioxide and the alumina appear in a crystal combining way, therefore true specific weight and granularity are obviously increased, chemical property is more stable, strength achieves 33 N, density achieves 4.02 g/cm<3>, the content of Al2O3 contained in the blue superindividual corundum achieves more than 99.55 percent, and the content of various impurities is lower.