50results about How to "Polymerization reaction temperature is low" patented technology

A carrying process for the carried non-metallocene catalyst includes activating the porous carrier, washing, filtering, drying and directly carrying the nno-metallocene catalyst used for olefine polymerization. Said catalyst can be used for the slurry-type or gas-phase homopolymerization or copolymerization of C2-C10 olefin, styrene, or ethylene.

The invention relates to a chemical grouting material for reinforcing loose and broken bedrock. The invention provides a chemical grouting material for reinforcing the loose and broken bedrock, in order to improve the flash point, the burning point and the antistatic performance of the grouting material, reducing the temperature in polymerization reaction and lowering the cost. According to the technical scheme provided by the invention, the chemical grouting material for reinforcing the loose and broken bedrock comprises two components, including a component A and a component B; according to the formulas of the raw materials, the component A comprises 90 to 100 parts by weight of sodium silicate or potassium metasilicate solution, 0 to 5 parts by weight of surface active agent, and 0 to 5 parts by weight of accelerator; the component B comprises 70 to 90 parts by weight of isocyanate, 5 to 20 parts by weight of plasticizer, 0.5 to 3 parts by weight of polyalkane silicone, and 0 to 5 parts by weight of catalyst; the components A and B are uniformly mixed respectively; and in use, the components A and B are mixed according to the volume ratio of 1: 1. The chemical grouting material can be applied to quickly reinforcing the broken coal bed and rock bed and blocking water leakage.

Provided is a preparation method for a polycarboxylate high-performance water reducer. The water reducer is prepared by copolymerization reaction of macromolecule monomer methoxy polyethylene glycol mono(meth) acrylate ester, small molecule monomer (meth)acrylic acid and sodium styrene sulfonate in an aqueous solution under the protection of inert gas and the action of a redox initiation system and a chain transferring agent. According to the invention, a high-activity redox initiation system is employed, which enhances the polymerization rate, reduces polymerization temperature, shortens reaction time, ensures non-hydrolysis of macro-molecular polyester monomers in the process of polymerization and a high conversion rate of raw materials, and guarantees that polymers have long side chains arraying at uniform intervals and an ideal comb shaped molecular structure. The water reducer prepared in the invention has the characteristics of a high water-reducing rate, a small slump loss and the like, and enables concrete with the water reducer to have high strength; simultaneously, the copolymerization reaction is carried out in water in the method, and therefore the method has the characteristics of simple preparation technology, environmental protection, low cost, etc.

The invention discloses a low-temperature synthesis polycarboxylate superplasticizer and a preparation method thereof. The low-temperature synthesis polycarboxylate superplasticizer comprises 150-250 parts by weight of unsaturated polyether, 2-30 parts by weight of unsaturated hydroxyl ester, 1-2 parts by weight of vinyl ether, 10-30 parts by weight of acyclic acid, 2-10 parts by weight of potassium hydroxide solution with the mass concentration of 30-35%, 0.5-2 parts by weight of chain transfer agent, 0.2-0.8 part by weight of low-temperature reducing agent, 0.1-0.5 part by weight of sodium sulfoxylate formaldehyde, 0.1-0.5 part by weight of ascorbic acid, 1-5 parts by weight of hydrogen dioxide solution with the mass concentration of 30-35%, 0.01-0.1 part by weight of ferrous sulfate, 12-20 parts by weight of sodium hydroxide solution with the mass concentration of 30-35% and 240-340 parts by weight of deionized water. The polycarboxylate superplasticizer can well adapt to a novel polyether raw material and is good in dispersibility and dispersibility keeping capability.

The invention relates to a preparation method of heat curing fluorosilicone raw rubber. The preparation method comprises the following steps: adding D3F and D4Vi into a reactor and then dehydrating D3F and D4Vi, adding prepared potassium silanolate catalyst pre-polymer, heating, introducing nitrogen and stirring to carry out polymerization, wherein the temperature is 60-115 DEG C and the reaction time is 20-100min, neutralizing with a neutralizer until the reactant is neutral, and finally, removing small molecular substances from the material, reducing temperature and discharging. Due to the adoption of the potassium silanol catalyst pre-polymer with high activity, the reaction temperature is low, the accelerant is not required, an end-capping reagent is not required in the polymerization process, and the nitrogen purging manner is adopted in the stage of removing the small molecular substances from the material, the volatile matter of the heat curing fluorosilicone raw rubber is reduced; the prepared heat curing fluorosilicone raw rubber can be widely used in the fields of aerospace, petrochemical industry, automobiles, artificial organ, and the like, and has a good promotional value.

The invention relates to a norbornene, acrylonitrile and perfluoromethyl vinyl ether ternary polymerization catalyst and a ternary polymerization method. The invention is characterized in that the preparation method of the catalyst includes: in a glove box of nitrogen atmosphere, dissolving vanadium trichloride and a ligand in a first solvent in a conical flask to obtain a mixed solution; then under magnetic stirring, dripping alkyl aluminum into the mixed solution, then further performing stirring for 30-60min at 30-60DEG C, steaming off part of the first solvent, conducting standing and filtering to obtain solid crystals, i.e. a vanadium-aluminum complex catalyst; adding a norbornene monomer, acrylonitrile and a perfluoromethyl vinyl ether monomer into a repeatedly vacuumized and nitrogen charged high pressure kettle, and adding a second solvent for dissolution; then adding the vanadium-aluminum complex catalyst for reaction; washing and filtering the reaction product, and conducting drying, thus obtaining a norbornene, acrylonitrile and perfluoromethyl vinyl ether terpolymer.

The invention relates to a norbornene-perfluoromethyl vinyl ether binary copolymer catalyst and a binary copolymerization method. The preparation method of the catalyst is characterized by comprising the following steps: in a container of dry inert gas atmosphere, dissolving antimony pentachloride and ligand in a first solvent; dropwise adding tetra-isopropoxy titanium at 200-300rpm, and then continuously stirring for 30-50 minutes at 30-50 DEG C to obtain an antimony-titanium complex catalyst; adding a norbornene monomer and a perfluoromethyl vinyl ether monomer in a molar ratio of 1:1 into an autoclave after repeated vacuumizing and nitrogen charge; adding a second solvent and dissolving; adding the antimony-titanium complex catalyst, and reacting for 1-6 hours at 30-120 DEG C and under the pressure of 0.1-8MPa; pouring the reaction product into an ethanol solution containing 4-5wt% of hydrochloric acid; washing the obtained precipitate with ethanol to neutrality; and performing vacuum drying to obtain a norbornene-perfluoromethyl vinyl ether binary copolymer.

The invention relates to a norbornene, tetrafluoroethylene and perfluoromethyl vinyl ether ternary copolymerized catalyst and a ternary copolymerization method, and is characterized in that the preparation method of the catalyst comprises the following steps: in a dry container with an inert gas atmosphere, dissolving di(t-butylcyclopentadienyl)titanium (IV) dichloride and a ligand in a first solvent, to obtain a mixed solution; then dropping alkyl aluminum into the mixed solution, and stirring for 30-60 minutes at the temperature of 30-60 DEG C, to obtain a titanium-aluminum complex catalyst; taking a norbornene monoer, tetrafluoroethylene and a perfluoromethyl vinyl ether monomer according to the molar ratio of 1:1:1, adding the components into a high pressure kettle vacuumized for multiple times and filled with nitrogen, adding a second solvent, and dissolving; then adding the titanium-aluminum complex catalyst, and completing a reaction under certain conditions; and washing and drying the reaction product to obtain the norbornene, tetrafluoroethylene and perfluoromethyl vinyl ether ternary copolymerized catalyst.

Provided is a technological method for synthesizing biologically degradable poly(succinic acid-co-polybutylene terephthalate) (PBST50-50) through organic guanidine catalysis. According to the technological method, a non-poisonous organic biomass compound is used as a main catalyst and non-poisonous zincate is used as a promoter to form a two-component high-activity catalysis system, succinic acid(SA), terephthalic acid (TA) and 1,4-diethylene glycol (BDO) are used as monomers, and the biodegradable PBST50-50 is synthesized through direct melting and condensation and then solid-phase polycondensation. The weight average molecular weight Mw of the PBST50-50 synthesized by adopting the method can be 1.0 * 105-1.2 * 105, Tm is 170 DEG C or above, and the product has a white color.

The invention relates to a norbornene, vinylcyclohexane and perfluoromethyl vinyl ether ternary copolymerization catalyst and a ternary copolymerization method. In a three-neck flask with dry inert gas atmosphere, bis-(1,5-cyclooctadiene) nickel and ligand are dissolved into a first solvent, so that a mixed solution is obtained; then, under stirring, titanium tetraisopropanolate is dripped into the mixed solution, the mixed solution continues to be stirred under 30 DEG C to 70 DEG C for 30 to 70 minutes, and thereby a nickel-titanium complex catalyst is obtained; a norbornene monomer, vinylcyclohexane and a perfluoromethyl vinyl ether monomer are added into a high-pressure kettle which is vacuumized multiple times and filled with nitrogen, and a second solvent is added for dissolution; the nickel-titanium complex catalyst is then added, and reaction takes place under certain temperature and pressure for 1 to 8 hours; the product obtained by the reaction is poured into ethanol solution containing 4 to 5wt percent of hydrochloric acid, the obtained precipitate is washed with ethanol to become neutral, and after vacuum drying, a norbornene, vinylcyclohexane and perfluoromethyl vinyl ether ternary copolymer is obtained.

The invention provides a method for preparing PMMA (polymethyl methacrylate) / CNTs (carbon nanotubes) composite materials. The method includes: preparing surface-modified carbon nanotubes from carbon nanotubes and auxiliaries such as organosilicon compounds, polycarboxylate, polyoxyethylene ether and acrylic resin under certain conditions by a physical blending process; adding the surface-modified carbon nanotubes and initiators into methyl methacrylate matrixes; uniformly dispersing the carbon nanotubes, the initiators and the methyl methacrylate matrixes to obtain mixtures and polymerizing the mixtures by means of standing under low-temperature conditions to obtain the PMMA / CNTs composite materials. The method has the advantages that monomer MMA (methyl methacrylate) is polymerized in a standing state under the effect of ultrasonic waves and the joint effects of the carbon nanotubes (CNTs) and the initiators at the low polymerization temperatures of 15-80 DEG C; reaction conditions are mild, surface chemical modification by the aid of strong oxidizing agents such as strong acid can be omitted, polymerization reaction can be carried out at the low temperatures, the method is low in energy consumption, technological conditions are simple, and operation is easy to implement; self-acceleration and implosion phenomena can be prevented in reaction procedures, the reaction procedures are stable and mild, the surfaces of products obtained by the aid of the method are smooth and flat, the carbon nanotubes are excellently dispersed, and the glass-transition temperatures of the obtained PMMA is increased.

The invention relates to a cross-linking polymerization acidic ionic liquid alkylating catalyst. The catalyst is obtained through the steps that a 4-halogenated-1-vinyl pyrazole monomer, 1-vinyl-3-alkyl imidazole bromide and crosslinkers crosslinkers are subjected to copolymerization to obtain cross-linking polymer ionic liquid, the cross-linking polymer ionic liquid reacts with halohydrocarbon toobtain substituted cross-linking polymer ionic liquid, and finally the substituted cross-linking polymer ionic liquid and organic acid are subjected to ion exchange to obtain the catalyst, wherein the general molecular formula is defined in the description, R1 is -CH2(CH2)2CH3 or -CH2(CH2)4CH3, R2 is -CH2(CH2)mCH3, m is 0, 2, 4 and 6, X is one of Cl, Br and I, Y<-> is SO3CF3<-> or CF3COO<->, thepolymerization degree is 2-50, a polymer b is 2-50, a polymer c is 2-50, and a polymer d is 2-50. Serving as a novel environmentally-friendly solid acid heterogenous catalyst for an alkylation reaction, the catalyst has the excellent catalytic performance, the catalytic efficiency can be effectively improved, and when styrene and o-xylene are catalyzed to generate the alkylation reaction, the yield of a diphenylethane product is larger than 90%.

The invention discloses a method for synthesizing nitrogen-containing, potassium-containing and high-water-absorption resin by using carboxymethyl potato starch and acrylamide. The method is mainly characterized by comprising the following steps: firstly, hydrolyzing the acrylamide by using potassium hydroxide; then heating in water bath under the protection effect of nitrogen; and carrying out graft polymerization on the carboxymethyl potato starch and the partially hydrolyzed acrylamide at the temperature of 30-60 DEG C and preparing the high-water-absorption resin. The maximum water absorption of the optimal product in 5,000 times of deionized water can reach 3,500 g / g. Moreover, through a result of an orthogonal experiment, the product of which the water absorption reaches 3,575 g / g is obtained, and the potassium content of the product is 15.59%. The result and the condition of the orthogonal experiment are analyzed to obtain the sequence of factors which affect the water absorption of the nitrogen-containing, potassium-containing and high-water-absorption resin and are arrayed from large to small. The high-water-absorption resin has the advantages that the carboxymethyl potato starch as a matrix can be dissolved in water so that gelatinization is not required, and graft polymerization reaction temperature is low. Therefore, the high-water-absorption resin is simple in synthesize technology, easy to operate, low in performance and suitable for being produced in a large scale and popularized.

The invention belongs to the technical field of graphene materials, and discloses a graphene-oxide-based redox system initiator and a preparation and use method thereof. The initiator is composed of the following components by mass: 50-60 parts of oxidant, 40-50 parts of main reducing agent, 0-10 parts of assistant reducing agent and 50-100 parts of water. The oxidant is mainly one or more of an organic peroxy oxidant, an inorganic peroxy oxidant and a tetravalent cerium salt. The initiator greatly reduces the polymerization temperature, and the polymerization temperature can be in the range of 0-60 DEG C. The introduction of the graphene oxide can utilize the reducibility of a large number of organic functional groups on the surface of the graphene oxide and fully utilize structural characteristics of the graphene oxide to introduce high strength, high elasticity modulus, high toughness and other characteristics into a product.

The invention belongs to the technical field of concrete admixtures and discloses a novel polycarboxylate based superplasticizer and a preparation method thereof. The polycarboxylate based superplasticizer comprises the following components: vinyl polyethylene glycol ether (ester), (meth) acrylic acid (acrylate) or other vinyl monomers and derivatives, an oxidizing agent, a reducing agent and water. The preparation method comprises the following steps: adding the vinyl polyethylene glycol ether (ester), the reducing agent and the water into a reactor, and heating; respectively dropping one ormore monomer solutions in the (meth) acrylic acid (acrylate) or other vinyl monomers and derivatives and an oxidizing agent solution, and reacting; maintaining the temperature and reacting after dropping completion; regulating the pH value of the solution with a sodium hydroxide solution, thereby obtaining the novel polycarboxylate based superplasticizer. According to the method disclosed by the invention, graphene oxide is introduced into the molecular structure of the polycarboxylate based superplasticizer, so that the dispersion problem of the graphene oxide in the admixture and cement-based materials can be fundamentally solved, and the mechanical property and durability of the cement-based materials are improved.

The invention discloses a method for producing trifluoro-propyl silicone oil by the aid of ion exchange resin. The method includes pretreating cyclo-rectification byproducts and water to obtain supernatant oil layers, then feeding the supernatant oil layers into a container, feeding 1, 3, 5 (3, 3, 3-trifluoro-propyl) trimethyl cyclo-trisiloxane into the container, uniformly stirring and mixing the supernatant oil layers and the 1, 3, 5 (3, 3, 3-trifluoro-propyl) trimethyl cyclo-trisiloxane with one another to obtain first mixtures, heating the first mixtures, dehydrating the first mixtures under vacuum conditions, adding end-capping agents into the first mixtures after the vacuum is eliminated, adding catalysts into the container to obtain second mixtures, continuing to heat the second mixtures, carrying out reaction under the conditions of the normal pressure and the stirring speed of 200-230 r / min for 1-3 h, then carrying out suction filtration by the aid of filter bags and measuring the conversion rate of filter liquor; pouring filtered liquid materials in three-mouth flasks, then heating the filtered liquid, removing low-boiling-point substances for 1-5 h, placing filtered resin in containers and hermetically storing the filtered resin in the containers. Products are sampled, and indexes of the appearance, the viscosity, the density, volatile matters, the flashing points and the like of the products are detected. The method has the advantages that processes for producing the trifluoro-propyl silicone oil are simple, the trifluoro-propyl silicone oil can be continuously industrially produced by the aid of the method, the products are stable in quality, and index requirements on the indexes of the conversion rate, the viscosity, the density, the volatile matters, the flashing points and the like of the products can be met.

The invention discloses a method for synthesizing a high water absorbent polymer by using potato starch xanthate and acrylamide. The method is mainly characterized by comprising the following steps of: firstly hydrolyzing the acrylamide by using alkaline, and subsequently heating in water bath under the protection of nitrogen, so the starch xanthate and a part of the hydrolyzed acrylamide are subjected to graft polymerization at 35 to 45 DEG C so as to prepare the high water absorbent polymer. The maximum water absorbing capacity of an optimal product in deionized water of 2500 times can be 2160g / g, and the water absorbing capacity in deionized water of 10000 times can be 5000g / g; and meanwhile the high water absorbent polymer prepared by the method is high in nitrogen content. The methodfor preparing the high water absorbent polymer has the following advantages that the parent potato starch xanthate does not need to be gelatinized, the graft polymerization reaction is low in temperature, and high temperature reaction is not needed, so that the method for synthesizing the high water absorbent polymer provided by the invention is simple in process, easy to operate, low in cost andexcellent in product performance, so that the method is more applicable for scale production and popularization of products.

The invention discloses the preparation of adsorbed Cu by using carboxymethyl potato starch and acrylamide as raw materials 2+ The method of ionic resin, the main feature is firstly hydrolyzing acrylamide with sodium hydroxide solution, and then heating in a water bath under the protection of nitrogen, so that carboxymethyl potato starch and partially hydrolyzed acrylamide are grafted and polymerized at 30-60°C to prepare adsorption Cu 2+ resin. Best product in 1000mlCu 2+ Cu in a solution with a concentration of 10ppm 2+ The adsorption capacity is 33.13mg / g, the removal rate is 98.78%, in 1000mlCu 2+ Cu in a solution with a concentration of 400ppm 2+ The adsorption capacity is 918.79mg / g, and the removal rate is 94.42%. The present invention adsorbs Cu 2+ The preparation of ion resin has the following advantages: the parent carboxymethyl potato starch is soluble in water, thus no gelatinization is required, the process is simple and easy, the graft polymerization reaction temperature is low, and the practicability is strong, and the obtained adsorbed Cu 2+ Resin to Cu 2+ High ion adsorption capacity.

The invention relates to a polyamide resin as well as a preparation method and application thereof. The polyamide resin comprises an aliphatic polyamide molecular chain segment, wherein an aromatic imide unit and an aromatic amide unit are embedded into the aliphatic polyamide molecular chain segment. The polyamide resin is prepared by controlling polymerization reaction conditions together with precipitation, cleaning and drying treatment. The polyamide resin provided by the invention is low in polymerization reaction temperature, easy in reaction process control and applicable to large-scaleproduction and application. The product has very good thermal resistance, and is capable of meeting requirements of electronic and electrical reflow soldering (SMT) processes and automobile engine accessories on thermal resistance of plastic products.