Blue ssuperindividual corundum and preparation method thereof

A single crystal corundum and blue technology, applied in the direction of single crystal growth, single crystal growth, chemical instruments and methods, etc., can solve the problems of grinding wheel deformation, affecting the working ability and effect of grinding wheel, air pollution, etc., and achieve a clear image of single crystal , Conducive to mechanical crushing, improve the effect of strength and hardness

Active Publication Date: 2010-12-08
XIXIA ZHENGHONG MONOCRYSTALLINE CORUNDUM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But there are big problems in the original production method, the one, can decompose in the refining process in the air, discharge a large amount of sulfur dioxide gas, produce a large amount of hydrogen sulfide gas in the process of hydrolysis, hydrogen sulfide gas is to all kinds of metals ( Copper, zinc) wires, and various types of electrical appliances have an astonishing degree of corrosion. All types of wires will become rust powder and break off within three months, which is harmful to human health, pollutes the atmosphere, and discharges a large amount of deep sediment into the water, polluting downstream water sources
2. After the single crystal corundum produced by the original production method is made into a grinding wheel, there are iron spots and shrinkage phenomena. The result of the shrinkage is that abnormal cracks and deformation appear on the grinding wheel, which seriously affects the working ability and effect of the grinding wheel. Before leaving the factory A large number of grinding wheels are required for cutting and shaping, which greatly increases its production cost; in addition, the original production method consumes a lot of energy, and the production of single crystal corundum requires 6000 degrees of electricity per ton

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0024] A production method of blue single crystal corundum includes the following steps:

[0025] a. Mixing: Mix 1 ton of alumina, 2kg of anatase titanium dioxide, 6kg of titanium powder, 8kg of aluminum fluoride, and 6kg of zirconium dioxide powder;

[0026] b. Melting: Put the mixed raw materials into the electric arc furnace, heat to 2100°C, and continue heating for 26 hours;

[0027] c. Cooling and solidification: After smelting, let it stand at room temperature for 4 days to fully solidify;

[0028] d. Opening the furnace and breaking: Open the furnace, first use a hammer to break the corundum into small pieces, and then use a counterattack to break it;

[0029] e. Magnetic separation and impurity removal: Use a magnetic separator to select the magnetic impurities in the corundum sand;

[0030] f. Screening: Use a sieve of appropriate mesh to classify the magnetically separated particles;

[0031] g. Removal of impurity by secondary magnetic separation: Use a magnetic separator to ob...

Embodiment 2

[0033] A production method of blue single crystal corundum includes the following steps:

[0034] a. Mixing: Mix 1 ton of alumina powder, 4kg of anatase titanium dioxide, 10kg of titanium powder, 12kg of aluminum fluoride powder, and 4kg of zirconium dioxide powder;

[0035] b. Melting: Put the mixed raw materials into the electric arc furnace, heat to 2400℃, and continue heating for 30 hours;

[0036] c. Cooling and solidification: After smelting, let it stand at room temperature for 6 days to fully solidify;

[0037] d. Opening the furnace and breaking: Open the furnace, first use a hammer to break the corundum into small pieces, and then use a counterattack to break it;

[0038] e. Magnetic separation and impurity removal: Use a magnetic separator to select the magnetic impurities in the corundum sand;

[0039] f. Screening: Use a sieve of appropriate mesh to classify the magnetically separated particles;

[0040] g. Removal of impurity by secondary magnetic separation: Use a magnetic ...

Embodiment 3

[0042] A production method of blue single crystal corundum includes the following steps:

[0043] a. Mixing: Mix 1 ton of alumina, 3kg of anatase titanium dioxide, 8kg of titanium powder, 10kg of aluminum fluoride, and 5.2kg of zirconium dioxide powder;

[0044] b. Melting: Put the mixed raw materials into the electric arc furnace, heat it to 2350℃, and continue heating for 28 hours;

[0045] c. Cooling and solidification: After smelting, let it stand at room temperature for 5 days to fully solidify;

[0046] d. Opening the furnace and breaking: Open the furnace, first use a hammer to break the corundum into small pieces, and then use a counterattack to break it;

[0047] e. Magnetic separation and impurity removal: Use a magnetic separator to select the magnetic impurities in the corundum sand;

[0048] f. Screening: Use a sieve of appropriate mesh to classify the magnetically separated particles;

[0049] g. Removal of impurity by secondary magnetic separation: Use a magnetic separator ...

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Abstract

The invention discloses a blue superindividual corundum and a preparation method thereof. The preparation method comprises the following steps of: carrying out mixing, smelting, temperature reduction solidification, blowing-in grinding, magnetic separation impurity removal, screening and secondary magnetic separation impurity removal on one ton of alumina powder, anatase titanium dioxide, titanium stone powder, aluminium fluoride and zirconium dioxide powder; and then carrying out magnetic separation by using a magnetic separator so as to obtain the blue superindividual corundum. Because iron ores are not used, the smelting process causes no smoke and odour, and the processing process of a product causes no hydrogen sulfide gas, therefore the whole production process causes no pollution to the environment; in addition, because a right amount of the zirconium dioxide is added, the zirconium dioxide and the alumina appear in a crystal combining way, therefore true specific weight and granularity are obviously increased, chemical property is more stable, strength achieves 33 N, density achieves 4.02 g/cm<3>, the content of Al2O3 contained in the blue superindividual corundum achieves more than 99.55 percent, and the content of various impurities is lower.

Description

Technical field [0001] The invention belongs to the technical field of production methods of single crystal corundum, and particularly relates to a blue super single crystal corundum and a preparation method thereof. Background technique [0002] The traditional production method of single crystal corundum is to use bauxite, pyrite and carbonaceous materials as raw materials, and send them to the electric arc furnace for smelting after mixing, and produce Al at high temperature. 2 O 3 After cooling the electric furnace, the single crystal of corundum precipitated from the molten liquid. However, the original production method has big problems. One is that a large amount of sulfur dioxide gas is decomposed into the air during the refining process, and a large amount of hydrogen sulfide gas is generated during the hydrolysis process. The hydrogen sulfide gas affects various metals ( The corrosion of copper, zinc) wires and all kinds of electrical appliances is alarming. All kinds o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C30B29/20
Inventor 王虎山史萌明李保生王冬林王毅敏王毅青
Owner XIXIA ZHENGHONG MONOCRYSTALLINE CORUNDUM
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