256 results about "Zr element" patented technology

The invention discloses a cast magnesium alloy of low linear shrinkage, which belongs to the field of magnesium alloys. The magnesium alloy consists of Mg, Al, Zn, Mn, rare earth, Nb, Li and M element, wherein the materials have the following weight percentage composition: 1.5-25 percent of Al, 0.1-3.5 percent of Zn, 0.1-2.2 percent of Mn, 0.0002-16 percent of rare earth, 0.0002-4 percent of Nb, 0.0002-9 percent of Li, 0.0002-2 percent of M element and the balance Mg; and the M element is at least one of Zr, Ti, Sr, Ca, C and B. According to the heat-resistant magnesium alloy, the rare earth element and the Nb element are added into the magnesium alloy, so that the structure of beta phase is changed; the Zr element and the M element are added to refine crystal grains; due to combined action of the elements, latent heat of crystallization during alloy solidification is changed; and the magnesium alloy which has superior mold-filling capacity, low shrinkage, superior mechanical property and good machinability, fluidity and die-cast performance and is suitable for casting is obtained.

The invention discloses a magnesium alloy refiner and a preparation method thereof, and relates to a grain refiner and a preparation method thereof. The method solves the problems that an overheating treatment method of the existing magnesium alloy refining method has strict condition requirement, the oxidation burning loss of magnesium is serous, a carbon-containing material treatment method has high temperature and produces harmful gases such as Cl2, HCl and the like, a ferric chloride method reduces the corrosion resistance of the magnesium alloy, an alloying method has high cost, a granular graphite or aluminium carbide granule method is easy to produce segregation on the grain boundary and a Zr element method has narrow application range. The magnesium alloy refiner is prepared from a calcium metal and a primary magnesium ingot. The preparation method comprises the following steps: heating and melting the primary magnesium ingot under atmospheric protection, then adding the calcium metal into the melted primary magnesium ingot, dissolving the calcium metal and stirring the mixture uniformly, and casting the mixture to form the magnesium alloy refiner. The magnesium alloy refiner has no burning loss, does not produce the harmful gases, has no influence on the corrosion resistance of the magnesium alloy, has low cost, is uniformly distributed in the alloy, can improve the mechanical property of the alloy, and is used for refining the magnesium alloy.

The invention relates to a low-cost high-performance rare-earth-based AB5-type hydrogen storage alloy and a preparation method thereof. The alloy has a general formula: Ml(Ni(1-x-y-w)CoxMnyAlzMw)mMgn, wherein x, y, z, w, m and n present a mol ratio; x is larger than zero and smaller than or equal to 0.1; y is larger than zero and smaller than or equal to 0.2; z is larger than zero and smaller than or equal to 0.2; w is larger than or equal to zero and smaller than or equal to 0.06; m is larger than or equal to 4.8 and smaller than or equal to 5.5; n is larger than zero and smaller than or equal to 0.1; the Ml comprises La and at least one element selected from Ce, Pr, Nd, Sm, Gd, Dy, Y, Ca, Ti and Zr; the content of the La in the Ml is 40-80 percent by weight; accordingly, the content of the La in the alloy is 10-26 percent by weight; and the M comprises at least one element of Cu, Fe, Si, Ge, Sn, Cr, Zn, B, V, W, Mo Ta and Nb. The alloy has high content, long service life, low Co content, low cost and good recovery performance.

A mesoporous silica has uniform mesopores and a periodic structure, which contains a Zr element in the form of a Si-O-Zr bond and wherein the Zr content in the Si-O-Zr bond, represented by [Zr/(Si+Zr)] is 0.05 to 20 mole %. The mesoporous silica is superior in alkali resistance and is suitably used particularly as a separation membrane (e.g. a ceramic membrane) and a catalytic support for solid-liquid system, in which an alkaline liquid may be used.

The invention discloses a zirconium cladding surface resistant to high temperature and oxidation ZrCrFe/AlCrFeTiZr composite gradient coating preparing technology. Ultrahigh vacuum multitarget co-sputtering technique is adopted, a ZrCrFe/AlCrFeTiZr composite gradient alloy resistant to high temperature and oxidation protecting coating is prepared on the surface of a zirconium alloy base body, and the zirconium cladding surface resistant to high temperature and oxidation ZrCrFe/AlCrFeTiZr composite gradient coating preparing technology comprises the steps of predepositional treatment, bias voltage anti-splash washing and ZrCrFe/AlCrFeTiZr composite gradient alloy coating deposition. The preparing process of the composite coating is divided into two steps, the first step is to prepare ZrCrFe gradient transition layer coating, in a deposited ZrCrFe transition layer, the atomic percentage content of Zr element is changed from the gradient of 100 at%-35 at% in the thickness direction, the atomic percentage content of Cr element is changed from the gradient of 0 at%-33 at% in the thickness direction, and the atomic percentage content of Fe element is changed from the gradient of 0 at%-33 at% in the thickness direction; the second step is to prepare a AlCrFeTiZr high-entropy alloy coating, in a deposited AlCrFeTiZr high-entropy alloy coating, the atomic percentage content of Al element is controlled in 0.5 at%-1.0at %, and the atomic percentage of other elements is between 10 at%-35 at%. Bonding force of the coating prepared by the technology is excellent, the surface is dense and uniform, and the coating has excellent performance such as high strength, resistance to high temperature and oxidation and irradiation resistance.

The present invention belongs to the field of composite material preparation technology. The composite material has the chemical expression of: AlaMgbBcMd, Where a is 50-96, b 1-7, c3-30 and d 0-13; M is one or several of Si, Cu, Ni, Ti, Fe, Cr, La, Mn, Ce, Zn, V and Zr. The preparation process is one combined powder metallurgy and in-situ reaction process and includes mixing material powder, cold pressing the mixture for forming, heating the formed mixture and hot pressing for the material powder to produce chemical reaction at temperature over 950 deg.c. Inside the aluminum alloy base, A1MgB14 ceramic phase particle as reinforcing phase is formed to prepare the composite aluminum alloy material. The ceramic particle reinforced composite aluminum alloy material. The ceramic particle reinforced composite aluminum alloy material has light weight and high strength, integrated functions, and may be used widely in transport industry and national defence industry.

The invention discloses a high-strength and high-plasticity magnesium alloy. The high-strength and high-plasticity magnesium alloy comprises the following components in percentage by mass: 3.0-4.5% of Ni, 4.0-5.0% of Y, 0.01-0.1% of Zr, not more than 0.15% of inevitable impurities and the balance of magnesium. According to the high-strength and high-plasticity magnesium alloy disclosed by the invention, Y and Ni elements are simultaneously added into a magnesium matrix, and in the smelting and molding process of the alloy, Y and Ni form Mg2Ni and Mg12YNi phases with the magnesium matrix, wherein the Mg12YNi phase is a long-period stacking ordered structure (LPSO), so that the strength of the alloy can be improved, and the plasticity of the alloy can also be improved; and Mg2Ni can improve the strength of the alloy by a strengthening mechanism of the second phase. According to the high-strength and high-plasticity magnesium alloy disclosed by the invention, an appropriate amount of Zr element is further added into the alloy, and zirconium can be dispersed and distributed in the matrix in an elemental form by controlling the smelting and molding process to play a role in refining grains.

The invention discloses a low-cost magnesium alloy with the high room-temperature plastic deformation and a preparation process thereof, and belongs to the technical field of metal materials. The magnesium alloy comprises, by weight, 0.1%-0.9% of zinc, 0.1%-0.4% of calcium, 0-0.05% of manganese and the balance magnesium. The magnesium alloy does not contain rare earth elements or the Zr element and is low in alloy cost, an ingot of the magnesium alloy has good thermoplastic machining performance, large-rolling-reduction rolling with the rolling reduction being 80% at most in one pass can be achieved during hot rolling, and cracks in the surface are avoided. The ingot is subjected to thermoplastic machining and then annealing, the obtained magnesium alloy has a weak non-basal texture, the maximum density value of the magnesium alloy is not greater than 5, and the room-temperature elongation of the magnesium alloy is high and can reach 25%-40%.

The invention relates to a crystal grain refining agent for aluminum or aluminum alloy, and belongs to the technical field of the crystal grain refining agent. An aluminum alloy refining agent uses aluminum as a base body; the content of Er in the aluminum alloy refining agent is 0.5 to 10 weight percent; the Zr content is 0.1 to 10 weight percent; the content of other elements is 0 to 5 weight percent; other elements include but are not limited to one or several kinds of materials in Fe, Si, Cu, Mg, Mn, Zn, Ti, Cr, B and C; the balance of Al. The refining agent containing Er and Zr elements has the obvious crystal grain refining effects on the aluminum alloy; the adverse effects caused by infusible TiB2 particles in the Al-Ti-B refining agents cannot occur.

The invention discloses a wet-method zirconium-doped concentration-gradient nickel-cobalt-aluminum ternary precursor and a preparation method thereof. The nickel-cobalt-aluminum ternary precursor hasa chemical general formula of NixCoyAlz(OH)2, wherein x+y+z=1, 0.3<=x<=0.9, 0.01<=y<=0.4, and 0.01<=z<=0.4; the Zr element accounts for 0.001%-3% of the total mass of the nickel-cobalt hydroxide precursor, the ternary precursor consists of three layers, and the inner layer is a zirconium-doped nickel-cobalt binary precursor with a molecular formula of NixCoy(OH)2; and the outer layer is a zirconium-doped nickel-cobalt-aluminum ternary precursor with a molecular formula of NixCoyAlz(OH)2, and the intermediate layer is a concentration-gradient precursor between the zirconium-doped nickel-cobaltbinary precursor and the zirconium-doped nickel-cobalt-aluminum ternary precursor. The invention also includes the method for preparing the nickel-cobalt-aluminum ternary precursor. The zirconium-doped nickel-cobalt-aluminum ternary precursor has a narrow particle size distribution and good particle morphology, the doped element is distributed uniformly through complex controlled crystallizing co-precipitation, and a positive-electrode precursor prepared from the zirconium-doped nickel-cobalt-aluminum ternary precursor has high specific capacity, good cycling stability, good processability andstable performance.

The invention relates to a refractory high-entropy alloy material with high plasticity and low neutron absorption cross section and a preparation method thereof, and belongs to the technical field of high-entropy alloys. The high-entropy alloy material is AlVTiNbZr high-entropy alloy, wherein the atomic percent of an aluminum element is 5%-10%, the atomic percent of a V element is 3%-15%, the atomic percent of a Ti element is 20%-40%, the atomic percent of an Nb element is 25%-35%, and the atomic percent of a Zr element is 20%-35%. The AlVTiNbZr high-entropy alloy is of a single-phase BCC structure. The AlVTiNbZr high-entropy alloy is obtained in a vacuum arc melting mode, has a high theoretical melting point, low alloy density, high room-temperature yield strength and deformation plasticity, can resist deformation failure in the service process, and brings sufficient safety margin in the service process.

The invention discloses a layered positive electrode material for a lithium-ion battery. The layered positive electrode material comprises a body and a B2O3 coating layer, wherein a chemical formula of the body is Li<x>(NiCoMn<c>)<1-y>M<y>O<2>, wherein x is smaller than or equal to 1.04 and greater than or equal to 0.96, y is smaller than or equal to 0.06 and greater than or equal to 0.01, ais smaller than or equal to 0.9 and greater than or equal to 0.8, a+b+c is equal to 1, and M is selected from at least one of an Al element, a Mg element, a Ti element and a Zr element. The inventionfurther discloses a preparation method of the layered positive electrode material for the lithium-ion battery. The method comprises the following steps of mixing a nickel-cobalt manganese hydroxide,a lithium source and a nano oxide additive evenly and carrying out first sintering to obtain unmodified powder; stirring the unmodified powder and water, carrying out centrifugal separation to obtaina solid material, drying and crushing to obtain washing powder; adding LIBOB to an organic solvent for dissolving, adding the washing powder for mixing, stirring, evaporating and carrying out second sintering to obtain the layered positive electrode material for the lithium-ion battery.