Magnetoplumbate-type permanent magnetic ferrite and manufacturing method thereof
A permanent magnet ferrite and magnetoplumbite technology, applied in the field of permanent magnets, can solve the problems of complicated manufacturing process, high substitution amount of expensive element Co, and high production cost, and achieves good drainage effect, inhibited growth, and molding cycle. short effect
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Embodiment 1
[0044] Prepare Fe with a mass fraction of more than 99% 2 o 3 powder, its SiO 2 The mass fraction of ≤0.015%, its chloride (Cl - ) mass fraction ≤ 0.15%; its average particle size is 0.95 μm; prepare SrCO with mass fraction above 98% 3 Powder, the average particle size is 2 μm; the mass fraction is more than 98.5% CaCO 3 Powder, the average particle size of which is 4 μm; the mass fraction is more than 99% La 2 o 3 Powder with an average particle size of 4 μm; cobalt oxide powder containing more than 72% Co, with an average particle size of 2.7 μm; more than 99% ZrO 2 Powder with an average particle size of 1 μm. According to (1-x-y)CaO xSrO (y / 2)R 2 o 3 ·(n-z / 2-m / 2)Fe 2 o 3 ·zMO·mZrO 2 The addition amount of each main raw material was calculated, wherein x=0.1, y=0.6, z=0.25, m=0.04, n=4.9. Then the compounds containing each element are accurately weighed according to the calculated amount, and the main raw materials are wet mixed. Its mixing time was 4 hours. T...
Embodiment 2
[0046] Adopt the calcined powder in embodiment 1, add 0.6% calcium gluconate as dispersant when finely pulverizing, all the other are identical with embodiment 1. Its magnetic properties are shown in Table 1, and the microstructure of the obtained magnet is as follows figure 2 shown. The SEM analysis of the magnet section shows that the crystal structure is relatively loose, the grain size is not uniform, the porosity is 1.1%, and no abnormal growth grains are seen.
Embodiment 3
[0048] Adopt the calcined powder in embodiment 1, do not add dispersant when pulverizing finely, all the other are the same as embodiment 1. Its magnetic properties are listed in Table 1.
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