294 results about "Cr element" patented technology

The invention belongs to the technical field of alloy material, and discloses a high-strength high-toughness ultrafine-grained high-entropy alloy and a preparation method thereof. The high-strength high-toughness ultrafine-grained high-entropy alloy is composed of the following elements according to the atomic percentage: 20%-25% of Ni, 18%-20% of Fe, 18%-22% of Co, 18%-20% of Cr, and 20%-24% of Al; the microstructure takes a body-centered cubic disordered solid solution phase rich in Ni and Al elements as a matrix phase, and takes a face-centered cubic disordered solid solution phase rich in Fe and Cr elements as a reinforcing phase. The preparation method of the alloy comprises the steps: elemental powders with the atomic percentages are subjected to powder mixing and high-energy ball milling to prepare an amorphous composite powder, and the amorphous composite powder is sintered to obtain the high-strength high-toughness ultrafine-grained high-entropy alloy. The prepared high-entropy alloy has the advantages of large size and good comprehensive mechanical properties, and can be used in the fields of aeronautics and astronautics, military industry, electrons, instruments and apparatuses and the like.

The invention relates to a catalyst for dehydrogenating light alkane in order to mainly solve the problem of relatively-low activity of a dehydrogenating catalyst prepared in the prior art. The problem is better solved through the technical scheme that the catalyst for dehydrogenating light alkane comprises the following components in parts by weight: 1-30 parts of a Cr element or an oxide of the Cr element (a), 0.1-5 parts of alkali metal oxides or alkaline earth metal oxides (b), 0.001-1 part of the group VA elements selected from a periodic table of elements or oxides of the group VA elements (c), 0.001-1 part of the group IIIA elements selected from the periodic table of elements or oxides of the group IIIA elements (d), and 54-99 parts of Al2O3 or SiO2 (e). The catalyst can be used for industrial production of light olefin prepared by dehydrogenating light alkane.

The invention relates to a non-oriented high-silicon electrical steel ribbon and its making method, and belongs to the fields of the metallurgical technology and the material science. The chemical components of the ribbon comprise 4.5-7.0wt% of Si, 2.0-5.0wt% of Cr, 0.06-1.0wt% of Al, 0.3-0.8wt% of Mn, 0.005wt% or less of N, 0.004wt% or less of S, 0.02wt% or less of P, 0.003wt% or less of O, 0.005wt% or less of C, and the balance Fe, and the thickness of the ribbon is 0.35-0.5mm. The making method comprises the following steps: smelting non-oriented high-silicon steel in a vacuum smelting furnace; carrying out double-roller ribbon roll-casting at a casting temperature of 1420-1460DEG C to the ribbon thickness of 1.0-1.5mm; carrying out hot rolling of the ribbon at 800-1100DEG C to the hot rolled ribbon thickness of 0.8-1.0mm; pickling, and preheating the ribbon, and carrying out warm rolling at 400-700DEG C; and annealing. The addition of the Cr element in the high-silicon electrical steel ribbon obviously improves the processing performance of the high-silicon steel ribbon, the iron loss value is same to the iron losses of present high-silicon steel products, and the magnetic induction intensity is above 0.03T higher than that of the present products. The making method has the advantages of simple technology, low energy consumption, high yield, and excellent product magnetic property.

The invention discloses a hard alloy blade and a preparation method thereof. The hard alloy blade comprises a hard alloy blade basal body and a coating layer; the hard alloy blade basal body uses Co as a binding phase, and uses tungsten carbide and a titanium-contained cubic-phase compound as a hard phase; the solid solution is performed for a W element and a Cr element in the binding phase; the mass fraction of the W element in the binding phase is 2-10 wt.%; the mass fraction of the Cr element in the binding phase is 1-10 wt.%; the titanium-contained cubic-phase compound is a carbon-nitrogen compound containing one or two in a Ta element and a Nb element and a Ti element; and the grain distribution of tungsten carbide has a double-peak structure. The preparation method comprises batching, powder preparation by mixing, molding by pressing, sintering and preparation of a coating layer. The hard alloy blade has the advantages of high hardness, toughness and strength and excellent and stable cutting performance, and is high in generality, suitable for various processing fields, simple in preparation method and low in cost.

The invention discloses a metal support half-cell of a solid oxide fuel cell and a preparation method thereof. The half-cell comprises a porous metal supporting layer thick membrane, a porous cermet gradient transition layer film, a porous anode layer and a compact electrolyte layer film from down to up. The porous gradient transition layer composed of a mixed oxide and a oxide with a fluorite structuring can avoid the direct contact of the porous metal supporting layer and the porous anode layer, and the mutual diffusion of Fe/Cr elements in the metal supporting layer and Ni element in the porous anode layer can be reduced under high temperature sintering condition. The mixed oxide is reduced to an alloy under the work condition of the cell; a high anode active material is formed at a side interface of the anode, a high conductivity composite material which takes the alloy as a main phase is formed on the side interface of a metal support body, so that higher conductivity is presented, ohmic resistance is reduced, electrocatalytic activity is not reduced, long-term stability for operation of the cell can be ensured, and good combination of the porous metal supporting layer and the porous anode layer can be simultaneously realized.

The invention discloses a zirconium cladding surface resistant to high temperature and oxidation ZrCrFe/AlCrFeTiZr composite gradient coating preparing technology. Ultrahigh vacuum multitarget co-sputtering technique is adopted, a ZrCrFe/AlCrFeTiZr composite gradient alloy resistant to high temperature and oxidation protecting coating is prepared on the surface of a zirconium alloy base body, and the zirconium cladding surface resistant to high temperature and oxidation ZrCrFe/AlCrFeTiZr composite gradient coating preparing technology comprises the steps of predepositional treatment, bias voltage anti-splash washing and ZrCrFe/AlCrFeTiZr composite gradient alloy coating deposition. The preparing process of the composite coating is divided into two steps, the first step is to prepare ZrCrFe gradient transition layer coating, in a deposited ZrCrFe transition layer, the atomic percentage content of Zr element is changed from the gradient of 100 at%-35 at% in the thickness direction, the atomic percentage content of Cr element is changed from the gradient of 0 at%-33 at% in the thickness direction, and the atomic percentage content of Fe element is changed from the gradient of 0 at%-33 at% in the thickness direction; the second step is to prepare a AlCrFeTiZr high-entropy alloy coating, in a deposited AlCrFeTiZr high-entropy alloy coating, the atomic percentage content of Al element is controlled in 0.5 at%-1.0at %, and the atomic percentage of other elements is between 10 at%-35 at%. Bonding force of the coating prepared by the technology is excellent, the surface is dense and uniform, and the coating has excellent performance such as high strength, resistance to high temperature and oxidation and irradiation resistance.

The invention provides a manufacturing method of steel, comprising the following steps: smelting the molten steel to ensure that the content of P in the molten steel is less than or equal to 0.035%, the content of S is less than or equal to 0.015% and the content of V is less than or equal to 0.15%; then adding Cu element and Ni element to the molten steel to ensure that the content of Cu in the molten steel is 0.20-0.60% and the content of Ni is 0.15-0.55%; tapping to a steel ladle when the content of C in the molten steel is below 0.05%; adding physical mixture of lime and fluorite and predeoxidizing agent to the steel ladle in the tapping process to ensure that the content of S in the molten steel is less than or equal to 0.012%; adding Cr element, Si element and Mn element to the molten steel to ensure that the content of Si in the molten steel is 0.25-0.60%, the content of Mn is 0.80-1.60% and the content of Cr is 0.20-0.80%; feeding Al simple substance to the molten steel to carry out final deoxidation; heating the molten steel in the condition of argon blowing to lead the steel slag to melt; then adding Al simple substance to the steel ladle to ensure that the content of S in the molten steel is less than or equal to 0.010%; and then adding C element to the molten steel to ensure that the content of C in the molten steel is 0.08-0.16%; feeding Al simple substance and alloy containing Ti, V and N to the molten steel to control that the content of acid-soluble aluminium in the molten steel is 0.025-0.040%, the content of Ti is 0.005-0.015%, the content of V is 0.08-0.15% and the content of N is 0.010-0.020%.

In a method of producing large-grained nuclear fuel pellet, Cr-compound contained in an uranium oxide green pellet is reduced to Cr phase at 1,470° C. or below and maintained to the Cr phase, and the uranium oxide green pellet containing the Cr-compound is then sintered at 1,650° C.-1,800° C. in a gas atmosphere of oxygen potential at which Cr element in the uranium oxide green pellet becomes liquid phase.

The environment friendly no-chromium conversion treating solution consists of titanium salt in 1-25 g/l, complexing agent in 12-30 g/l, silicate in 5-15 g/l, redox agent in 10-25 g/l, additive in 3- 6.5 g/l and deionized water for the rest. The treating solution contains no Cr element, is suitable for chemical conversion treatment of galvanizing coating and zinc alloy product, and produces no environmental pollution. When the treating solution is used in chemical conversion treatment of galvanizing coating and zinc alloy product, white film, blue film or film in other color may be obtained.

The invention discloses low-alloy high-intensity high-toughness steel and a production method of low-alloy high-intensity high-toughness steel. The method comprises the following work procedures of: the casting work procedure: the casting is carried out according to the following ingredients and contents to obtain low-alloy steel cast ingots: 0.15 to 0.30 weight percent of C elements, 0.30 to 0.70 weight percent of Si elements, 0.60 to 1.00 weight percent of Mn elements, 0.60 to 1.10 weight percent of Cr elements, 0.50 to 1.00 weight percent of Ni elements, 0.20 to 0.60 weight percent of Mo elements and the balance Fe and unavoidable impurities; the forging work procedure: the low-alloy steel cast ingots are forged, in addition, the blank opening forging heating temperature is 1160 DEG C to 1200 DEG C, the final forging temperature is 650 DEG C to 900 DEG C, and the deformation in each firing time is not smaller than 30 percent; and the heat treatment work procedure: the temperature of the forged and formed forgings is raised to 900 to 940 DEG C to be subjected to normalizing, the temperature is raised to 880 to 920 DEG C for carrying out quenching after the normalizing treatment, the temperature is raised to 530 to 600 DEG C for carrying out high-temperature tempering after the quenching treatment, and the low-alloy high-intensity high-toughness steel is obtained. In the embodiment of the invention, the low-alloy high-intensity high-toughness steel has high intensity and high toughness.

The invention provides a nickel-based deformed superalloy with high aluminum content and a preparation method thereof. A traditional Ni-Co-Cr component serves as a matrix element, the content of the alloy element is increased, particularly, the content of a solid solution strengthening phase gamma'phase forming element Al is increased, the content of a strengthening phase gamma'phase is increasedto 55%-65%, and the temperature bearing capacity of the alloy is effectively improved. A proper amount of Nb element is added into the alloy, so that the stability of a gamma'phase can be improved, the casting-forging process performance is further improved, the long-time structure stability of the alloy at 850 DEG C can be improved by reducing the addition of Cr element, and the surface stabilityloss caused by the reduction of the Cr element can be compensated by the high-content Al element. Meanwhile, a duplex technology or a triple technology is adopted for preparing and machining an alloyraw material, the obtained nickel-based deformed superalloy solves the problem that no high-performance wheel disc forge piece material capable of being used at 850 DEG C for a long time exists at present, and the nickel-based deformed superalloy particularly has excellent tensile strength and yield strength and long service life at 850 DEG C.

The invention discloses a 6-series railway vehicle suspension arm aluminum profile which contains the following metal substances in percentage by mass: 0.6-0.7% of Si, less than 0.15% of Fe, 0.5-0.7% of Mg, 0.02-0.25% of Mn, less than 0.01% of Cu, 0.1-0.25% of Cr, less than 0.05% of Zn, 0.03-0.06% of Ti and the balance of Al. The invention also discloses a preparation method of the 6-series railway vehicle suspension arm aluminum profile. The 6-series railway vehicle suspension arm aluminum profile has optimized chemical components as compared with the aluminum profile in the prior art, the Mn element content is enhanced to 0.2%, and the Cr element content is enhanced to 0.12%; the Mn can be utilized to enhance the recrystallization temperature characteristic and inhibit the crystal grains from growing, thereby refining the crystal grains of the profile and enhancing the microstructure of the material (grain refinement); and the optimized aluminum profile has the advantages of high tensile strength, high yield strength and high elongation percentage.

The invention discloses a cast-rolling method for restraining a Cr element and a Mo element of super-austenitic stainless steel from center segregation and belongs to the technical field of manufacturing of the super-austenitic stainless steel. The method includes the steps that (1) raw materials are weighed according to the composition proportion of the super-austenitic stainless steel, and the raw materials are subjected to heat preservation at the temperature ranging from 150 DEG C to 250 DEG C for 100 minutes to 150 minutes; (2) the raw materials are sorted and placed into a vacuum induction melting furnace step by step to obtain molten steel by being smelted; and (3) the molten steel is poured into a dual-roll thin strip cast-rolling machine for cast rolling under shielding of high-purity nitrogen, and a thin super-austenitic stainless steel strip 2.0-3.0 mm thick is obtained, wherein the pouring temperature ranges from 1450 DEG C to 1550 DEG C, the cast-rolling speed ranges from 10 m/min to 40 m/min, and the cast-rolling force ranges from 30 kN to 70 kN. According to the manufactured thin super-austenitic stainless steel strip, center segregation of the Cr element and the Mo element is restrained, and on the premise of maintaining the plasticity, the yield strength is improved by 5%-10% compared with that of traditional strip steel of the same specification as the thin super-austenitic stainless steel strip. Meanwhile, the cast-rolling method reduces energy consumption and production cost, improves the utilization rate of materials and reduces environmental pollution.

The invention pertains to the field of heat treatment of nonferrous metal and relates to a heat treatment technique for improving the strength and conductivity of copper alloy of Cu-Cr series. The alloy is used as lead frame materials, electrified railway contact lines and the like in the electronic industry. The invention adopts a secondary ageing heat treatment technique with two stages, which comprises the following steps: copper alloy containing supersaturation precipitated phase element Cr after solution treatment is first aged at lower temperature for a long time for leading the precipitated phase to be in a fine and dispersed distribution and the precipitation to be relatively sufficient, and laying a foundation for obtaining high strength; then the ageing temperature is properly increased to improve the diffusion velocity of atoms, thus leading the Cr elements in the residual solution in the Cu matrix to be further precipitated; as the precipitated phase exists, part of the newly precipitated Cr is precipitated on the existing Cr particles; the existing dispersed distribution of Cr is retained at the lower temperature, and the other part of Cr is also precipitated, thereby forming more dispersion-distributed nanometer particles, greatly improving the strength of the alloy, and simultaneously purifying the copper matrix and improving the conductivity.

The invention discloses a high-strength and high-toughness metastable beta titanium alloy and a preparation method thereof. The Ti-Al-Mo-V-Cr-Zr metastable beta titanium alloy comprises the componentsof, in percentage by weight, 4.5%-5.5% of Al, 6.5%-9.0% of Mo, 1%-4% of V, 1.5%-4% of Cr, 1%-2.5% of Zr and the balance Ti and other inevitable impurities. According to the high-strength and high-toughness metastable beta titanium alloy and the preparation method thereof, after an alloy is subjected to smelting, hot rolling and heat treatment, good matching of strength and plasticity can be obtained; according to the high-strength and high-toughness metastable beta titanium alloy and the preparation method thereof, the content of the V element is further reduced to about 3.5%, and the cheap Cr element is added so that the cost can be reduced to a certain extent; meanwhile, a certain amount of the Cr and Mo elements are added to reinforce a beta matrix, so that the solid solution strengthening effect of the multi-component alloy is improved; and according to the high-strength and high-toughness metastable beta titanium alloy and the preparation method thereof, the yield strength of thealloy is improved to 1518 MPa, meanwhile, and the alloy also has the total elongation at break of 5.3%, so that the requirements of a new generation of high-strength and high-toughness titanium alloyare met.

Each of an antiferromagnetic layer and a pinned magnetic layer has a region containing a Cr element, thereby increasing an exchange coupling magnetic field (Hex) produced between the antiferromagnetic layer and the pinned magnetic layer. Therefore, the exchange coupling magnetic field produced between the antiferromagnetic layer and the pinned magnetic layer can be increased, and a coupling magnetic field due to RKKY interaction can also be increased, thereby increasing a one-directional exchange bias magnetic field (Hex*) in the pinned magnetic layer as compared with a conventional exchange coupling film.

The catalyst for preparing 1, 1-difluoroethane includes Cr element and one or two other metal elements of Co, Mn, Zn, Fe, Mg, Al and Ni in the molar ratio of 1 to 0.001-0.6, as well as F element and O element. The Cr base catalyst has less environmental pollution, high activity, high stability, long service life, no tendency of polymerizing 1, 1-difluoroethane, great contact area, fast reaction, high space time yield and easy regeneration. When the reaction is controlled in 150-200 deg.c, the reaction pressure has no influence on the variety of the reaction products, and the reaction products have less side products. The catalyst is prepared through a simple co-precipitation process.

The invention relates to a catalyst for dehydrogenating light alkane and application of the catalyst in order to mainly solve the problem of relatively-low activity of a dehydrogenating catalyst prepared in the prior art. The problem is better solved through the technical scheme that the catalyst for dehydrogenating light alkane comprises the following components in parts by weight: 1-30 parts of a Cr element or an oxide of the Cr element (a), 0.1-5 parts of Li, Na, K and Rb elements or oxides of the Li, Na, K and Rb elements (b), 0.1-10 parts of Cu, Co, Ni and Fe elements or oxides of the Cu, Co, Ni and Fe elements (c), 0.001-1 part of a Ga element or an oxide of the Ga element (d), and 54-99 parts of Al2O3 (e). The catalyst can be used for industrial production of light olefin prepared by dehydrogenating light alkane.

The invention provides a Cr-doped Ge2Sb2Te5 phase change material, a phase change memory unit and a preparation method. The ingredient general formula of the Cr-doped Ge2Sb2Te5 phase change material is CrxGe2Sb2Te5, wherein x is an atomic ratio of the Cr element, and x is more than 0.5 and less than 1.5. Cr doping in Ge2Sb2Te5 is carried out, Cr is a kind of metal with an extremely high melting point, heat stability of a phase change material can be raised, Cr can form bonds with Ge, Sb and Te, so segregation is avoided effectively. Under action of external energy, the Cr-doped Ge2Sb2Te5 phase change material can achieve reversible conversion between high resistance state and low resistance state, and the resistance value ratio of the high resistance state to the low resistance state can reach about two orders of magnitudes. When the phase change material is employed as a memory media of a phase change memory, the phase change memory unit has advantages of fast phase change speed, low write operation current and the like, and high temperature data retentivity and reliability of the device are raised greatly. The phase change memory employing the phase change memory unit structure has advantages of high speed, low power consumption, good data retentivity and the like.

The invention relates to a farmland chromium pollution remediation method under a planting production condition. The farmland chromium pollution remediation method comprises the following steps: performing crop rotation of wheat and corn on soil to be treated according to growth seasons, and applying an organic fertilizer at least before seeding of wheat and corn, wherein a heavy metal passivator consists of the following components in percentage by weight: 64-75% of ferrous sulfate, 0.2-1% of compound bacteria and 0-35% of aluminum oxide; the organic fertilizer is one or a combination of two of wormcast, commercial organic fertilizers and cow dung. The passivation remediation technique provided by the invention is relatively low in remediation cost, normal planting and production of cereal crops are not affected, moreover, a bio-availability passivation effect on the Cr element can be achieved, and the condition requirements on heavy metal polluted soil remediation can be relatively well met. As ferrous sulfate and the active compound bacteria are induced to have oxidation reduction with Cr in the soil, Cr can be transformed to be trivalent from hexavalent, and CrO2- and Cr3+ compound precipitate can be formed.

The invention provides a Cr2O3 doped silicon dioxide aerogel material and a preparation method thereof. The preparation method of the Cr2O3 doped silicon dioxide aerogel material comprises the following steps: taking a silicon source as a precursor, adopting an inorganic compound containing the Cr element and an organic compound as doping ions, mixing the compounds with a solvent, a complexing agent and a catalyst to form a composite sol, conducting impregnation technology to be compounded with reinforced fibers, carrying out gelatinizing, ageing, solvent replacement, supercritical carbon dioxide drying, high-temperature pretreatment and other technologies to obtain the product. The preparation method disclosed by the invention is to conduct metal Cr doping and modification on the aerogel through a complexing-gelatinizing method, skillfully combine the complexing reaction with the gelatinizing reaction to increase the complexing force of the metal Cr doping ions in the gel system, effectively restrain the phenomenon that the Cr is not uniform in distribution as the Cr ions are migrated during the follow-up treatment process of the gel, so that the diffusion effect of the complexing-gelatinizing method is uniform and stable, and the complexing-gelatinizing method is better than the in-situ doping method. The aerogel obtained by the complexing-gelatinizing method is treated in advance at high temperature, so as to enable the internal reaction to be conducted thoroughly under high-temperature action, then transform the aerogel to be the Cr2O3 doped stable aerogel structure, and facilitate the pore structure and the heat-insulating property to be stable.

The invention discloses a two-dimensional titanate nanometer material and a preparation method thereof. The two-dimensional titanate nanometer material comprises a modified protonated titanate film which comprises organic groups and a doped Cr element. Through the doped Cr element which facilitates to broadening absorption bandwidth of the two-dimensional titanate nanometer material, the two-dimensional titanate nanometer material can absorb ultraviolet light and visible light, and greatly improves efficiencies of light absorption and photoelectric conversion, thereby improving photocatalytic efficiency. Meanwhile, through doping of the organic groups which are relatively large molecules and are used as a balance medium of nanometer sheets, the prepared two-dimensional titanate nanometer material is not easy to curl and has relatively-stable two-dimensional structure and relatively-large surface area, thereby further improving photocatalytic efficiency.

The invention discloses a device for detecting the content of heavy metal Cr element in soil by laser-induced breakdown spectroscopy, which comprises an electromagnetic valve A, an air inlet tube, a temperature and air pressure sensor, a soil sample carrier, a feed inlet, an air outlet tube, an electromagnetic valve B, a fused quartz lens A, an optical fiber probe, an optical fiber, an optical fiber connector, a closed laser induction chamber, a spectrometer, a fused quartz lens B, a laser head, an ICCD (Intensified Charge Coupled Device) detector, an external connection cable, a femtosecond laser, a bottom shell, a cover plate and a miniature air conditioner. The laser head, the fused quartz lens B and the soil carrier on the femtosecond laser are located on the shame horizontal straight line, the centers of the soil carrier, the fused quartz lens A and the optical fiber probe are located on the same longitudinal straight line, both ends of the optical fibers are connected with the optical fiber probe and the optical fiber connector, and the ICCD detector, the left side of which is connected with the external connection cable, is mounted on the left side of the spectrometer.