The invention belongs to the technical field of
nuclear fuel element surface protection, and particularly relates to a multi-layer composite (Cr, Al) Nx / Cr protective
coating for a
nuclear reactor zirconium alloy cladding and a preparation method of the multi-layer composite (Cr, Al) Nx / Cr protective
coating. The
coating adopts a multi-layer structure design consisting of a buffer layer, a middle layer and an outermost layer in sequence from inside to outside, wherein the buffer layer is a Cr coating; the middle layer is a
nitrogen-saturated (Cr, Al) Nx coating, x is larger than or equal to 1, the middle layer is of a columnar
crystal structure, and the
hardness of the middle layer is 5-10 GPa; the outermost layer is a non-stoichiometric ratio (Cr, Al) Nx coating, x is larger than or equal to 0.6 and smaller than or equal to 0.9, a nanocrystalline structure is shown, and the
hardness is 12-25 GPa. Component regulation,
hardness gradient and a
microstructure are subjected to
collaborative design, so that the coating has excellent
wear resistance, high
oxidation resistance and
structural integrity at the same time under a harsh nuclear working condition, the
safety margin of the
zirconium alloy cladding under normal service and accident working conditions is greatly improved, and the service life of the
zirconium alloy cladding under normal service and accident working conditions is greatly prolonged.