532results about How to "Reduce hydrogen consumption" patented technology

A method is provided for manufacturing cleaner fuels, in which NPC (Natural Polar Compounds), naturally existing in small quantities within various petrolic hydrocarbon fractions, are removed from the petrolic hydrocarbon fractions ranging, in boiling point, from 110 to 560° C. and preferably from 200 to 400° C., in advance of catalytic hydroprocessing. The removal of NPC improves the efficiency of the catalytic process and produces environment-friendly products, such as diesel fuel with a sulfur content of 50 ppm (wt) or lower. Also, the NPC can be used to improve fuel lubricity.

A continuous process for upgrading sour crude oil by treating the sour crude oil in a two step process that includes a hydro-demetallization section and a hydro-desulfurization section, both of which are constructed in a permutable fashion so as to optimize the operating conditions and catalyst lifespan to produce a high value crude oil having low sulfur and low organometallic impurities.

The invention provides a catalytic conversion method for producing gasoline containing rich aromatic hydrocarbon. The catalytic conversion method comprises the following steps: cutting catalytic cracking light cycle oil to obtain a light fraction and a heavy fraction, performing hydrogenation treatment on the heavy fraction to obtain a hydrogenated heavy fraction, singly and respectively conveying the light fraction and the heavy fraction into different riser reactors of catalytic cracking devices, performing a cracking reaction in the presence of a catalytic cracking catalyst, and separating reaction products to obtain a product containing the gasoline which contains rich aromatic hydrocarbon and the light cycle oil. According to the method, single catalytic cracking devices are used for processing the light fraction and the hydrogenated heavy fraction of the light cycle oil to satisfy harsh conditions necessary for the catalytic cracking reaction of different fractions of the light cycle oil to the maximum, so as to produce catalytic gasoline containing rich benzene, toluene and xylene to the maximum.

The invention relates to a hydrocracking method for producing chemical materials to the maximum with low cost, comprising the following steps: mixing raw oil and hydrogen gas , entering a first reaction area, sequentially contacting with hydrofining catalyst and hydrocracking catalyst, reacting under the pressure of 6.0-16.0 MPa; carrying out oil-gas separation and fractionation on the reaction products thereof to obtain liquefied gas, light naphtha fractions, heavy naphtha fractions, middle fractions and tail oil fractions; mixing the middle fractions and the hydrogen gas and enteringa second reaction area, contacting with the hydrocracking catalyst under the pressure of 1.0-5.5 MPa to react; and carrying out oil-gas separation on the reaction products thereof and entering a fractionation system . By adopting the method, heavy raw materials such as vacuum gas oil, coking gas oil and the like are treated to obtain more than 98 weight percent chemical materials. In the invention, themiddle fractions are wholly converted into the chemical materials in the low pressure condition, and low hydrogen consumption, low investment cost and low operation cost are realized.

A power supply device or system for aeronautics, having a hydrocarbon supply for supplying an engine with hydrocarbon fuel and a hydrogen supply having a fuel reformer for producing hydrogen from hydrocarbon fuel from said hydrocarbon supply. The hydrogen supply is connected to a hydrogen-powered fuel cell for producing electric power and to a hydrogen injecting system for injection of hydrogen into a combustion chamber of the engine. Further, the invention relates to an aircraft having an engine that can be supplied by that power supplying device or system, and to a method for operating said engine.

Method of producing syngas in an IGCC system, comprising compressing and heating carbon dioxide-rich gas to produce heated compressed carbon dioxide-rich gas, mixing the heated compressed carbon dioxide-rich gas with oxygen and feedstock to form a feedstock mixture, subjecting the feedstock mixture to gasification to produce syngas, cooling the syngas in a radiant syngas cooler, contacting syngas cooled in the radiant syngas cooler with compressed carbon dioxide-rich gas to further cool the syngas, and removing an amount of carbon dioxide-rich gas from the product mixture and compressing the removed carbon dioxide-rich gas prior to mixing with oxygen and feedstock.

The invention discloses a method for hydrogenation of coal tar via a fluidized bed. The method comprises the following steps: subjecting a coal tar raw material to hydro-upgrading; carrying out separation to remove water; and then carrying out hydrorefining and fractionation so as to obtain a gasoline fraction, a diesel fraction and hydrogenation tail oil. A hydro-upgrading catalyst used in the method comprises iron oxyhydroxide, organic polybasic carboxylic acid, macroporous alumina, a molecular sieve and pseudo-boehmite; and a hydrofining catalyst used in the method comprises iron oxyhydroxide, organic polybasic carboxylic acid, macroporous alumina and a binder. The method provided by the invention adopts cheap iron oxyhydroxide as an active metal component, the hydro-upgrading catalyst and the hydro-refining catalyst are graded, so cost is low. According to the invention, moderate cracking of coal tar is carried out before refining of coal tar, so impurities in coal tar are effectively removed, product distribution and product quality are adjusted, and the running period of a device is prolonged.

The invention discloses a method for using non-noble metal catalyst to catalyze decarboxylation of saturated fatty acid to prepare long-chain alkane. The method includes: 1) adding saturated fatty acid and a non-noble metal catalyst into a high-temperature and high-pressure reaction kettle; 2) conducting heating to 300-390DEG C to carry out decarboxylation for 0.5-8h; 3) cooling the decarboxylation product, conducting dissolving by an organic solvent, and performing filtering to obtain a liquid product and a solid catalyst; and 4) cleaning and regenerating the non-noble metal catalyst for reuse. The non-noble metal catalyst is prepared by a co-precipitation method or impregnation method, and the catalyst is regenerated through reductive calcination in hydrogen. The reaction process involved in the invention has the characteristics of no need for a solvent, low energy consumption, and zero emission. The non-noble metal catalyst can effectively catalyze decarboxylation, the catalyst is low in cost and is easy to recover, and the process is simple and green.

The invention discloses a method for hydrotreating heavy hydrocarbon. A hydrotreatment process comprises a pre-hydrogenation reaction zone, an up-flow hydrogenation reaction zone and a fixed bed-trickle bed reaction zone. The method comprise the following steps that: catalytic cracking slurry oil and/or catalytic cracking heavy cycle oil pass/passes through the pre-hydrogenation reaction zone; the pre-hydrogenation reaction zone adopts a fixed bed-trickle bed operation mode; both the reaction effluent of the pre-hydrogenation reaction zone and a residual oil raw material are jointly introduced into the up-flow hydrogenation reaction zone and the fixed bed-trickle bed reaction zone in turn; and the final reaction effluent is separated. The method of directly taking the catalytic cracking residual oil, the catalytic cracking heavy cycle oil and the like as fluxing oil of the residual oil raw material is changed, and the catalytic cracking residual oil and the catalytic cracking heavy cycle oil are pretreated to retard the coking of a catalyst and effectively prevent the generation of a bed layer hot point, so that stable operation of an up-flow reactor is guaranteed, the service life of the catalyst is prolonged, simultaneously the product quality is improved.

The invention relates to a pure silicon S-1 molecular sieve catalyst for packaging metal nanoparticles and a preparing method and application of the catalyst. By means of the catalyst, a metal precursor is added in the pure silicon S-1 molecular sieve in-situ synthesis process, and the metal nanoparticles are packaged by a pure silicon S-1 molecular sieve through a one-step method. The packaging catalyst is neat in morphology, and the metal nanoparticles are uniform in distribution and particle size and have the size of 1-10 nm. The metal content in the pure silicon S-1 molecular sieve for packaging the metal nanoparticles is 0.1-20 wt%. The packaging catalyst is applied in the phenol catalysis reaction; compared with a metal catalyst synthesized through a traditional wet impregnation method, the phenol conversion rate, the phenol selectivity and the catalysis stability are remarkably improved.

The invention relates to a process of preparing hydrocarbon compounds. According to the process, grease is used as a raw material, the raw material contacts with hydrogen on a catalyst, and a hydrocarbon compound is generated through one-step catalytic reaction. The catalyst involved in the process is a supported metal/carrier catalyst M1-[Sup], and has catalytic activity for converting the grease into the hydrocarbon compounds through one-step reaction, wherein in the composition of the catalyst, M1 is an active metal component, and [Sup] is an acid carrier component. The process can be used for producing the hydrocarbon compounds which have high cetane values, low freezing points, and main components of C11-C24 isoparaffin by using the grease as the raw material, and the hydrocarbon compounds can be used as diesel oil and/or aviation kerosene. In the process provided by the invention, the yield of converting the grease into C11-C24 alkanes is more than 70wt.%, wherein the selectivity of the isoparaffin is more than 60wt.%.

The present invention discloses a hydrocracking method. According to the method, heavy distillate oil and hydrogen gas are mixed and then enter a hydrorefining reactor to carry out a hydrorefining reaction; the hydrorefining reaction effluent directly enters a hydrocracking reactor and is subjected to a contact reaction with grading catalyst bed layers in the hydrocracking reactor, wherein at least two cracking catalyst bed layers are arranged inside the hydrocracking reactor, and the hydrogenation activity of the hydrocracking catalyst presents the decrease tendency according to the reaction material flowing direction; and the hydrocracking reaction effluent is subjected to separation and fractionation to obtain the hydrocracking products including heavy naphtha and tail oil. With the method of the present invention, the heavy component hydrocracking effect can be ensured while the excessive hydrogenation and the excessive cracking of the heavy naphtha are reduced, and the chemical hydrogen consumption is reduced, such that the aromatic potential and the selectivity of the heavy naphtha are increased.

The invention relates to turbine engines used in aeronautics, but also for industrial and marine turbine engines. To reduce turbine engine combustor gaseous emissions at given combustor sizes or to reduce combustor sizes at given combustor gaseous emissions, the invention proposes the injection of hydrogen into the combustor in response to a power output level. According to a preferred embodiment, gaseous hydrogen is always injected at low-power operations and switched off at mid-power and high-power operations.

The invention discloses a resource utilization method for waste lubricating oil and belongs to the fields of environmental protection and energy technology. The method is characterized in that the waste lubricating oil is used as the raw material, is distilled and then is hydrofined to produce high-quality gasoline, diesel and base oil, and comprises the steps that the waste lubricating oil is firstly distilled to obtain a fraction with the temperature lower than 500 DEG C and a fraction with the temperature higher than 500 DEG C, then the fraction with the temperature lower than 500 DEG C is reacted in a manner of hydrofining on a sulfide catalyst, a monoene compound is removed by monoolefine hydrostturation reaction, desulfuration, denitrification, deoxygenation and colloid removal are carried out to produce odorless high-quality mixed oil of the gasoline, the diesel and the base oil, and then the mixed oil is distilled to obtain distillate oil of the gasoline, the diesel and the base oil. The distilled fraction with the temperature higher than 500 DEG C is hydrofined after being reactively distilled. The method disclosed by the invention has the advantages of simple process, high catalyst activity and selectivity, and good economic benefits and industrial application prospects.

The method for producing cyclohexanone by using coked benzene is implemented according to the following steps: A. hydrogenation of the coked benzene to prepare cyclohexene; B. extraction and rectification; C. hydratization of the cyclohexene to prepare cyclohexanol; D. separation and extraction of the cyclohexanol; E. dehydrogenation of the cyclohexanol to prepare the cyclohexanone; and F. refining of alcohol and ketone. The method has the advantages that 1. as the coked benzene, the product of the coal chemical industry, is used as the raw material, the method has resource advantage and cost advantage and saves 15-20 percent of resource and cost when compared with a cyclohexane method; 2. the method has high comprehensive yield rate and low hydrogen consumption, almost 99 percent of the coked benzene is converted into usable products, namely the cyclohexanone and the cyclohexane, the ratio between the cyclohexanone and the cyclohexane is 1:0.25, and the hydrogen consumption is reduced by two thirds; 3. the method is environment friendly; a small amount of waste gas and waste liquid is generated, and the investment in waste disposal is small, therefore the method is a clean production technology; and 4. the method is safer; the hydrogenation reaction and the hydratization reaction are both carried out in liquid, conditions are mild, and the method is safer when compared with a traditional oxidation technology, prevents the corrosion and the byproduct blockage and has high operation stability.

The present invention is loading method of hydroprocessing catalyst. Unlike conventional grading loading scheme, The hydrogenating and denitrogenating reaction region is loaded with the catalyst in antitone grading mold, in which the activity of the hydrogenating and denitrogenating catalyst in the downstream bed side is slightly lower than that in the upstream bed side, and the pore size of the catalyst in the downstream bed side is slightly greater than that in the upstream bed side. The said loading method can control the temperature raise of hydrogenating and denitrogenating catalyst bed, reduce cold hydrogen amount to lower the hydrogen consumption of the apparatus, reduce the carbon deposit speed in the catalyst bed to reduce bed pressure drop of bed, and prolong the service life of catalyst.