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325 results about "Ti oxides" patented technology

Method for preparing spherical titanium oxide niobate anode material in large scale by utilizing spray drying method and application thereof to lithium ion battery

The invention discloses a method for preparing a spherical titanium oxide niobate anode material in a large scale by utilizing a spray drying method and application thereof to a lithium ion battery. The method comprises: 1, dispersing and dissolving a titanium source and a niobium source in an equal molar ratio in a solvent system, and sufficiently stirring to enable the titanium source and the niobium source to be uniformly dispersed; 2, spraying out the mixed solution in a spray dyer according to a certain flow, and drying obtained powder in an oven to obtain a precursor; 3, calcining the precursor in a high-temperature furnace in the air atmosphere at a temperature of 800 to 1,400 DEG C so as to obtain the spherical TiNb2O7 anode material. The spherical titanium-niobium composite oxide TiNb2O7 prepared by the method has excellent electrochemical performance, and has high coulombic efficiency and reversible capacity and excellent high-rate charge/discharge performance and safety performance when being used as a lithium ion battery anode material. The spherical titanium oxide niobate anode material is low in raw material cost, is non-toxic and harmless, and has a very wide application prospect.
Owner:HARBIN INST OF TECH

Honeycomb manganese denitration catalyst and preparation method thereof

The invention relates to a honeycomb manganese denitration catalyst and a preparation method thereof. The method includes the following steps that manganese salt and a complexing agent are dissolved in water, titanium dioxide is added and stirred, ultrasonic dipping, drying and grinding are conducted, and Mn-Ti oxide solid particles are obtained, wherein the molar ratio of the manganese salt to the complexing agent is (65-187):1; metal salt and cerium salt are dissolved in water to obtain a mixed metal solution, wherein metal salt is at least one of ferric salt, cobalt salt, lanthanum salt, antimony salt and nickel salt; a pore-forming agent, an adhesive, an extrusion aid, a reinforcing agent, the Mn-Ti oxide solid particles and the mixed metal solution are mixed and formed into a honeycomb blank, and drying and forging are conducted. The catalyst is good in active component dispersity, is not easily sintered, good in pore structure, large in porosity and high in mechanical strength, the axial compressive strength of the catalyst is 4.7-5.1 MPa, and the radial compressive strength of the catalyst is 1.2-1.4 MPa. The porosity of the catalyst is 84-90%. The catalyst prepared through the method has relatively high denitration activity in the range of 120-250 DEG C and is suitable for low-temperature denitration.
Owner:CHINA BUILDING MATERIALS ACAD

Lithium titanate particles and process for producing the lithium titante particles, MG-Containing lithium titanate particles and process for producing the MG-Containing lithium particles, negative electrode active substance particles for non-aqueous electrolyte secondary batteries, and non-aqeous electrolyte secondary battery

According to the present invention, there are provided lithium titanate particles which exhibit an excellent initial discharge capacity and an enhanced high-efficiency discharge capacity retention rate as an active substance for non-aqueous electrolyte secondary batteries and a process for producing the lithium titanate particles, and Mg-containing lithium titanate particles. The present invention relates to lithium titanate particles with a spinel structure comprising TiO2 in an amount of not more than 1.5%, Li2TiO3 in an amount of not less than 1% and not more than 6%, and Li4Ti5O12 in an amount of not less than 94% and not more than 99% as determined according to Rietveld analysis when indexed with Fd-3m by XRD, and having a specific surface area of 7 to 15 m2/g as measured by BET method, a process for producing lithium titanate particles comprising the steps of adding and mixing a water-soluble lithium solution into a water suspension of an oxide of titanium having a BET specific surface area of 40 to 400 m2/g and a primary particle diameter of 5 to 50 nm and subjecting the resulting mixed suspension to aging reaction at a temperature of 50 to 100° C.; subjecting the resulting reaction product to filtration, drying and pulverization; and subjecting the obtained dry particles to heat-calcination treatment at a temperature of 550 to 800° C., and Mg-containing lithium titanate particles having a composition represented by the formula: LixMgyTizO4 wherein x, z>0; 0.01≦y≦0.20; 0.01≦y/z≦0.10; and 0.5≦(x+y)/z≦1.0, the Mg-containing lithium titanate particles having a BET specific surface area of 5 to 50 m2/g, a spinel single phase as a crystal structure, and a lattice constant (a) represented by a value of 0.050y+8.3595<a≦0.080y+8.3595 (Å).
Owner:TODA IND

Vanadium-base SCR (selective catalytic reduction) catalyst for efficiently treating nitric oxides in diesel engine exhaust and preparation method thereof

The invention relates to a novel vanadium-base SCR (selective catalytic reduction) catalyst for efficiently treating nitric oxides in diesel engine exhaust and a preparation method thereof and belongs to the technical field of emission of purified motor vehicle exhaust through a catalytic reduction method. The novel vanadium-base SCR catalyst comprises a first component and a second component, wherein the first component is selected from vanadium oxides, vanadium-erbium composite oxides and vanadium-iron composite oxides; the second component is selected from one or combination of titanium oxides, titanium-tungsten composite oxides and titanium-silicon composite oxides. The novel vanadium-base SCR catalyst is applied to a diesel engine exhaust after-treatment system in a form of coating the catalyst on cordierite honeycomb ceramics to serve as a honeycomb type catalyst. The invention also discloses a method for preparing the catalyst. The method comprises the following steps: preparing a first component through a precursor of the first component; loading the first component to the second component, and coating the component to the surface of the cordierite honeycomb ceramics. The catalyst has high-efficiency catalytic performance and environment friendliness.
Owner:WUXI WEIFU ENVIRONMENT PROTECTION CATALYST

Ink composition and application for same, as well as product with selectively-metallized surface and preparation method for same

The invention provides an ink composition and an application for the same. The composition contains titanium oxides shown in formula I: TiO2-sigma and a connecting material, wherein relative to 100 parts by weight of the titanium oxides shown in formula I, the content of the connecting material is 1-30 parts by weight. The invention further provides a product with a selectively-metallized surface and a preparation method for the same. The method comprises the following steps of: applying the ink composition on the surface needing to be metallized of an insulating base material, so as to form an ink layer; and plating one or more than two metal layers on the surface of the insulating base material with the ink layer by virtue of electroplating or chemical plating. Compared with the generally-used conductive precious metals, metal compounds in the ink composition provided by the invention are low in price, wide in raw material source, and capable of remarkably reducing production cost for signal components. The method for selectively metallizing the surface of the insulating base material provided by the invention is strong in universality, capable of being applied to insulating base materials with various sources, and simple and convenient in process.
Owner:BYD CO LTD

High energy type zinc oxide piezoresistor material and preparation method thereof

The invention relates to a high energy type zinc oxide piezoresistor material and a preparation method thereof, which belong to the technical field of piezoresistor material preparation. The preparation method comprises (1) enabling manganese carbonate, barium carbonate and strontium carbonate to be mixed, ball-milled and calcined to obtain mixture A; (2) enabling titanium oxide, antimony pentoxide, bismuth trioxide, cobalt oxide, nickel oxide, silica and stannic oxide to be mixed in submicron-sized zinc oxide powder to obtain mixture B which is mixed and ball-milled with the mixture A to obtain mixture C; and (3) adding aluminum nitrate, silver nitrate, magnesium nitrate, a dispersing agent and an antifoaming agent in the mixture C, ball-milling and drying to obtain high energy type zinc oxide piezoresistor composite powders which are formed in a pressing mode and sintered to obtain a high energy type zinc oxide piezoresistor. The high energy type zinc oxide piezoresistor material is simple in preparation method, prepared zinc oxide piezoresistor has high energy density, low leakage current and residual voltage ratio, batch of products is stable, acceptability is high, and the high energy type zinc oxide piezoresistor material is applicable to scale production.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI
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