The method comprises the following steps: adding the activated curing agent into
wastewater, controlling the temperature of the
wastewater to be 45-60 DEG C, controlling the pH value of the
wastewater to be 9-11, and then filtering to remove a
solid phase so as to obtain a pretreatment solution; rectifying and separating the pretreatment liquid to obtain an
ammonia water product and crude
phenol water; adjusting the pH value of the crude
phenol water to 4.5-6.5 by using inorganic acid, then removing insoluble substances separated out from the crude
phenol water, and rectifying to remove
hydrogen sulfide in the crude phenol water to obtain purified phenol water; extracting and purifying the phenol water by using an organic extracting agent to obtain
purified water and a loaded organic phase; and recovering phenol from the loaded organic phase to obtain a
phenol product, and returning the obtained regenerated extractant to purified phenol water for recycling. According to the scheme, the problems of coking and blocking in the conventional phenol-
ammonia wastewater treatment process can be effectively solved, the
energy consumption and medicament consumption in the
deamination process are reduced, the formation of a
third phase in the
phenol extraction process is reduced, the purity of an
ammonia water product and a
phenol product is improved, and the
pollutant removal rate of purified wastewater is improved.