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111 results about "Oxocarbon" patented technology

An oxocarbon or oxide of carbon is a chemical compound consisting only of carbon and oxygen. The simplest and most common oxocarbons are carbon monoxide (CO) and carbon dioxide (CO₂) with IUPAC names carbon(II) oxide and carbon(IV) oxide respectively. Many other stable (practically if not thermodynamically) or metastable oxides of carbon are known, but they are rarely encountered, such as carbon suboxide (C₃O₂ or O=C=C=C=O) and mellitic anhydride (C₁₂O₉).

Process for Preparing 1,3-Butadiene from N-Butenes by Oxidative Dehydrogenation

The invention relates to a process for preparing butadiene from n-butenes, which comprises the steps:A) provision of a feed gas stream a comprising n-butenes;B) introduction of the feed gas stream a comprising n-butenes and an oxygen-comprising gas into at least one oxidative dehydrogenation zone and oxidative dehydrogenation of n-butenes to butadiene, giving a product gas stream b comprising butadiene, unreacted n-butenes, water vapor, oxygen, low-boiling hydrocarbons, high-boiling secondary components, possibly carbon oxides and possibly inert gases;Ca) cooling of the product gas stream b by contacting with an organic solvent as coolant,Cb) compression of the product gas stream b in at least one compression stage, giving at least one aqueous condensate stream c1 and a gas stream c2 comprising butadiene, n-butenes, water vapor, oxygen, low-boiling hydrocarbons, possibly carbon oxides and possibly inert gases;D) separation of incondensable and low-boiling gas constituents comprising oxygen, low-boiling hydrocarbons, possibly carbon oxides and possibly inert gases as gas stream d2 from the gas stream c2 by absorption of the C4-hydrocarbons comprising butadiene and n-butenes in an absorption medium, giving an absorption medium stream loaded with C4 -hydrocarbons and the gas stream d2, and subsequent desorption of the C4-hydrocarbons from the loaded absorption medium stream to give a C4-product gas stream d1,E) separation of the C4 product stream d1 by extractive distillation using a solvent selective for butadiene into a stream e1 comprising butadiene and the selective solvent and a stream e2 comprising n-butenes;F) distillation of the stream f2 comprising butadiene and the selective solvent to give a stream g1 consisting essentially of the selective solvent and a stream g2 comprising butadiene.
Owner:BASF AG

Cerium-zirconium composite oxide with high specific surface area, and preparation method and application thereof

The present invention provides a cerium-zirconium composite oxide with a high specific surface area. The cerium-zirconium composite oxide comprises cerium oxide, zirconium oxide and at least one oxide of a rare earth metal element other than cerium, and the composite oxide has a specific surface area of 80 m<2>/g or above, a pore volume of 0.50-0.60 mL/g, an oxygen storage amount of 500-1200 [mu]mol O2/g and two-hole group distributed apertures after subjected to heat treatment at 850 DEG for 4-8 h, wherein the diameter of the first pore group is concentrated at 1-8 nm, and the diameter of the second pore group is concentrated at 20-60 nm. The cerium-zirconium composite oxide provided by the invention has a higher specific surface area and a better pore volume distribution than composite oxides prepared by existing methods, has good low-temperature catalytic activity, and can be used for catalyzing hydrocarbons, carbon oxides and/or nitrogen oxides in mobile source exhaust gas. The invention also provides a preparation method of the cerium-zirconium composite oxide. The composite oxide which has uniform element crystal lattice doping distribution and does not produce phase separation can be prepared, and is of great significance to study mobile source exhaust gas treatment purifying agents containing the cerium-zirconium composite oxide.
Owner:SHANDONG SINOCERA FUNCTIONAL MATERIAL CO LTD

Preparation method and application of high-purity nanometer silicon

The invention discloses a method for preparing high-purity nanometer silicon. According to the method, calcium chloride or a calcium chloride-containing mixed fused salt is used as electrolyte, silicon dioxide or quartz is put in a metal current collector to serve as a cathode, graphite or an inert electrode is used as an anode, constant potential electrolysis is carried out under the condition that the electrolytic potential is controlled by adopting a reference electrode at a certain electrolysis temperature under the inert gas protection, thus obtaining the needed product, namely the high-purity nanometer silicon. The invention also discloses application of the high-purity nanometer silicon. The preparation method is high in electrolytic efficiency, the electrolytic efficiency is more than 70 percent, and the energy consumption is far lower than the energy consumption during silicon preparation through an industrial carbon heat method. In addition, lots of carbonic oxides are emitted in the process of preparing monatomic silicon through the industrial carbon heat method, and lots of charcoal is consumed. Moreover, the charcoal is not needed to serve as a reducing agent, an inert anode is adopted, and oxygen is discharged from the anode, so that zero emission is realized. Finally, the product obtained by the method is high in purity.
Owner:JIANGSU HUAFU STORAGE NEW TECH DEV +1
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