The invention belongs to the field of organic
silicon, and particularly provides self-emulsifying cationic
silicone wax as well as a preparation method and application thereof. The self-emulsifying cationic
silicone wax is represented by the following average composition formula (I): R < 1 > aR < 2 > bR < 3 > cSiO < 4-a-b-c > / 2 (I), in the formula, R1 is represented by a general formula (II), and R2 is represented by a general formula (III); r3 is an
organic group; * represents a connection position; a ranges from 0.01 to 0.5, b ranges from 0.05 to 0.5, and c ranges from 1.4 to 2.5. The preparation method of the self-emulsifying cationic
silicone wax comprises the following steps. The self-emulsifying cationic silicone wax provided by the invention is soft hydrophobic silicone wax, not only can provide excellent waterproofness and soft hand feeling, but also can improve the durability of the effect, and can be widely applied to the fields of daily chemicals, textiles, coatings and the like.