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72results about How to "Alleviate coking" patented technology

System and Method for Introducing an Additive into a Coking Process to Improve Quality and Yields of Coker Products

Gas oil components, coking process recycle, and heavier hydrocarbons are cracked or coked in the coking vessel by injecting an additive into the vapors of traditional coking processes in the coking vessel. The additive contains catalyst(s), seeding agent(s), excess reactant(s), quenching agent(s), carrier(s), or any combination thereof to modify reaction kinetics to preferentially crack or coke these components. The quenching effect of the additive can be effectively used to condense the highest boiling point compounds onto the catalyst(s), thereby focusing the catalyst exposure to these target reactants. With a catalyst to crack these highest boiling point materials, this mechanism can effectively increase the catalyst's selectivity, thereby increasing its efficiency and reducing catalyst requirements and costs. Selective, catalytic conversion of the highest boiling point materials in the coking process product vapors (coker recycle and/or ‘heavy tail’ of the heavy coker gas oil) may be accomplished with an exemplary embodiment of the present invention in varying degrees. Exemplary embodiments of the present invention can also provide methods to control the (1) coke crystalline structure and (2) the quantity and quality of volatile combustible materials (VCMs) in the resulting coke. Pet coke from this process may have unique characteristics with substantial utility.
Owner:ETTER ROGER G

Direct coal liquefaction cycle solvent, preparation method thereof and application thereof

The invention provides a direct coal liquefaction cycle solvent, a preparation method of the direct coal liquefaction cycle solvent and application of the direct coal liquefaction cycle solvent. The preparation method comprises the steps of S1, carrying out hydrogenation on a mixture of petroleum refining secondary products and direct coal liquefaction oil, and obtaining a hydrogenation product, S2, fractionating the hydrogenation product, and obtaining light distillate oil, medium distillate oil and heavy distillate oil, and S3, mixing the heavy distillate oil with a part of the medium distillate oil, and obtaining the direct coal liquefaction cycle solvent. In the preparation method of the direct coal liquefaction cycle solvent, on one hand, a large amount of arene is contained in the petroleum refining secondary products, the hydrogenation product is rich in components such as tetrahydronaphthalene, therefore, the hydrogen supplying capacity of the direct coal liquefaction cycle solvent can be obviously improved, and the yield of the direct coal liquefaction oil is improved; on the other hand, a part of high-added-value diesel distillate with the boiling range lower than 350 DEG C in the direct coal liquefaction cycle solvent is substituted with the petroleum refining secondary products, the diesel yield is improved, the economical efficiency of the coil liquefaction technology is remarkably improved, and the problem that an existing cycle solvent gets light can be solved.
Owner:CHNA ENERGY INVESTMENT CORP LTD +2

Direct coal liquefaction circulation solvent and preparation method and application of direct coal liquefaction circulation solvent

The invention provides a direct coal liquefaction circulation solvent and a preparation method and application of the direct coal liquefaction circulation solvent. The preparation method comprises the steps that S1, hydrogenation is carried out on a mixture of coal tar anthracene oil and direct coal liquefaction oil to obtain a hydrogenation product, S2, fractionation is carried out on the hydrogenation product to obtain light-weight distillate oil, middle-weight distillate oil and heavy-weight distillate oil, and S3, the heavy-weight distillate oil is mixed with a part of middle-weight distillate oil to obtain the direct coal liquefaction circulation solvent. According to the preparation method, on one hand, a large amount of aromatic hydrocarbon is contained in the coal tar anthracene oil, the hydrogenation product is rich in components such as tetrahydronaphthalene, therefore, the hydrogen supply capacity of the circulation solvent can be obviously improved, and the yield of direct coal liquefaction oil is improved; on the other hand, a part of high value-added gas and diesel oil distillate with the boiling range lower than 350DEG C in the direct coal liquefaction circulation solvent is substituted with the coal tar anthracene oil, the diesel oil yield is improved, in addition, the light-weight problem of an existing circulation solvent can be relieved, and deposition and coking of materials in a reactor in the direct coal liquefaction technological process are relieved.
Owner:CHNA ENERGY INVESTMENT CORP LTD +2

System and method of blending combustion of coal type with low ash melting point in coal-fired utility boiler

The invention discloses a system and method of blending combustion of a coal type with a low ash melting point in a coal-fired utility boiler and belongs to the technical field of coal-fired utility boiler operation. The coal-fired utility boiler is equipped with a positive-pressure, direct-firing, double-in and double-out steel ball coal pulverizer; the method of blending combustion of coal type with the low ash melting point in the coal-fired utility boiler comprises the following steps: the coal type with the low ash melting point and a coal type with a high ash melting point are sent into the steel ball coal pulverizer from one end of the positive-pressure, direct-firing, double-in and double-out steel ball coal pulverizer respectively; after thorough mixing and grinding, powder is uniformly output from two ends of the steel ball coal pulverizer; after the blending, compared with the melting point of the coal type with a low ash melting point, the melting point of the blended ash is increased to a relatively large extent; under various boiler loading, through adjusting the belt rotational speeds of coal feeders that correspond to the coal type with the low ash melting point and the coal type with the high ash melting point, the mixing proportion control is realized on the coal type with the low ash melting point. The system and method of blending combustion of coal type with the low ash melting point in the coal-fired utility boiler can improve the combustion and utilization proportion of the coal type with the low ash melting point to the utmost extent, on the basis of effectively relieving the boiler from coking and ensuring the safe operation of the boiler; the cost of fuel is reduced; the economical efficiency in the operation of the coal-fired utility boiler machine set is improved.
Owner:HUANENG POWER INTERNATIONAL +3

Condense-dilute type double-cyclone cylinder pulverized coal burner and pulverized coal boiler using same

The invention discloses a condense-dilute type double-cyclone cylinder pulverized coal burner which comprises a pulverized coal entrance channel, a pulverized coal concentrator and two cyclone separation type burners communicated with the pulverized coal entrance channel. The burner is characterized in that the pulverized coal concentrator is arranged in the pulverized coal entrance channel; and a blade in the pulverized coal concentrator inclines towards the side away from a boiler side wall and a wing wall adjacent to the pulverized coal concentrator along the flowing direction of pulverized coal so as to divide a pulverized coal airflow into a condense part and a dilute part. The invention changes a traditional double-cyclone cylinder burner into a condense-dilute type and has more obvious effect on reducing the discharge of NOx. Aiming at the reformation of an original burner, the condense-dilute type double-cyclone cylinder pulverized coal burner is the equipment having smallest changes, lowest cost and easiest implementation, a more effective measure for solving side (wing) wall coking under a current coal condition and can create a good condition for the safe and stable operation of boilers.
Owner:DONGFANG BOILER GROUP OF DONGFANG ELECTRIC CORP

Method and apparatus for continuously and rapidly separating pyrolysis oil

The invention discloses a method and an apparatus for continuously and rapidly separating a pyrolysis oil, which is characterized in that a waste rubber, a waste plastic or the pyrolysis oil generated by thermal cracking of biomass is filtered and enters into a first preheater, the preheated pyrolysis oil enters into a cyclone hydraulic separator in a tangential direction, and enables spiral movement downwardly, the impurities spirally flow downwards to an outlet of a cone base due to inertial centrifugal force, the pyrolysis oil is discharged from a center tube at the top and enters into a second preheater for heating, then enters into an evaporator, the certain temperature is kept in the evaporator, steam is continuously introduced in the evaporator, the steam carries the distilled components enter into a condenser from the top of the evaporator together for condensate recovery, and the heavy components are sent from the bottom of the evaporator and cooled to obtain the finished product. The apparatus comprises a filter, a charge pump, the first preheater, the cyclone hydraulic separator, the second preheater, the evaporator in series, the top of the evaporator is connected to the condenser, the bottom of the evaporator is connected to a cooler. The method and apparatus for continuously and rapidly separating the pyrolysis oil have the advantages of high automation degree, and convenient and easy operation.
Owner:JIANGSU QIANGLIN BIO ENERGY +1

High-efficiency catalyst for producing chloroform by gas phase hydrogenation of carbon tetrachloride

The invention relates to a high-efficiency catalyst for producing chloroform by gas phase hydrogenation of carbon tetrachloride. The high-efficiency catalyst is mainly characterized in that the activeingredient platinum is distributed in a thick-shell layer permeation form on a carrier alumina. According to the catalyst, the precious metal platinum serves as the active ingredient, the introduction amount of the platinum is 0.1-1% of the total mass of the carrier, the carrier is alumina of being spherical, strip-shaped or in the other shapes, and the carrier is pre-treated by adopting an organic acid competitive adsorbent, so that the active ingredient platinum is distributed in the thick-shell layer permeation form on the carrier. Compared with a catalyst without being subjected to organic acid pretreatment, the catalyst has high activity, conversion rate and selectivity under the same operating conditions, capable of effectively reducing the production of harmful conjugate impuritiessuch as hexachloroethane and tetrachloroethylene, and has long service life. The catalyst is applied to industrial production, and when the transformation capacity of the carbon tetrachloride is maintained at 40-50Kg / day.Kg, the catalyst can be continuously operated by 180 days or longer, and the transformation rate and selectivity are respectively maintained at 98% or 70% or higher.
Owner:JIANGSU LEE & MAN CHEM +2
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