This invention relates to the field of piezoelectric materials technology, specifically to a chiral
nitrogen-containing heterocyclic organic crystalline piezoelectric material and its preparation method. The organic crystalline piezoelectric material is N-cyanoethyl-( S )-2-methylpiperazine
hydrochloride, whose core is a one-dimensional
hydrogen-bonded chain construction strategy of unilaterally protonated chiral
piperazine, with protonated N-cyanoethyl-( S Using 2-methylpiperazine cations as structural building blocks and
chloride ions as charge balancers, a highly oriented one-dimensional
hydrogen bond chain is constructed by regulating intermolecular
hydrogen bonding. This enhances the ordered arrangement of molecular dipoles and optimizes the synergistic mode of
lattice strain-polarization response, achieving a breakthrough in piezoelectric properties. The material exhibits a
piezoelectric coefficient as high as ±80 pC / N and an
electromechanical coupling coefficient as high as 0.35, far exceeding known chiral organic piezoelectric materials. Furthermore, it demonstrates excellent
thermal stability and can be widely applied in demanding applications such as micro-pressure sensors, low-frequency vibration detectors, and micro energy harvesters.