32 results about "Perinone" patented technology

The invention relates to a method for production of an aqueous dispersion of polymer-encapsulated pigments, characterised in that (a) an aqueous pigment dispersion, containing at least one organic pigment (P), selected from the group of azo, isoindolinone, isoindoline, anthanthrone, thioindigo, thiazinindigo, triarylcarbonium, quinophthalone, anthraquinone, dioxazine, phthalocyanine, quinacridone, quinacridonquinone, indanthrone, perylene, perinone, pyranthrone, diketopyrrolopyrrole, isoviolanthrone and azomethine pigments, at least one detergent (T), and water is prepared, (b) a monomer miniemulsion, stabilised by a hydrophobic organic compound with a water solubility at 20 DEG C of at most 5x10<-5> g / l, is prepared from a polymerisable monomer (M) and at least one detergent (T) in water, (c) a monomer pigment emulsion is prepared, whereby the aqueous dispersion from (a) and the monomer miniemulsion from (b) are mixed and homogenised and (d) the pigment-containing monomer from (c) is polymerised in the presence of a polymerisation initiator and / or by heat, whereupon an encapsulation of the pigment with the polymer thus formed occurs.

The present invention relates to black pigment compositions comprising(a) carbon black, and(b) a compound of the formula(MO3S)m-Q(CH2)k—X]n,  (I)whereinQ is a pigment or pigment intermediate radical selected from the group of anthraquinone, perinone, perylene, diketopyrrolopyrrole, thioindigo, iminoisoindoline, iminoisoindolinone, quinacridone, 6,13-dihydroquinacridone, flavanthrone, dioxazine, indanthrone, anthrapyrimidine and quinophthalone,X is a cyclo hetero aliphatic group with at least one 5 or 6 atom ring or a hetero aromatic group with at least one 6 atom ring,M is hydrogen, a metal cation or nitrogen cation,k is 0 or 1, andm and n are each independently of the other from 0 to 4, wherein 0 and 4 are not simultaneously 0.Compositions are useful for coloring high molecular weight material, like inks, plastics and in particular automotive coatings.

Provided is a pigment combination exhibiting excellent electrical properties including electrical insulating properties and environmental safety, and having a hue close to that of carbon black and giving a high coloring strength. The invention provides a pigment composition containing a plurality of organic pigments P1 and P2 as essential components and optionally further containing a third pigment P3, wherein the first pigment P1 is at least one phthalocyanine pigment, the second pigment P2 is at least one pigment selected from perylene pigments, azo pigments, perinone pigments, quinacridone pigments, and anthraquinone pigments, and each of the organic pigments P1, P2, and P3 is a pigment which contains no halogen in its molecular structure.

The present invention relates to polybenzazole fibers or filaments, staple fibers, spun yarns, and woven or knitted fabrics containing in themselves an organic pigment having heat resistance as high as a thermal decomposition temperature of 200° C. or higher, and soluble in a mineral acid and having group(s) of —N=and / or NH— in the molecule, such as any of perinones and / or perylenes, any of phthalocyanines, any of quinacridones, and any of dioxazines, wherein they have a strength retention of 50% or higher when exposed to light from a xenon lamp for 100 hours and having a tensile strength retention of 85% or higher after exposed to an atmosphere of a temperature of 80° C. and a relative humidity of 80% for 700 hours. The polybenzazole fibers or filaments, staple fibers, spun yarns, and woven or knitted fabrics can be used for cords for reinforcing rubber, sheets and rods for reinforcing cement / concrete, composite materials, sail clothes, ropes, knife proof vests and bullet proof vests.

In a developing roller having a shaft member, a conductive elastic layer provided on the shaft member, and a conductive resin layer constituting a most-surface layer, the conductive resin layer contains a condensed polycyclic organic pigment as exemplified by at least one selected from the group consisting of a quinacridone pigment, a threne pigment, a perylene pigment and a perinone pigment. The developing roller can effectively keep ghost form occurring and can achieve high image density in a low-temperature and low-humidity environment.

A resin composition for laser welding contains: relative to 100 mass parts of (A) a thermoplastic polyester resin material that contains a polybutylene terephthalate homopolymer and at least one of a polybutylene terephthalate copolymer, a polyethylene terephthalate resin, and a polycarbonate resin, 0.0005 to 0.5 mass parts of (B) nigrosine; and 0.01 to 2 mass parts of (C) a colorant containing at least an anthraquinone dye C1 having a maximum absorption wavelength in a range of 590 to 635 nm, a perinone dye C2 having a maximum absorption wavelength in a range of 460 to 480 nm, and an anthraquinone dye C3 having a maximum absorption wavelength in a range of 435 to 455 nm, at C1: C2:C3=24 to 41:24 to 39:22 to 46 as the mass ratio relative to 100 mass parts for a total of C1, C2, and C3.

A method for preparing a perylene pigment or perinone pigment involves a condensation reaction between perylene tetracarboxylic acid or naphthalene tetracarboxylic acid, or anhydrides or imides thereof, and amines in the presence of certain metal catalysts, such as ammonium molybdate, molybdenum oxide, and metal carbonyls, such as hexacarbonylmolybdenum, titanium carbonyl, iron carbonyls, and the like. The use of these catalysts provides various advantages, including the reduction of the amount of the catalyst, while achieves high yields, the lowering of reaction temperatures, and the reduction of insoluble sludge in the reaction mixture, thereby making the reaction operation easier and reducing the amounts of hazardous wastes containing heavy metals.

The present invention relates to polybenzazole fibers or filaments, staple fibers, spun yarns, and woven or knitted fabrics containing in themselves an organic pigment having heat resistance as high as a thermal decomposition temperature of 200 DEG C. or higher, and soluble in a mineral acid and having group(s) of -N=and / or NH- in the molecule, such as any of perinones and / or perylenes, any of phthalocyanines, any of quinacridones, and any of dioxazines, wherein they have a strength retention of 50% or higher when exposed to light from a xenon lamp for 100 hours and having a tensile strength retention of 85% or higher after exposed to an atmosphere of a temperature of 80 DEG C. and a relative humidity of 80% for 700 hours. The polybenzazole fibers or filaments, staple fibers, spun yarns, and woven or knitted fabrics can be used for cords for reinforcing rubber, sheets and rods for reinforcing cement / concrete, composite materials, sail clothes, ropes, knife proof vests and bullet proof vests.

An aqueous ink for use in an ink jet recording method in which ink is thermally ejected from a recording head to record an image on a recording medium. The aqueous ink includes zirconium oxide; a pigment; a resin dispersant for the pigment; and a first and a second urethane resin. The content (ppm) of the zirconium oxide in terms of zirconium is 0.5-20.0 ppm based on the total mass of the ink. The pigment is at least one of phthalocyanine, quinacridone, diketopyrrolopyrrole, dioxazine, perinone, perylene and anthraquinone pigments. Each of the first and second urethane resins has a unit derived from a polyether polyol. The ratio of the weight-average molecular weight Mw1 of the first urethane resin to the weight-average molecular weight Mw2 of the second urethane resin is 0.20-0.80 times. The second urethane resin has a weight-average molecular weight Mw2 of 20,000-70,000.

A chromatic dye such as a heterocyclic, perinone or thioindigo dye is contained in an ABS resin, and this dye-containing resin is mixed / kneaded and then pelletized. The pellets are extrusion-molded to form an uncemented first resin layer, to which an uncemented second resin layer having metallic luster and provided with a metallic film formed by depositing a metal is attached, heated and pressed, whereby the uncemented first and second resin layers are cemented together and the dye present in the uncemented first resin layer is caused to migrate into the second resin layer to color it to such a degree that a color difference Δ E of not less than 0.8 is produced. Thereby a laminate having chromatic metallic luster on the second resin layer side is obtained.

A polymerizable composition for an optical material of the present invention includes a compound (A) represented by General Formula (1) including two or more allyloxycarbonyl groups; an ultraviolet absorbing agent (B) represented by General Formula (i); at least one kind of radical polymerization initiator (C) selected from the group consisting of a peroxyketal-based radical polymerization initiator, a peroxymonocarbonate-based radical polymerization initiator, and a peroxyester-based radical polymerization initiator; at least one kind of dye (D) selected from an anthraquinone-based dye, a perinone-based dye, a monoazo-based dye, a diazo-based dye, and a phthalocyanine-based dye.

A photoconductive imaging member containing a photogenerator layer comprised of a mixture of bis(methylbenzimidazo)perinone, optionally an (alkylimido)perylene, such as (n-pentylimido)perylene or mixtures of (n-pentylimido)perylene, bisbenzimidazo(2,1-a-1',2'-b)anthra(2,1,9-def:6,5,10-d'e'f')diisoquinoline-6,11-dione and bisbenzimidazo(2,1-a:2',1'-a)anthra(2,1,9-def:6,5,10-d'e'f')diisoquinoline-10,21-dione, and a charge transport layer.

The present invention relates to a coloring resin composition exhibiting pleochroism comprising 100 parts by weight of a transparent thermoplastic resin (A); 0.01 to 0.03 parts by weight of a dye for coloring a resin (B) which is one selected from the group consisting of an azo-based dye (b1), an anthraquinone-based dye (b2), and a methine dye (b3); and 0.1 to 0.3 parts by weight of a functional black dye (C) obtained by mixing an anthraquinone-based dye (c1) and a perinone-based dye (c2). A resin molded article manufactured by the coloring resin composition exhibiting pleochroism of the present invention is characterized by exhibiting different colors of light according to thicknesses although the resin molded article is irradiated with light sources in a single wavelength.

The present invention relates to a biaxially oriented polyester film, whicha) has a base layer B, which includes a yellow dye and a red dye,b) has, on each side of the base layer B, at least one layer (A or C) which includes, based on the weight of layer A or C, less than 0.01% by weight of the yellow dye and less than 0.01% by weight of the red dye, andc) the film has one absorption maximum lying at from 400 to 500 nm in the UV / visible spectrum from 400 to 800 nm.Preferred dyes are anthraquinone dyes and perinone dyes; the polyester is preferably PET. After metallization or lamination, the film has a gold appearance, and is a suitable packaging material.

The present invention relates to a coloring resin composition exhibiting pleochroism comprising 100 parts by weight of a transparent thermoplastic resin (A); 0.01 to 0.03 parts by weight of a dye for coloring a resin (B) which is one selected from the group consisting of an azo-based dye (b1), an anthraquinone-based dye (b2), and a methine dye (b3); and 0.1 to 0.3 parts by weight of a functional black dye (C) obtained by mixing an anthraquinone-based dye (c1) and a perinone-based dye (c2). A resin molded article manufactured by the coloring resin composition exhibiting pleochroism of the present invention is characterized by exhibiting different colors of light according to thicknesses although the resin molded article is irradiated with light sources in a single wavelength.

A pigment composition including at least one pigment selected from the group consisting of a perinone-based pigment and a perylene-based pigment, water, a resin having a constitutional unit represented by Formula 1, and at least one compound selected from the group consisting of a phthalimide compound having a carboxyalkyl group and a naphthalimide compound having a carboxyalkyl group; a method for producing thereof; and an aqueous ink composition using the pigment composition. In Formula 1, R1 represents a hydrogen atom or a methyl group, L2 represents —C(═O)O—, —OC(═O)—, or —C(═O)NR2— and R2 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and R3 represents an alkyl group having 6 or more carbon atoms.

The invention relates to a method for production of an aqueous dispersion of polymer-encapsulated pigments, characterised in that (a) an aqueous pigment dispersion, containing at least one organic pigment (P), selected from the group of azo, isoindolinone, isoindoline, anthanthrone, thioindigo, thiazinindigo, triarylcarbonium, quinophthalone, anthraquinone, dioxazine, phthalocyanine, quinacridone, quinacridonquinone, indanthrone, perylene, perinone, pyranthrone, diketopyrrolopyrrole, isoviolanthrone and azomethine pigments, at least one detergent (T), and water is prepared, (b) a monomer miniemulsion, stabilised by a hydrophobic organic compound with a water solubility at 20 DEG C of at most 5x10-5 g / l, is prepared from a polymerisable monomer (M) and at least one detergent (T) in water, (c) a monomer pigment emulsion is prepared, whereby the aqueous dispersion from (a) and the monomer miniemulsion from (b) are mixed and homogenised and (d) the pigment-containing monomer from (c) is polymerised in the presence of a polymerisation initiator and / or by heat, whereupon an encapsulation of the pigment with the polymer thus formed occurs.

An electrophotographic photoreceptor includes a conductive substrate, an undercoat layer on the conductive substrate, and a photosensitive layer on the undercoat layer. The undercoat layer contains at least one perinone compound selected from the group consisting of a compound represented by general formula (1) below and a compound represented by general formula (2) below, an amine compound (A) having an ionization potential of 5.4 eV or more and 5.9 eV or less, and a binder resin,where: in general formula (1), R11, R12, R13, R14, R15, R16, R17, and R18 each independently represent a hydrogen atom, an alkyl group, an alkoxy group, an aralkyl group, an aryl group, an aryloxy group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkoxycarbonylalkyl group, an aryloxycarbonylalkyl group, or a halogen atom; R11 and R12 may be bonded to each other to form a ring, so may R12 and R13, and so may R13 and R14; and R15 and R16 may be bonded to each other to form a ring, so may R16 and R17, and so may R17 and R18, and in general formula (2), R21, R22, R23, R24, R25, R26, R27, and R28 each independently represent a hydrogen atom, an alkyl group, an alkoxy group, an aralkyl group, an aryl group, an aryloxy group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkoxycarbonylalkyl group, an aryloxycarbonylalkyl group, or a halogen atom; R21 and R22 may be bonded to each other to form a ring, so may R22 and R23, and so may R23 and R24; and R25 and R26 may be bonded to each other to form a ring, so may R26 and R27, and so may R27 and R28.

A chromatic dye such as a heterocyclic, perinone or thioindigo dye is contained in an ABS resin, and this dye-containing resin is mixed / kneaded and then pelletized. The pellets are extrusion-molded to form an uncemented first resin layer, to which an uncemented second resin layer having metallic luster and provided with a metallic film formed by depositing a metal is attached, heated and pressed, whereby the uncemented first and second resin layers are cemented together and the dye present in the uncemented first resin layer is caused to migrate into metallic film or metallic film and the second resin layer to color it to such a degree that a color difference ΔE of not less than 0.8 is produced. Thereby a laminate having chromatic metallic luster on the second resin layer side is obtained.

A method for preparing a perylene pigment or perinone pigment involves a condensation reaction between perylene tetracarboxylic acid or naphthalene tetracarboxylic acid, or anhydrides or imides thereof, and amines in the presence of certain metal catalysts, such as ammonium molybdate, molybdenum oxide, and metal carbonyls, such as hexacarbonylmolybdenum, titanium carbonyl, iron carbonyls, and the like. The use of these catalysts provides various advantages, including the reduction of the amount of the catalyst, while achieves high yields, the lowering of reaction temperatures, and the reduction of insoluble sludge in the reaction mixture, thereby making the reaction operation easier and reducing the amounts of hazardous wastes containing heavy metals.

The instant invention is related with new perimidine derivatives synthesized via direct condensation between naphthalene-1,8-diamine and itaconic or citraconic anhydrides at low temperature. The targeting itaco-perinone (IP) molecule formed via double low temperature cyclization has fluorescence properties emitting white light intensively. Besides, 9-methylene-8H-pyrrolo[1,2-a]perimidin-10(9H)-one is copolymerizable with several kind of organic monomer compounds via free radical mechanism maintaining the ability to emit white light even within the polymer film.

A resin composition for laser welding contains:relative to 100 mass parts of (A) a thermoplastic polyester resin material that contains a polybutylene terephthalate homopolymer and at least one of a polybutylene terephthalate copolymer, a polyethylene terephthalate resin, and a polycarbonate resin, 0.0005 to 0.5 mass parts of (B) nigrosine; and 0.01 to 2 mass parts of (C) a colorant containing at least an anthraquinone dye C1 having a maximum absorption wavelength in a range of 590 to 635 nm, a perinone dye C2 having a maximum absorption wavelength in a range of 460 to 480 nm, and an anthraquinone dye C3 having a maximum absorption wavelength in a range of 435 to 455 nm, at C1:C2:C3=24 to 41:24 to 39:22 to 46 as the mass ratio relative to 100 mass parts for a total of C1, C2, and C3.

The invention relates to a method for directly producing fine-particle 1,4-diketopyrrolo[3,4-c]pyrrols of formula (1), wherein R1a, R1b, R2a and R2b independently represent hydrogen, halogen, C1-C4 alkyl, C1-C4 alkoxy, cyano or phenyl, said compounds being characterized by a maximum frequency distribution between 20 and 120 nm. According to the method, nitriles are reacted with succinic acid esters or lactames or enamines in an alkali medium to form a pigment salt, and then protolysis of the pigment alkali salt is carried out. Said method is characterized in that an effective quantity of a pigment dispersant of formula (II) is added during the protolysis of the pigment alkali salt. In formula (II), Q is a radical of an organic pigment from the group of perinone, quinacridone, quinacridonquinone, anthanthrone, indanthrone, dioxazine, diketopyrrolopyrrol, indigo, thioindigo, thiazineindigo, isoindoline, isoindolinone, pyranthrone, isoviolanthrone, flavanthrone or anthrapyrimidine pigments.

An electrophotographic photoreceptor includes a conductive substrate, an undercoating layer that is disposed on the conductive substrate, and a photosensitive layer that is disposed on the undercoating layer, in which the undercoating layer contains at least one perinone compound selected from the group consisting of a compound represented by Formula (1) and a compound represented by Formula (2) which are shown below, and polyurethane, contains at least one perinone compound selected from the group consisting of the compounds represented by Formulas (1) and (2), and at least one acceptor compound selected from the group consisting of compounds represented by Formula (3) to (15) which are shown in the specification, or contains a resin obtained by polymerizing a diallyl phthalate compound and a charge transporting material.

The invention relates to a method for directly producing fine-particle 1,4-diketopyrrolo[3,4-c]pyrrols of formula (I), wherein R1a, R1b, R2a and R2b independently represent hydrogen, halogen, C1-C4 alkyl, C1-C4 alkoxy, cyano or phenyl, the compounds being characterized by a maximum frequency distribution between 20 and 120nm. According to the method, nitriles are reacted with succinic acid esters or lactames or enamines in an alkali medium to form a pigment alkali salt, and then protolysis of the pigment alkali salt is carried out. The method is characterized in that an effective quantity of a pigment dispersant of formula (II) is added during the protolysis of the pigment alkali salt. In formula (II), Q is a radical of an organic pigment from the group of perinone, quinacridone, quinacridonquinone, anthanthrone, indanthrone, dioxazine, diketopyrrolopyrrol, indigo, thioindigo, thiazineindigo, isoindoline, isoindolinone, pyranthrone, isoviolanthrone, flavanthrone or anthrapyrimidine pigments.

A novel crystal form of C.I. Solvent Orange 60 gives a higher space-time yield in dye synthesis and is more easily finished.