This invention discloses a method and its application for controlling the bending degree of a two-dimensional
cobalt four-coordinate conjugated compound on a three-dimensional tubular carbon material. The specific procedure involves ultrasonically dispersing a three-dimensional
honeycomb-structured tubular carbon material in
methanol, and dispersing the two-dimensional
cobalt four-coordinate conjugated compound in
methanol. The dispersion of the two-dimensional
cobalt four-coordinate conjugated compound is slowly added dropwise to the dispersion of the three-dimensional
honeycomb-structured tubular carbon material, while magnetic stirring. The solution is filtered and washed with
methanol. Finally, the resulting
solid is dried in a
vacuum drying oven to obtain a
composite structure of the two-dimensional cobalt four-coordinate conjugated compound and the three-dimensional
honeycomb-structured tubular carbon material. This invention modifies the
bending strain of the two-dimensional cobalt four-coordinate conjugated compound on the three-dimensional honeycomb-structured tubular carbon material by controlling the
diameter of the tubular material. The preparation method is simple, efficient,
environmentally friendly, and low-cost.