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194 results about "Cesium ions" patented technology

Method for extracting rubidium salt and cesium salt

The invention relates to a method for extracting rubidium salt and cesium salt. The method comprises the steps of 1) regulating a high-salinity solution to obtain an alkaline solution which has a pH value of 11-14; 2) extracting rubidium ions and cesium ions from the alkaline solution obtained from the step 1) in a centrifugal extractor through an organic extracting agent, thus obtaining a loaded organic phase (I) and raffinate; 3) washing the organic phase (I) obtained from the step 2) through washing water to obtain an organic phase (II) and a washing solution; 4) implementing reverse extraction to the loaded organic phase (II) through reverse extraction acid (I) to obtain a rubidium salt reverse extraction solution and an organic phase loaded with cesium ion; and 5) implementing reverse extraction to the organic phase loaded with the cesium salt obtained from the step 4) through reverse extraction acid (II) to obtain a cesium salt reverse extraction solution and a blank organic phase. The extraction method disclosed by the invention is simple and easy to implement, and can be matched with comprehensive development and utilization of a high-salinity medium to produce a rubidium salt and cesium salt product of preset type.
Owner:QINGHAI INST OF SALT LAKES OF CHINESE ACAD OF SCI

Method for preparing composite adsorption material used for absorbing rubidium and cesium ions

The invention belongs to the technical field of a functional material, and discloses a method for preparing a composite adsorption material used for absorbing rubidium and cesium ions. The method is characterized in that a polymer layer containing an o-dihydroxybenzene structure is prepared through in-situ polymerization on the surface of a porous material, then am ion exchange function nano adsorbent layer is subjected to in-situ growth on the surface of the polymer layer, and the composite adsorption material can be obtained. The polymer layer on the surface of the porous material has strong rubidium caesium complexation and adsorption functions, has strong adhesion effect on a porous material and the ion exchange function adsorbent, greatly increase the stability of the composite adsorption material, is in favor of in-situ growth of the adsorbent, and can adjust and control the granularity of the adsorbent layer; during adsorption, a solution and the adsorbent are fully contacted, and are connected with the polymer layer through particle gaps of the adsorbent, synergism is used for absorbing rubdium and cesium, the adsorption capacity is high, and the composite adsorption material can be used for absorbing rubidium and caesium in salt lake brine and absorbing caesium in radioactivity waste water.
Owner:BEIJING NORMAL UNIVERSITY

Method for the preparation of a cesium-separating sorbent

The invention provides a method for the preparation of a sorbent capable of efficiently and selectively sorbing cesium ions from an aqueous solution. The method comprises impregnating the pores of a high-porosity carrier material such as silica gel and porous adsorbent resin with water-soluble potassium or sodium hexacyanoferrate (II) and contacting the carrier material with a solution of a copper salt in a solvent in which the water-soluble hexacyanoferrate (II) is hardly soluble such as ethyl alcohol to convert the water-soluble hexacyanoferrate (II) into water-insoluble copper hexacyanoferrate (II). The cesium ions sorbed on the sorbent can be readily desorbed and the sorbent can readily be regenerated. Alternatively, the carrier material is impregnated with a water-soluble hexacyanoferrate (III) which is converted into copper hexacyanoferrate (III) followed by a reducing reaction of the same into copper hexacyanoferrate (II).
Owner:NAT INST OF ADVANCED IND SCI & TECH

Method for detecting metal ions in solution by perovskite nanocrystal based metal ion sensor

The invention discloses a method for detecting metal ions in a solution by a perovskite nanocrystal based metal ion sensor. The metal ion sensor contains a perovskite nanocrystal with structure as shown in the general formula ABX3, wherein A is cesium ion Cs <+>, B is lead ion Pb<2+>, X is one or more of halogen ions Cl<->, Br<-> and I<->, and detectable metal ions comprise but are not limited to metal ions such as Cu<2+>, Yb<3+> and the like. A solution containing to-be-measured ions is added to a perovskite nanocrystal solution, the concentration of the to-be-measured ions is calculated by measuring change of fluorescence intensity of the perovskite nanocrystal under the excitation of light. The sensor has the advantages of high sensitivity, high selectivity, low detection limit, high response speed, low price, wide detection range, mild test conditions (detection at room temperature), good reproducibility and the like, is easy to operate, and has broad application prospect in field of metal ion detection for environment, industry and food.
Owner:NANJING NORMAL UNIVERSITY

Green and environment-friendly synthesis method of CsPbX3 perovskite quantum dot

The invention discloses a simple, green, and environment-friendly synthesis method of a CsPbX3 perovskite quantum dot, wherein the X can be Cl, Br, or I. The synthesis method is characterized in that cesium ions, lead ions, and bromine ions are dissolved in a solvent, a proper amount of carboxylic acids and amines is added and taken as the stabilizing agent; a low pressure distillation method is adopted to separate the solvent from the cesium ions, lead ions, and bromine ions; cesium ions, lead ions, and bromine ions are precipitated out due to the evaporation of the solvent, and CsPbX3 perovskite quantum dots are formed. The synthesis method has the advantages that the solvent can be repeatedly used through a low pressure distillation technology, the cost is saved, the method is green and environment-friendly, the reaction temperature is low, the operation is simple, and the synthesis method is suitable for large scale massive production.
Owner:宁波智正伟盈信息科技有限公司

Method for extracting lithium by processing lepidolite through alkali dissolution process

The invention discloses a method for extracting lithium by processing lepidolite through an alkali dissolution process, which comprises the following steps of: enabling the lepidolite to react with alkali in a liquid environment so as to enable the lithium, sodium, potassium, rubidium and cesium in the lepidolite to enter a solution, diluting lepidolite powder after alkali dissolution, and further performing ion exchange to acquire cations in a system. By adopting the method, 100% of the lithium in the lepidolite can enter the solution, reaction filter slag of the lepidolite returns to the alkali dissolution process step, and the complete alkali dissolution is realized. As sodium ions, potassium ions, lithium ions, cesium ions and rubidium ions in the lepidolite are obtained through ion exchange, and the interference of silicon, aluminum, fluorine and other elements in the system is removed, the lithium ions, the cesium ions and the rubidium ions in the lepidolite are easier to be extracted. According to the method, as the reaction is performed in the alkaline liquid environment, the fluorine in the lepidolite can not generate highly-corrosive hydrofluoric acid capable of corroding equipment. A byproduct generated by the method is aluminum silicon sol with a wide range of applications, and the direct selling of the aluminum silicon sol can greatly lower the cost of lithium extraction reaction.
Owner:INST OF APPLIED CHEM JIANGXI ACAD OF SCI

Method for extracting rubdium and cesium from acid brine

The invention discloses a method for extracting rubdium and cesium from acid brine. The method includes the steps that brine is pumped into an ammonium type chelate resin adsorption column, calcium ions and magnesium ions are adsorbed through the ammonium type chelate resin adsorption column, and effluent is brine without the calcium ions and the magnesium ions; the effluent is mixed with t-BAMBP or kerosene or sulfonated kerosene to be shaken, and a mixture stands still for layering and separation of a water phase and an organic phase; and reextraction is conducted on the organic phase, and the water phase containing rubidium chloride and cesium chloride is obtained. The method is simple in process, low in production cost, capable of achieving separate extraction for removing rubdium and cesium ions in radioactive water and free of secondary pollution.
Owner:QINGHAI INST OF SALT LAKES OF CHINESE ACAD OF SCI

Novel class of calixarene crown ether bond-type silicon-based adsorption materials and preparation method thereof

The present invention discloses a novel class of calixarene crown ether bond-type silicon-based adsorption materials and a preparation method thereof, belonging to the technical field of metal ion adsorption material preparation. The adsorbent materials have the structure shown in the formula below: wherein, R is H or; and X = 2-12. During the preparation of the adsorbent materials, firstly modifying di(2-propoxy)calix [4] arene-crown-6 to bring reactive amino group to the molecular structure; then a preparing silicon-based precursor containing haloalkyl; and finally reacting amino-substituted di(2-propoxy)calix [4] arene-crown-6 with the silicon-based precursor containing haloalkyl, so that the calixarene crown ether groups are bonded on the silicon carrier to get a novel class of calixarene crown ether bond-type silicon-based adsorption materials. The method provided by the invention is simple in operation; and the obtained adsorption materials have excellent thermal stability and chemical stability, high reusability, and large adsorption capacity for cesium ions.
Owner:TSINGHUA UNIV

Method for extracting and separating uranyl ions from aqueous phase

InactiveCN101638722AEfficient extraction performanceEasy extractionProcess efficiency improvementDiluentUranyl
The invention discloses a method for extracting and separating uranyl ions from an aqueous phase. In the method, hydrophobic ion liquid serves as a diluting agent and octyl phenyl group-N, N-diisobutylamine formacyl methylphosphineoxide serves as an extracting agent so as to extract uranyl ions from an aqueous solution containing the uranyl ions. The method can be used for efficiently extracting the cesium ions from the aqueous phase, and the extracting distribution ratio can reach more than 10<3> at most. The method has a wide applicable range to different aqueous phase acidity conditions, and can be used for extracting the cesium ions from neutral conditions to 3MHNO3; ion liquid serves as a diluting agent, and phenomena which are disadvantageous to technology such as emulsification in the process of extracting the cesium ions do not exist. Ion liquid almost has no volatility, thus the system is environmental-friendly. To sum up, the method of the invention has favorable applicationprospect in the field of nuclear fuel recycling.
Owner:PEKING UNIV

Preparation method of adsorbent for selectively separating cesium ions from salt lake brine

The invention discloses a preparation method of an adsorbent for selectively separating cesium ions from salt lake brine, belonging to the field of non-ferrous metallurgy. The method for preparing the adsorbent comprises the following steps: by taking the cesium ions as a template agent, mixing a surfactant, a soluble cesium salt, sodium silicate and sodium aluminate, regulating the pH value of the system by using an alkaline solution, thereby obtaining cesium-containing silica-alumina gel; crystallizing to obtain a precursor under hydrothermal conditions, washing and calcining the precursor, thereby obtaining cesium-containing artificial zeolite; eluting the artificial zeolite, desorbing Cs<+> from the cesium-containing artificial zeolite, filtering, and separating, thereby obtaining an artificial zeolite ion sieve with a cesium ion customized pore structure, wherein the selective adsorption performance on Cs<+> in the salt lake brine is excellent. The method disclosed by the invention is simple in process and does not have any special requirement on equipment, and the prepared adsorbent is stable in properties and long in service life, has high selectivity and good enrichment effect on the cesium ions in the salt lake brine and has good industrialization application prospects.
Owner:CENT SOUTH UNIV

Technology for extracting lithium by processing lithium ores through high-pressure steaming process

The invention discloses a technology for extracting lithium by processing lithium ores through a high-pressure steaming process. The technology comprises the following steps: mixing lithium ore powder with a powdery solid strong alkali for 20-40min to uniformity, directly letting in high-pressure steam, and carrying out dissolving and reacting of the powdery solid strong alkali and the lithium ores through utilizing water in the high-pressure water at a high temperature under a high pressure to completely generate soluble substances. In the invention, the strong alkali in the above reaction materials dissolves through absorbing water molecules in the water steam, so the application amount of the strong alkali can be substantially reduced, and the cost is saved. Lithium, sodium, potassium, rubidium and cesium ions in the lithium ores can be completely dissolved in a solution, so the lithium extraction is convenient, and the lithium yield is high. Fluorine in the lithium ores does not form strong-corrosion hydrofluoric acid corroding apparatuses. Reaction byproducts comprising an alumina sol and a silica sol can be directly sold, so the lithium extraction reaction cost is correspondingly reduced.
Owner:INST OF APPLIED CHEM JIANGXI ACAD OF SCI

Method for extracting and separating cesium ions from aqueous phase

InactiveCN101638721AEfficient extraction performanceEasy extractionProcess efficiency improvementLiquid wasteHigh activity
The invention discloses a method for extracting and separating cesium ions from an aqueous phase. In the method, hydrophobic ion liquid serves as a diluting agent and 25, 27-2(2-propoxy) calixarene [4]-26, 28-crown-6 serves as an extracting agent so as to extract cesium ions from an aqueous solution containing cesium ions. The method can be used for efficiently extracting the cesium ions from theaqueous phase, and the extracting distribution ratio can reach more than 10<3> at most. Ion liquid almost has no volatility, thus the system is environmental-friendly. The extracting system of the invention has a wide applicable range to different aqueous phase conditions and has favorable application prospect in the related field of extracting the cesium ions from high activity liquid waste.
Owner:PEKING UNIV

Decontamination method and apparatus for solid-state material contaminated by radiocesium

A decontamination method of solid-state material contaminated by radiocesium comprising bringing the solid-state material containing radiocesium in contact with a first processing solution and preferably eluting cesium ion from the solid-state material to the liquid phase under the presence of potassium ion or ammonium ion.
Owner:EBARA INDS SENJIYOU +1

Sulfonated polyarylether based on triphenylphosphine oxide structure unit and preparation method thereof

The invention discloses sulfonated polyarylether based on a triphenylphosphine oxide structure unit and a preparation method thereof in the technical field of chemical industry. Sulfonated triphenylphosphine monomer, triphenylphosphine monomer and dihydroxyl monomer are used as raw materials to be polycondensed directly in polar solvent by the action of reaction accelerant to obtain a polymer with a structural formula as above, wherein, M is hydrogen ion, lithium ion, sodium ion, kalium ion, cesium ion or ammonium ion; when m is equal to 1, the polymer is a homopolymer containing sulfonated triphenylphosphine oxide; when m is more than 0 and less than 1, the polymer is the multipolymer containing the sulfonated triphenylphosphine oxide. The polymer has good thermal stability, mechanical property and solubility, large molecular weight and good compatibility with inorganic material and can be applied in proton exchange membrane fuel cell field.
Owner:SHANGHAI JIAO TONG UNIV

Method for extracting rubidium and cesium from lepidolite ores

The invention belongs to the technical field of metallurgy and discloses a method for extracting rubidium and cesium from lepidolite ores. The method comprises the steps: converting alpha-type lepidolite into beta-type lepidolite by using a microwave oven, smashing the beta-type lepidolite, mixing concentrated sulfuric acid to carry out microwave sulfatizing roasting, and soaking the beta-type lepidolite to obtain a mother solution of an alkali metal solution containing lithium, potassium, rubidium and cesium; then, circularly adsorbing cesium ions by using a cesium cation exchange resin column, and carrying out elution to obtain a cesium salt; and next, circularly adsorbing rubidium ions by using a rubidium cation exchange resin column, and carrying out elution to obtain a rubidium salt. If the lepidolite ores are treated by using the method disclosed by the invention, the energy consumption is low, no sulfur trioxide is produced, in addition, the extraction ratios of rubidium and cesium are high, and the subsequent lithium extraction process can be favorably simplified.
Owner:江西南氏锂电新材料有限公司

Perovskite solar cell and preparation method thereof

The invention, which belongs to the technical field of the solar cell, provides a perovskite solar cell and a preparation method thereof. In order to overcome a defect of poor humidity stability of the perovskite solar cell due to poor humidity stability of the existing perovskite type formamidinium lead iodide, the invention provides a method using cesium ion doping to improve the moisture-resistant capability of the formamidinium lead iodide and enhance humidity stability of the solar cell. The prepared perovskite solar cell uses a piece of FTO conductive glass (1) as a substrate; a compact titanium dioxide layer (2), a porous titanium dioxide layer (3), a perovskite layer (4), a hole transport layer (5) and an electrode (6) are formed on the substrate successively. And the perovskite layer is made of caesium-doped formamidinium lead iodide. According to the invention, the prepared perovskite solar cell has high humidity stability and is suitable for practical application. In addition, compared with the solar cell without cesium ion doping, the prepared solar cell has high efficiency and high repeatability and is suitable for popularization and practical production.
Owner:JILIN UNIV

Catalyst for preparing ethylbenzene and styrene through toluene and methanol side chain alkylation and use thereof

The invention relates a catalyst for preparing ethylbenzene and styrene through toluene and methanol side chain alkylation. The catalyst solves the problem that the existing catalyst for toluene and methanol side chain alkylation has a low methanol use rate and low ethylbenzene and styrene selectivity. Under toluene and methanol side chain alkylation conditions, raw materials contacts with the catalyst and undergoes a reaction to produce ethylbenzene and styrene. The catalyst is an X molecular sieve having a molar ratio of SiO2 / Al2O3 of 2 to 3. Before use, an X molecular sieve is subjected to ion exchange with at least two of potassium ions, rubidium ions and cesium ions, and then the molecular sieve catalyst is loaded with one or more of iron, cobalt, chromium, zirconium and bismuth by an impregnation method. The catalyst well solves the existing problem and can be used for the industrial production of ethylbenzene and styrene through toluene and methanol side chain alkylation.
Owner:CHINA PETROLEUM & CHEM CORP +1

Method for preparing supported ferrocyanide bacterial cellulose membrane for adsorbing Cs+

The invention discloses a method for preparing a supported ferrocyanide bacterial cellulose membrane for adsorbing Cs+. The method is characterized by comprising the following steps: 1) pretreating abacterial cellulose membrane, and cutting the bacterial cellulose membrane into different sizes; 2) adsorbing transition metallic ions by using the bacterial cellulose membrane, soaking the bacterialcellulose membrane obtained in the step 1) into a transition metallic ion solution, and washing the surface of the bacterial cellulose membrane with distilled water; 3) supporting ferrocyanide on thebacterial cellulose membrane, soaking the bacterial cellulose membrane obtained in the step 2) into a potassium ferrocyanide solution, performing oscillation by using a table concentrator, and washingthe surface of the bacterial cellulose membrane with distilled water. The material prepared by using the method can be cut into different sizes according to demands, a ferrocyanide crystal is deeplyembedded into a fiber structure, and after treatment, the ferrocyanide is not liable to lose in the wastewater treatment process; the material has a relatively good adsorption property for radionuclide cesium ion, and meanwhile the problem that a bed layer has too large water resistance when the ferrocyanide is used independently is avoided.
Owner:TSINGHUA UNIV

Catalyst for synthesizing ethylenimine as well as preparation method and application thereof

The invention relates to a catalyst for synthesizing ethylenimine as well as a preparation method and application thereof. The related catalyst comprises a carrier and metal ions loaded on the carrier; the carrier is a composite oxide comprising titanium, silicon and phosphorus elements; the metal ions are magnesium ions, iron ions and cesium ions; the molar ratio of the magnesium ions to the iron ions to the cesium ions is (1-10):1:0.1; the mass of all metal ions is 0.5-10 percent of that of the carrier. The related preparation method comprises the step of roasting a catalyst precursor at the temperature of 350-650 DEG C, so that the catalyst is obtained; the catalyst precursor is the mixture of the carrier, soluble salt of magnesium, soluble salt of iron and soluble salt of cesium. The invention also provides the application of the catalyst to synthesis the ethylenimine by using amino alcohol as the raw material. Compared with a common catalyst which has the requirement on the temperature of over 400 DEG C, the catalyst disclosed by the invention obviously reduces the reaction temperature. The prepared catalyst can catalyze the intramolecular dehydration reaction of the amino alcohol and has relatively excellent selectivity.
Owner:XIAN MODERN CHEM RES INST

Side chain alkylation method of toluene with methanol

The invention mainly relates to a side chain alkylation method of toluene with methanol, and mainly solves the problems of low toluene conversion rate and low ethylbenzene and styrene selectivity when a catalyst used in the prior art is used for side chain alkylation reaction of toluene with methanol. The method adopts the following technical scheme: by taking toluene and methanol as raw materials, the raw materials are enabled to be in contact with an X molecular sieve catalyst under the conditions that the reaction temperature is 200-600 DEG C, the reaction pressure is 0-0.5 MPa and the weight space velocity of the raw materials is 0.5-10 h<-1>, and reaction is performed to generate ethylbenzene and styrene, wherein mol ratio of the toluene to the methanol in the raw materials is (0.1-10):1; the silicon-aluminum mol ratio SiO2 / Al2O3 of the X molecular sieve is 2-3, and the K<+> / (K<+>+Na<+>) is more than 0-90%; and the X molecular sieve catalyst is subjected to ion exchange respectively through at least one of a potassium-ion-containing solution, a rubidium-ion-containing solution or a cesium-ion-containing solution before being used. Thus, the problems are well solved. The method can be used for industrial production of ethylbenzene and styrene preparation through side chain alkylation reaction of toluene with methanol.
Owner:CHINA PETROLEUM & CHEM CORP +1

Cesium ion adsorbing agent and preparing method thereof

The invention discloses a preparing method of a cesium ion adsorbing agent. The preparing method comprises the steps that firstly, carboxyl ferroferric oxide is prepared; secondly, carboxyl ferroferric oxide and a condensing agent are mixed, and a first mixture is obtained; thirdly, the first mixture is put into a solvent and stirred, an amination crown ether derivative is then added into the solvent, a reaction is carried out at the temperature ranging from 60 DEG C to 80 DEG C for at least 2 hours, and a second mixture is obtained, wherein the solvent is used for dissolving the amination crown ether derivative and the condensing agent; fourthly, the second mixture is subjected to solid and liquid separation, a first solid phase is obtained, cleaned and dried, and the cesium ion adsorbing agent is obtained. The invention further discloses the cesium ion adsorbing agent prepared through the method. The cesium ion adsorbing agent has high cesium ion adsorption selectivity and magnetism, and stable adsorption performance is maintained in the recycle use of adsorption and desorption. The cesium ion adsorbing agent can be applied to adsorption separation of cesium ions form radioactive nuclear waste, a polyion competing system and the like.
Owner:QINGHAI INST OF SALT LAKES OF CHINESE ACAD OF SCI

Prussian blue/graded porous carbon composite adsorbent and preparation method and application thereof

The invention relates to a Prussian blue / graded porous carbon composite adsorbent as well as a preparation method and application thereof. The Prussian blue / graded porous carbon composite adsorbent takes biomass-based graded porous carbon as a carrier, and Fe<3+> can be anchored by heteroatoms on the surface of the graded porous carbon, meanwhile Fe<3+> release in ferric chloride is inhibited by oxalic acid, nucleation and growth speed of Prussian blue is further controlled, and finally, Prussian blue microcrystals are grown in situ on the surface of the graded porous carbon to prepare the nano-grade, highly-dispersed Prussian blue / graded porous carbon composite adsorbent. The method provided by the invention has the advantages of simple preparation process, and green and environment-friendly raw materials, and the synthesized adsorbent has a micropore-mesopore-macropore hierarchical pore structure, high specific surface area, uniform dispersion of Prussian blue particles, and capability of efficiently and rapidly adsorbing cesium ions in water.
Owner:BEIJING UNIV OF CHEM TECH

Cesium ion adsorbent and preparation method therefor

The present invention discloses a preparation method for a cesium ion adsorbent. The preparation method comprises the steps of: A, preparing aminated ferroferric oxide; B, mixing a carboxylated crownether derivative and a condensation agent to obtain a first mixture; C, placing the first mixture in a solvent to be stirred, adding the aminated ferroferric oxide into the solvent and performing a reaction at 40-80 DEG C for at least 1 h to obtain a second mixture, wherein the solvent is used for dissolving the carboxylated crownether derivative and the condensation agent; and D, performing solid-liquid separation on the second mixture to obtain a first solid phase, and washing and drying the first solid phase to obtain a cesium ion adsorbent. The present invention also discloses a cesium ion adsorbent obtained by the preparation method. The adsorbent has good cesium ion adsorption selectivity and magnetic properties, and retains stable adsorption performance after using in repeated adsorption-desorption cycles. The cesium ion adsorbent disclosed by the present invention can be applied to adsorbing and separating the cesium ion from systems such as radioactive waste and ionic competition systems.
Owner:QINGHAI INST OF SALT LAKES OF CHINESE ACAD OF SCI

Cesium ion adsorbent and preparation method thereof

The invention discloses a preparation method of cesium ion adsorbent. The method includes the steps that A, hydroxylation ferroferric oxide is prepared; B, hydroxylation ferroferric oxide is mixed with crown ether derivatives to obtain a first mixture; C, the first mixture is placed in solvent, stirred at the temperature of 50-80 DEG C and subjected to reflux for 1-2 h to obtain a second mixture, wherein the solvent is used for dissolving the crown ether derivatives; D, the second mixture is separated to obtain a first solid phase, the first solid phase is washed and dried, and the cesium ion adsorbent is obtained. The invention further discloses the cesium ion adsorbent prepared through the method, and the cesium ion adsorbent has high adsorption capacity and strong cesium ion adsorption selectivity; meanwhile, the cesium ion adsorbent has magnetism, and rapid solid-liquid separation can be achieved after cesium ions in a solution containing cesium ions are completely adsorbed. The cesium ion adsorbent can be used for adsorbing and separating out cesium ions from, for example, radioactive nuclear waste and multi-ion competition systems.
Owner:QINGHAI INST OF SALT LAKES OF CHINESE ACAD OF SCI

Preparation method of porous AMP/CNC-PUF adsorption material and application thereof

The invention relates to a preparation method of a porous AMP / CNC-PUF adsorption material and an application thereof and belongs to the fields of nano composite materials and environmental pollution repair. In order to overcome the technical defects that in the prior art, ammonium phosphomolybdate is poor in mechanical strength, hard to form and recover and complex in treatment process if being used for adsorption of radioactive elements, for example, rubidium and caesium, the invention provides the preparation method of the porous AMP / CNC-PUF adsorption material and the application thereof. The adsorption material is prepared by the steps: loading ammonium phosphomolybdate on nano carbon microparticles; and then capsulating the nano carbon microparticles in foamed polyurethane sponge. The treatment process after adsorption is simplified, the adsorption activity part can be fully exposed, and the adsorption efficiency is improved. The prepared composite material for repairing caesium ion polluted environments such as a water body and soil has a wide application prospect in the field of repairing a nuclear polluted environment.
Owner:BINZHOU UNIV

Preparation method of cesium carbonate

The invention relates to a preparation method of cesium carbonate. The cesium carbonate is prepared from raw materials of cesium powder, 98% of sulfuric acid and water, wherein a weight ratio of cesium powder to 98% of sulfuric acid to water is 1:0.7 to 0.8:1.8 to 2.2. The preparation method comprises the steps that: cesium powder is pretreated, such that a leached stock solution is obtained; the pH value of the stock solution is regulated; the stock solution is extracted, layered, back-extracted, dried by centrifugation, dried by baking, and packaged. After the processes, a finished product is obtained. The cesium carbonate preparation method provided by the invention is advantaged in that: (1) a high energy consumption of traditional alkali production methods is reduced, a requirement to equipment is reduced, and cesium carbonate production cost is greatly reduced; (2) generation of toxic substances during a production process with an acid method is avoided, production period is shortened, and productivity is improved; (3) a cesium ion leaching rate of the product provided by the present invention in a metal ion solution reaches 98.5%, while a cesium ion leaching rate of products provided with traditional technologies in a metal ion solution is 80%; (4) product quality is improved, and application scope of the product is enlarged.
Owner:上海实验试剂有限公司 +1

Microchannel plate and preparation method thereof

The invention relates to a microchannel plate and a preparation method thereof. The preparation method comprises the steps of 1) performing bar-tube combination, wiredrawing, plate layout, melting, pressing, mechanical processing and acid cleaning on a core glass bar and a skin glass tube to obtain a microchannel plate blank; 2) performing ion exchange, cleaning, high-temperature reduction and film coating on the microchannel plate blank in molten salt to obtain a microchannel plate, wherein the molten salt comprises rubidium salt and / or cesium salt. According to the invention, ion exchange isperformed on the microchannel plate blank, so that rubidium ions and cesium ions with high atomic weight and large atomic radius replace potassium ions and sodium ions in a reflecting layer, the electron flushing resistant performance of the reflecting layer is improved by the aid of increase in atomic weight of alkali metal ions and a volume congestion effect, so that the service life and the gain performance of the microchannel plate are improved, and the service life and the gain of the microchannel plate are improved by more than 30% and 20% respectively.
Owner:CHINA BUILDING MATERIALS ACAD
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