The invention discloses a preparing method of a cesium
ion adsorbing agent. The preparing method comprises the steps that firstly, carboxyl ferroferric
oxide is prepared; secondly, carboxyl ferroferric
oxide and a condensing agent are mixed, and a first mixture is obtained; thirdly, the first mixture is put into a
solvent and stirred, an
amination crown ether derivative is then added into the
solvent, a reaction is carried out at the temperature
ranging from 60 DEG C to 80 DEG C for at least 2 hours, and a second mixture is obtained, wherein the
solvent is used for dissolving the
amination crown ether derivative and the condensing agent; fourthly, the second mixture is subjected to
solid and liquid separation, a first
solid phase is obtained, cleaned and dried, and the cesium
ion adsorbing agent is obtained. The invention further discloses the cesium
ion adsorbing agent prepared through the method. The cesium ion adsorbing agent has high cesium
ion adsorption selectivity and
magnetism, and stable adsorption performance is maintained in the recycle use of adsorption and
desorption. The cesium ion adsorbing agent can be applied to
adsorption separation of
cesium ions form radioactive nuclear waste, a polyion competing
system and the like.