The invention discloses a high-efficiency organic-inorganic ternary
perovskite solar cell and a preparation method thereof, and the
solar cell sequentially comprises an ITO conductive glass substrate layer, a
hole transport layer (MeO-2PACz), a ternary
perovskite layer formed by mixing an
ionic liquid TFPBF4 and a
perovskite layer Cs0.05 (FA0.95 MA0.05) 0.95 Pb (I0.95 Br0.05) 3, a [6, 6]-phenyl-C61-
butyric acid isomethyl ester
electron transport layer (PCBM), a 2, 4, 6, 7, 8-tetramethyl-3, 7, 8-tetramethyl-3, 7, 8-tetramethyl-3, 7, 8-tetramethyl-3, 7, 8-tetramethyl-3, 7, 8-tetramethyl-3, 7, 8-tetramethyl-3, 7, 8-tetramethyl-3, 7, 8-tetramethyl-3, 8-tetramethyl-3 The
thin film solar cell is characterized by comprising a
metal electrode layer, a
metal electrode layer, a hole
blocking layer, a 9, 9-dimethyl-4, 7-
biphenyl-1, 10-
phenanthroline hole
blocking layer (BCP) and a
metal Ag electrode layer. According to the scheme, the
fluorine-rich
ionic liquid is introduced into the perovskite
active layer, so that multi-point
passivation of defects is realized, the
photoluminescence intensity is improved, the form of the film is improved, the
crystallinity is expanded, charge transfer is balanced, the
photoelectric conversion efficiency is enhanced, the stability is improved, and the
hysteresis effect of a device is effectively inhibited.