Semi-conductor electrode and method for making and solar cell containing the semiconductor electrode

A solar cell and semiconductor technology, applied in the field of dye-sensitized solar cells, can solve the problems of low photoelectric conversion rate of dye-sensitized solar cells, low utilization rate of conductive particles, low conductivity of semiconductor nanocrystal film, etc., and achieve cost reduction , prolong life, reduce the effect of dosage

Active Publication Date: 2008-06-04
BYD CO LTD
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  • Application Information

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Problems solved by technology

According to this dye-sensitized solar cell electrode, conductive particles are added to the semiconductor nanocrystal film, and the conductivity of the conductive particle is utilized. Although the conductivity of the semiconductor nanocrystal film can be improved to a certain extent, the utilization rate of the conductive particle is not high. Therefore, the conductivity of the semiconductor nanocrystalline film is still not high, and the photoelectric conversion rate of the dye-sensitized solar cell is low.

Method used

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  • Semi-conductor electrode and method for making and solar cell containing the semiconductor electrode
  • Semi-conductor electrode and method for making and solar cell containing the semiconductor electrode
  • Semi-conductor electrode and method for making and solar cell containing the semiconductor electrode

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preparation example Construction

[0023] The preparation method of the semiconductor electrode provided by the present invention comprises forming a semiconductor nanocrystalline film containing semiconductor particles and conductive particles on the conductive bottom layer, and then forming a dye layer on the semiconductor nanocrystalline film, wherein the conductive particles are obtained by loading metal particles Composite conductive particles made on the surface of carbon particles.

[0024]The preparation method of the composite conductive particles includes loading metal particles on the surface of carbon particles. Metal particles can be supported on the surface of carbon particles by various existing methods, for example, impregnation reduction method or ion exchange method can be used. The preparation process of the composite conductive particles will be described in detail below by taking the impregnation reduction method as an example.

[0025] The impregnation reduction method involves contacting...

Embodiment 1

[0038] This example is used to prepare the semiconductor electrode for a dye-sensitized solar cell provided by the present invention and the dye-sensitized solar cell containing the semiconductor electrode.

[0039] (1) Preparation of composite conductive particles

[0040] 0.25 gram of carbon black powder (particle diameter is 25 nanometers) is uniformly dispersed in 100 milliliters of isopropanols, then add concentration and be 0.005 mol / L chloroplatinic acid aqueous solution, keep stirring for 5 hours, control pH value simultaneously to be 7, make carbon Black fully adsorbed chloroplatinic acid to obtain a suspension. Wherein, the consumption of the chloroplatinic acid aqueous solution is such that the weight ratio of platinum contained in the chloroplatinic acid to carbon black is 1:5. Add formaldehyde subsequently, reduce at 40 ℃ for 1 hour, the number of moles of formaldehyde is 3 times of the number of moles of platinum in chloroplatinic acid. After the reaction was c...

Embodiment 2

[0054] This example is used to prepare the semiconductor electrode for a dye-sensitized solar cell provided by the present invention and the dye-sensitized solar cell containing the semiconductor electrode.

[0055] The dye-sensitized solar cell R2 was prepared in the same manner as in Example 1, except that the composite conductive particles P1 prepared as follows were used to replace the composite conductive particles P1, and the mixed weight of the composite conductive particles P2, semiconductor particles and water The ratio is 1:200:600.

[0056] 3 grams of VXC-72 active carbon (particle diameter is 30 nanometers) is uniformly dispersed in 450 milliliters of isopropanols, then adding concentration is 0.05 mol / liter silver nitrate aqueous solution, keep stirring for 5 hours, control pH value simultaneously to be 10, make Activated carbon fully adsorbs silver nitrate to obtain a suspension. Wherein, the consumption of silver nitrate aqueous solution makes the weight ratio ...

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Abstract

A semiconductor electrode for a dye-sensitized solar cell comprises a conductive bottom layer, a semiconductor nanometer crystal membrane formed on the conductive bottom layer, and a dye layer formed on the semiconductor nanometer crystal membrane. The semiconductor nanometer crystal membrane contains semiconductor particles and conductive particles; the conductive particles are composite conductive particles which contain metal particles and carbon particles, and the metal particles are loaded on the surface of the carbon particles. The invention also provides a method for preparing the semiconductor electrode and the dye-sensitized solar cell which contains the semiconductor electrode. The semiconductor nanometer crystal membrane contains the composite conductive particles which contain the carbon particles and the metal particles which are loaded on the surface of the carbon particles, thus improving the use efficiency of the metal particles. The metal particles can be used as capture wells for electrons, so that the electrons and cavities in the semiconductor are separated effectively, and the life of the electronic-cavity is prolonged and the photo-generated current is increased, thus enhancing the photoelectric conversion rate of the dye-sensitized solar cell.

Description

technical field [0001] The invention relates to a semiconductor electrode, a preparation method thereof and a dye-sensitized solar cell containing the semiconductor electrode. Background technique [0002] Today, when non-renewable energy sources such as electricity, coal, and oil are in short supply, free, clean and inexhaustible solar energy has attracted the attention of the world. Solar cells, a device that can directly convert solar energy into electrical energy, have become the field of many researchers. Silicon solar cells were first developed by Bell Laboratories in the United States and have high photoelectric conversion efficiency, so it became the first solar cell product to be industrially produced. However, the manufacturing process of silicon solar cells is complex, expensive and the raw material silicon is increasingly scarce, which restricts its wide application. Swiss Institute of Technology Lausanne Professor and others first proposed the concept of dye...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L31/0224H01L31/04H01L51/44H01L51/42H01M14/00H01G9/20
CPCY02E10/542Y02E10/549Y02P70/50
Inventor 刘倩倩董俊卿
Owner BYD CO LTD
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