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33results about "Organic semiconductors manufacture/treatment" patented technology

Perovskite solar cell and preparation method thereof

The invention provides a perovskite solar cell and a preparation method thereof and relates to a solar cell. The perovskite solar cell is of a laminated structure and is sequentially provided with a substrate, a transparent electrode, a compact electron transfer layer, a mesopore layer, a perovskite light absorption layer, a hole transporting layer and a counter electrode from bottom to top. The preparation method comprises the steps of performing evaporation or sputtering of the transparent electrode on the substrate; coating the transparent electrode with dispersion liquid, and after sintering, preparing the electron transfer layer; coating the electron transfer layer with dispersion liquid, and after sintering, preparing the mesopore layer; coating the mesopore layer with a one-step method perovskite alkaline solution, and after annealing, preparing a perovskite crystal film; preparing the counter electrode on the perovskite crystal film, and obtaining the perovskite solar cell. Prepared perovskite film crystal is high in thickness and compact, holes and needle holes and the like are eliminated completely, the high quality film-forming reproducibility of perovskite is very good, and the stability and photoelectric conversion efficiency of the perovskite solar cell are greatly improved.
Owner:SUZHOU GCL NANO TECH CO LTD

Copper(I) complexes for optoelectronic devices

Copper(I) complexes for the emission of light with a structure according to formula A:wherein:M is Cu(I);L-B-L: a neutral, bidentate ligand,Z4-Z7: includes N or the fragment CR, with R=organic group, selected from the group consisting of: hydrogen, halogen or deuterium or groups which are bound via oxygen (—OR′″), nitrogen (—NR′″2), or phosphorous atoms (PR′″2) as well as alkyl, aryl, heteroaryl, alkenyl, alkinyl, trialkylsilyl and triarylsilyl groups or substituted alkyl, aryl, heteroaryl and alkenyl groups with substituents such as halogens or deuterium or lower alkyl groups;X is either CR′″2 or NR′″;Y is either O, S or NR′″;Z8 includes the fragment CR′, with R′=O*R′″, N*R′″2 or P*R′″2, wherein the bond to the Cu atom is carried out via these groups;R″ is a sterically demanding substituent, which inhibits a change in geometry in direction to planarization of the complex in excited state,R′″=organic group which is selected from the group consisting of: hydrogen, halogen or deuterium, as well as alkyl, aryl, heteroaryl, alkenyl, alkinyl groups or substituted alkyl, aryl, heteroaryl and alkenyl groups with substituents such as halogens or deuterium, alkyl groups, and further generally known donor and acceptor groups* indicates the atom which receives the complex bond; and# indicates the atom which mediates the bond with the second chemical unit.
Owner:SAMSUNG DISPLAY CO LTD

Organic semiconductor material composition and semiconductor layer of organic field effect transistor and preparation method for semiconductor layer

The invention relates to an organic semiconductor material composition and a semiconductor layer of an organic field effect transistor and a preparation method for the semiconductor layer. The organic semiconductor material composition comprises a naphthalimide derivative, a polymer additive and an organic solvent. The organic semiconductor material composition disclosed in the invention can prepare the semiconductor layer of the organic field effect transistor by adopting film dropping or ink jetting and printing methods, so that preparation of the organic field effect transistor by adopting an all-soliton method or even an all-printing method can be realized, and production efficiency and production scale can be improved and enlarged; and in addition, the composition is high in stability in the air, the prepared semiconductor layer is high in crystallization property, the performance of the transistor can be improved, and operation of the organic field effect transistor at a low voltage (less than or equal to 5V) can be realized. Particularly, the semiconductor composition disclosed in the invention adopts the non-chlorine solvent which has relatively low pollution to environment and human body, so that the chlorine-containing solvent which cannot be degraded by microbe in environment easily and is commonly used in the existing organic semiconductor field can be replaced.
Owner:SHANGHAI MI FANG ELECTRONICS LTD

Copper(i) complexes for optoelectronic devices

Copper(I) complexes for the emission of light with a structure according to formula A:
wherein:
    • M is Cu(I);
    • L-B-L: a neutral, bidentate ligand,
    • Z4-Z7: includes N or the fragment CR,
    •  with R=organic group, selected from the group consisting of: hydrogen, halogen or deuterium or groups which are bound via oxygen (—OR′″), nitrogen (—NR′″2), or phosphorous atoms (PR′″2) as well as alkyl, aryl, heteroaryl, alkenyl, alkinyl, trialkylsilyl and triarylsilyl groups or substituted alkyl, aryl, heteroaryl and alkenyl groups with substituents such as halogens or deuterium or lower alkyl groups;
    • X is either CR′″2 or NR′″;
    • Y is either O, S or NR′″;
    • Z8 includes the fragment CR′,
    •  with R′═O*R′″, N*R′″2 or P*R′″2, wherein the bond to the Cu atom is carried out via these groups;
    • R″ is a sterically demanding substituent, which inhibits a change in geometry in direction to planarization of the complex in excited state,
    • R′″=organic group which is selected from the group consisting of: hydrogen, halogen or deuterium, as well as alkyl, aryl, heteroaryl, alkenyl, alkinyl groups or substituted alkyl, aryl, heteroaryl and alkenyl groups with substituents such as halogens or deuterium, alkyl groups, and further generally known donor and acceptor groups
    • * indicates the atom which receives the complex bond; and
    • # indicates the atom which mediates the bond with the second chemical unit.
Owner:SAMSUNG DISPLAY CO LTD

Planar perovskite photovoltaic cell with metal phthalocyanine compound as electron transfer layer

The invention relates to a planar perovskite photovoltaic cell with a metal phthalocyanine compound as an electron transfer layer and belongs to the field of optoelectronic materials and devices. The cell is composed of a transparent conducting substrate, a hole transfer layer, a perovskite light absorption layer, the electron transfer layer, an electrode modifying layer and a metal electrode. The cell has the advantages that the metal phthalocyanine compound growing through a primary vacuum deposition method serves as the electron transfer layer to replace a traditional electron transfer layer based on a fullerene derivative. The prepared metal phthalocyanine compound has stable chemical properties, has good heat resistance, sun proofing, acid resistance and alkali resistance, and the perovskite light absorption layer can be well protected. The metal phthalocyanine compound is applied to the perovskite photovoltaic cell, the cost of the cell is reduced, and the service life of the cell is prolonged. The perovskite photovoltaic cell with the metal phthalocyanine compound as the electron transfer layer is high in photoelectric conversion efficiency, simple in structure, low in cost and stable in performance.
Owner:晋芳芳

Preparation method for patterned organic thin film

The invention discloses a preparation method for a patterned organic thin film, belongs to the technical field of organic thin film patterning, and solves a technical problem of high possibility of thermal damage to a non-processing layer adjacent to a to-be-processed layer during laser etching of the to-be-processed layer in an organic thin film patterning method in the prior art. The preparation method comprises the following steps: firstly, preparing a patterned substrate thin film layer on an upper surface of a substrate; secondly, preparing a single layer or a compound organic thin film layer on the patterned substrate thin film layer and the exposed upper surface of the substrate; thirdly, scanning the single layer or the compound organic thin film layer point by point through an infrared laser source, enabling the patterned substrate thin film layer to absorb heat by utilizing difference of the absorption rate of an organic thin film material and a substrate thin film material to infrared rays, burning off the single layer or the compound organic thin film layer on the patterned substrate thin film layer, reserving the single layer or the compound organic thin film layer on the exposed upper surface of the substrate, and obtaining the patterned organic thin film. The preparation method does not have a requirement on the pulse width of a laser, and is easy to guarantee in processing quality and low in cost.
Owner:CHANGCHUN INST OF APPLIED CHEMISTRY - CHINESE ACAD OF SCI

Photoelectric device manufacturing system with online detection function

The invention discloses a photoelectric device manufacturing system with an online detection function. The photoelectric device manufacturing system comprises a conversion chamber (1), a first evaporation chamber (2), a second evaporation chamber (3), a glove box (4) and a detection chamber (5). The conversion chamber (1) is communicated with the first evaporation chamber (2), the second evaporation chamber (3), the glove box (4) and the detection chamber (5) through a vacuum isolation valve; a first rotary table (16) is arranged in the first evaporation chamber (2), and a plurality of organic material evaporation sources (17) are arranged on the periphery of the first rotary table (16); a second rotary table (18) is arranged in the second evaporation chamber (3), and a plurality of inorganic material evaporation sources (19) are arranged on the periphery of the second rotary table (18); the first rotary table (16) and the second rotary table (18) can rotate; a transmission device is arranged in the conversion chamber (1), and an online detection device is arranged in the detection chamber (5). According to the photoelectric device manufacturing system, online detection of performance of photoelectric devices can be achieved, and therefore the photoelectric devices can be prevented from being exposed to the atmospheric environment in the detection process.
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI

Thermally Excited Delayed Fluorescent Host Material Based on Phosphine Heteroaryl Derivatives and Its Preparation Method and Application

A thermally excited delayed fluorescent host material based on phosphine heteroaryl derivatives and its preparation method and application, which relate to a thermally excited delayed fluorescent host material and its preparation method and application. It aims to solve the technical problem that the existing planar heat-excited delayed fluorescent dye molecules are prone to quenching, resulting in low device efficiency. The structural formula of the thermally excited delayed fluorescence host material of the present invention is: Preparation method: react the derivatives of o-dibromobenzene, phenylphosphine dichloride, and n-butyllithium in tetrahydrofuran, and then extract and dry, then directly purify or vulcanize / and purification after oxidation to obtain the product; or the derivatives of o-dibromobenzene, phenyl phosphine dichloride, and n-butyllithium react with diphenyl phosphine chloride in tetrahydrofuran and then react with diphenyl phosphine chloride. After reoxidation, carry out Purification affords the product. The fluorescent host material based on the phosphine heteroaryl derivative is used in thermal excitation delayed fluorescence electroluminescent devices.
Owner:HEILONGJIANG UNIV
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