The invention discloses a novel CH3NH3PbI3 /
polyimide composite material and a preparation method thereof. The preparation method comprises the following steps: (1) preparation of CH3NH3I and CH3NH3PbI3; (2) preparation of
polyimide; (3) preparation of the CH3NH3PbI3 /
polyimide composite material, i.e., dissolving the prepared polyimide into
dimethyl formamide, adding the CH3NH3PbI3 into a solution, stirring with great force under
room temperature, pouring an obtained uniform mixture onto a glass plate with a
silica gel mould, performing programmed heating in a
muffle furnace, after heating is ended, cooling to
room temperature, and stripping to obtain a CH3NH3PbI3 / polyimide
composite film. According to the CH3NH3PbI3 / polyimide
composite material prepared by the preparation method, a
perovskite / polyimide composite material is prepared by means of excellent film-forming property of the polyimide; electrical property of
perovskite and
mechanical property of the polyimide are both achieved; the CH3NH3PbI3 can serve as an
electron absorption layer, the polyimide can serve as a
hole transport layer, thus forming a perfect conductive network and facilitating the application of a
perovskite composite material in a
solar cell.