The invention relates to a bithiophene-biscoumarin-based
BODIPY near-
infrared fluorescent dye and a preparation method thereof, and the preparation method is realized by the following steps: carrying out
Knoevenagel condensation reaction on a diiodo
BODIPY derivative (I) and 7-(N, N-diethylamino)
coumarin-3-
formaldehyde to obtain a 3, 5-biscoumarin-based
BODIPY derivative (II), and then carrying out
Sonogashira coupling reaction of the 3, 5-biscoumarin-based BODIPY derivative (II) with 2-
acetylene thiophene, so as to obtain the bithiophene-biscoumarin-based BODIPY derivative (III). The preparation method has the advantages of simple reaction steps, mild
reaction conditions and good selectivity. The fluorescent dye has excellent photophysical properties such as high
molar extinction coefficient (greater than 3.0 * 10 < 5 > cm <-1 > mol <-1 > L), large
Stokes shift, good light stability and the like. The strongest
electron absorption spectrum
red shift is 770nm, the maximum
fluorescence emission
wavelength is 818nm, and the fluorescent dye has a good application prospect in the fields of
optical imaging,
fluorescence identification, tumor diagnosis, military reconnaissance,
infrared camouflage, organic photovoltaic materials and the like.