The invention discloses a preparation method of a sulfur-doped tin disulfide/tin dioxide@C/rGO material and application of the sulfur-doped tin disulfide/tin dioxide@C/rGO material in a lithium ion battery. The preparation method comprises the following steps: dissolving SnCl2 into concentrated HCl to form a stable SnCl2 solution; mixing a SnCl2 solution, GO colloid, thiourea, L-ascorbic acid andthe like, and performing stirring to form a uniform mixed solution; carrying out water bath negative pressure evaporation on the mixed solution, and then carrying out hydrothermal treatment to obtaina precursor; after a hydrothermal kettle is cooled to room temperature, centrifuging the precursor, and sequentially washing the obtained precipitate with water and alcohol; and transferring the precipitate into the hydrothermal kettle again, adding H2O2, carrying out hydrothermal treatment again, cooling a sample in the kettle to room temperature, performing centrifuging, performing washing withwater, performing washing with alcohol, and carrying out freeze drying on the obtained precipitate to obtain the sulfur-doped tin disulfide/tin dioxide@C/rGO material. The preparation method is simpleto operate, environment-friendly and low in energy consumption, and the prepared nano composite electrode material has excellent electrochemical performance.