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80results about How to "Break symmetry" patented technology

Novel phosphorus and nitrogen containing flame-retardant thermotropic liquid crystal copolyester with low melting point and synthesis method thereof

InactiveCN102140164ALower liquid crystal phase transition temperatureImprove flame retardant propertiesDiamineSolvent
The invention discloses a phosphorus and nitrogen containing flame-retardant thermotropic liquid crystal copolyester with low melting point and a synthesis method thereof; the phosphorus and nitrogen containing flame-retardant thermotropic liquid crystal copolyester with low melting point is synthesized by taking diacetic ester of 10-(2, 5-dyhydroxy phenyl group)-10-hydrogen-9-oxa-10-phosphaphenanthrene-10-oxide, p-acetoxy-benzoic acid, terephthalic acid and a condensation product of terephthalic acid and aliphatic series diamine with methylene flexible chain as reactive monomers which undergo melt phase polycondensation. The main chain of the molecules of the hermotropic liquid crystal copolyester contains methylene flexible chains; therefore, compared with the common liquid crystal copolyester, the transition temperature of the liquid crystal is greatly reduced and can be matched with the processing temperature of most general-purpose plastics. As the thermotropic liquid crystal copolyester contains halogen free and flame-retardant elements such as phosphorous and nitrogen, the thermotropic liquid crystal copolyester achieves the purpose of high efficiency flame retardant while reinforcing general-purpose plastics. The synthesis method for thermotropic liquid crystal copolyester is simple, is easy to operate, has high reaction speed and high yield, avoids the using of large quantity of solvents and is in line with the requirements of sustainable development.
Owner:DALIAN POLYTECHNIC UNIVERSITY

Compound containing spiro-xanthene fluorene and application of compound to organic light-emitting device

The invention discloses a compound containing spiro-xanthene fluorene and an application of the compound to an organic light-emitting device. The compound has a spiro-xanthene fluorene structure, so that the compound has high rigidity and the advantages that crystallization and aggregation between molecule cannot be easily formed, and the compound has good film-forming property and the like afterbeing connected with a long-chain branch structure of a carbazole derivative. A parent nucleus of the compound has double polarity, a branch chain is provided with an electron-donating group, the electron donating abilities of a branch chain group are different, so that HOMO energy levels of a material are different, and the compound can serve as different functional layer materials to be used. The compound has higher triplet-state energy levels, energy loss can be effectively blocked, and energy transfer is facilitated. The compound serves as an organic light-emitting functional layer material to be applied to an OLED (organic light-emitting diode) device, current efficiency, power efficiency and external quantum efficiency of the device are greatly improved, and the service life of the device is obviously prolonged.
Owner:JIANGSU SUNERA TECH CO LTD

Substituted 9,10-dinaphthyl anthracene blue light-emitting organic electro-luminescent material and method for preparing same

The invention relates to a blue light-emitting organic electro-luminescent material, in particular to the blue-light-emitting organic electro-luminescent material of 9,10-dinaphthyl anthracene derivatives, which has the following structural formula, wherein R1 and R2 can be methyl, ethyl, isopropyl, tertiary butyl, 4-metrylphenyl and the halides thereof, and can be either the same or different. The invention also provides a method for preparing the substituted anthracene blue light-emitting organic electro-luminescent material. In the invention, through a molecular designing method, some rigid radicals, such as the methyl, the ethyl or the tertiary butyl and the like, are introduced into a major structure of ADN so as to increase the steric hindrance of the ADN, which breaks the symmetry of the AND, increases intervals among molecules and can solve the problem of the shape of a thin film to make the image forms of the thin film of the material obtained better than that prior to and after annealing, achieve the effect of approaching dark blue light; and the efficiency of the material is remarkably improved and is 1.2 to 1.5 times of the traditional efficiency.
Owner:上海拓引数码技术有限公司

Spiro-xanthene fluorene-cored compound and application thereof to organic electroluminescent devices

The invention discloses a spiro-xanthene fluorene-cored compound and application thereof to organic electroluminescent devices. Containing a s spiro-xanthene fluorene structure, the spiro-xanthene fluorene-cored compound is high in rigidity, and after being connected with the long-branch-chain structure of carbazole derivatives, has the advantages of being less prone to intermolecular crystallization and aggregation, good in film forming properties and the like. Due to the facts that the parent nucleus is bipolarized and the branch chains serve as electron-donating groups with different electron-donating capacities, the spiro-xanthene fluorene-cored compound can present different HOMO (highest occupied molecular orbital) energy levels and further can serve as different functional layer materials. Besides, the spiro-xanthene fluorene-cored compound is high in triplet state energy level and capable of effectively blocking energy loss and facilitating energy transferring. Therefore, whenthe spiro-xanthene fluorene-cored compound is applied to OLED (organic light emitting diode) devices, the current efficiency, the power efficiency and the external quantum efficiency of the devices can be greatly improved, and meanwhile, the service life of the devices can be significantly prolonged.
Owner:JIANGSU SUNERA TECH CO LTD
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