The invention discloses a preparation method for 9,9-diaryl
thiophene xanthene-10,10-dioxide, and belongs to the field of fine
organic synthesis and
organic semiconductor material preparation. The preparation method comprises the following steps: using diphenylsulphone as a starting material and tetrahydro
furan as a
solvent, conducting ortho
metalation reaction on diphenylsulphone under the action of n-
butyllithium within a temperature range of -78-0 DEG C to obtain a corresponding
aryl lithium salt; allowing the
aryl lithium salt to react with an added
aryl formic
ether ester derivative, and performing
hydrolysis to obtain a corresponding
tertiary alcohol; dissolving the
tertiary alcohol and
electron-rich aromatic with an acetate or
methylene chloride solution, using Lewis acid as a catalyst, and carrying out friedel-crafts reaction to obtain the 9,9-diaryl
thiophene xanthene-10,10-dioxide. The preparation method has the advantages that the reactions are easy to control, the operation is simple, the cost is low, the
repeatability is good, the productivity is high, and the product quality is high; an organic
modular unit and an organic functional
semiconductor can be conveniently made; the 9,9-diaryl
thiophene xanthene-10,10-dioxide is used in the fields of organic light emitting diodes, organic transistors,
organic laser, and organic
nonlinear optics, and the like.